聚芳醚腈结构调控与结晶性能的研究进展

肖倩; 张婷; 陈亚妮; 童利芬; 刘书宁; 刘孝波

doi:10.11777/j.issn1000-3304.2025.25174

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聚芳醚腈结构调控与结晶性能的研究进展

综述 | 更新时间：2026-01-16

- 聚芳醚腈结构调控与结晶性能的研究进展
- Advances in Structural Regulation and Crystallization Properties of Poly(arylene ether nitrile)
- 高分子学报 2026年57卷第1期页码：47-65
- 作者机构：
  
  电子科技大学材料与能源学院四川省碳氮高分子新材料工程技术研究中心成都 611731
- 作者简介：
  
  [ "刘孝波，男，1965年生，电子科技大学，教授. 1986年获四川大学物理化学专业学士学位，1989年获四川大学高分子物理化学专业硕士学位，1995年获四川大学高分子材料科学与工程专业博士学位，1997年入选中国科学院首批“百人计划”，2021年入选俄罗斯自然科学院院士，曾获得四川省科技进步一等奖、四川省科技发明二等奖，四川省有突出贡献的优秀专家，享受国务院政府特殊津贴. 先后承担和完成国家“863”项目、国家自然科学基金、四川省杰出青年基金、军品配套项目及应用技术开发科研项目40余项，获得具有国际先进水平的省部级鉴定成果10余项，具有国际领先技术水平的鉴定成果3项. 申请中国发明专利100余项，其中授权专利60余项；发表SCI论文500余篇，被引用万余次. 主要从事先进功能高分子材料研究，首次在国内实现了芳腈基聚合物的工业化规模生产." ]
- 基金信息：
  
  四川省科技厅项目(2024YFCY0015)
- DOI：10.11777/j.issn1000-3304.2025.25174
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7481
- 收稿：2025-07-25，
  
  录用：2025-09-29，
  
  网络出版：2026-01-07，
  
  纸质出版：2026-01-20
- 稿件说明：
移动端阅览
肖倩, 张婷, 陈亚妮, 童利芬, 刘书宁, 刘孝波. 聚芳醚腈结构调控与结晶性能的研究进展. 高分子学报, 2026, 57(1), 47-65.

Xiao, Q.; Zhang, T.; Chen, Y. N.; Tong, L. F.; Liu, S. N.; Liu, X. B. Advances in structural regulation and crystallization properties of poly(arylene ether nitrile). Acta Polymerica Sinica (in Chinese), 2026, 57(1), 47-65.
肖倩, 张婷, 陈亚妮, 童利芬, 刘书宁, 刘孝波. 聚芳醚腈结构调控与结晶性能的研究进展. 高分子学报, 2026, 57(1), 47-65. DOI： 10.11777/j.issn1000-3304.2025.25174. CSTR： 32057.14.GFZXB.2025.7481.

Xiao, Q.; Zhang, T.; Chen, Y. N.; Tong, L. F.; Liu, S. N.; Liu, X. B. Advances in structural regulation and crystallization properties of poly(arylene ether nitrile). Acta Polymerica Sinica (in Chinese), 2026, 57(1), 47-65. DOI： 10.11777/j.issn1000-3304.2025.25174. CSTR： 32057.14.GFZXB.2025.7481.

摘要

结晶型聚芳醚腈作为高性能特种工程塑料，以其出色的力学强度、耐化学腐蚀性、柔韧性和电绝缘性，在电介质、光学器件、热管理材料等尖端领域展现出广阔的应用前景，其性能的优劣从根本上取决于分子链结构设计及聚集态结构的精确调控. 近年来，通过主链修饰、共聚改性等分子工程策略优化其结晶行为，借助成核剂调控、外场(热场、应力场)诱导等物理化学手段协同提升材料性能，成为该领域的研究热点. 本综述聚焦结晶型聚芳醚腈的最新研究进展，系统梳理了聚芳醚腈结晶行为的研究方法，深入探讨了结构调控对其热稳定性、机械性能及微观形貌的影响机制. 通过对比不同改性策略的优缺点，提出了“多尺度协同设计”的未来发展方向，旨在为新一代高性能聚芳醚腈材料的开发提供理论指导与技术支撑.

Abstract

As a high-performance special engineering plastic

semi-crystalline poly(arylene ether nitrile) (PEN) has shown broad application prospects in cutting-edge fields such as dielectrics

optical devices

and thermal management materials owing to its excellent mechanical strength

chemical corrosion resistance

flexibility

and electrical insulation. The quality of its performance fundamentally depends on the design of the molecular chain structure and the precise regulation of the aggregated structure. In recent years

researchers have optimized its crystallization behavior through molecular engineering strategies

such as main chain modification and copolymerization modification

and synergistically improved material performance using physical and chemical methods

such as nucleating agent regulation and external field (thermal field

stress field) induction

which has become a research hotspot in this field. This paper systematically reviews the research methods of polyarylene ether nitrile crystallization behavior

focusing on the latest research progress of crystalline polyarylene ether nitrile

and discusses the influence mechanism of structural regulation on its thermal stability

mechanical properties

and micro-morphology. By comparing the advantages and disadvantages of different modification strategies

the future development direction of "multi-scale collaborative design" is proposed

aiming to provide theoretical guidance and technical support for the development of a new generation of high-performance polyarylene ether nitrile materials.

关键词

Keywords

references

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