新型高性能环烯烃光学树脂的制备与性能研究

丁营利; 高欢; 潘莉; 李悦生

doi:10.11777/j.issn1000-3304.2025.25257

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新型高性能环烯烃光学树脂的制备与性能研究

研究论文 | 更新时间：2026-02-11

- 新型高性能环烯烃光学树脂的制备与性能研究
- Preparation and Performance Study of Novel High-performance Cycloolefin Optical Resins
- 高分子学报 2026年57卷第3期页码：742-753
- 作者机构：
  
  天津大学材料科学与工程学院天津 300350
- 作者简介：
  
  E-mail: lilypan@tju.edu.cn
- 基金信息：
  
  国家自然科学基金面上项目(基金号 52373013)
- DOI：10.11777/j.issn1000-3304.2025.25257
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7513
- 收稿：2025-10-04，
  
  录用：2025-11-05，
  
  网络首发：2026-01-14，
  
  纸质出版：2026-03-20
- 稿件说明：
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丁营利, 高欢, 潘莉, 李悦生. 新型高性能环烯烃光学树脂的制备与性能研究. 高分子学报, 2026, 57(3), 742-753.

Ding, Y. L.; Gao, H.; Pan, L.; Li, Y. S. Preparation and performance study of novel high-performance cycloolefin optical resins. Acta Polymerica Sinica (in Chinese), 2026, 57(3), 742-753.
丁营利, 高欢, 潘莉, 李悦生. 新型高性能环烯烃光学树脂的制备与性能研究. 高分子学报, 2026, 57(3), 742-753. DOI： 10.11777/j.issn1000-3304.2025.25257. CSTR： 32057.14.GFZXB.2025.7513.

Ding, Y. L.; Gao, H.; Pan, L.; Li, Y. S. Preparation and performance study of novel high-performance cycloolefin optical resins. Acta Polymerica Sinica (in Chinese), 2026, 57(3), 742-753. DOI： 10.11777/j.issn1000-3304.2025.25257. CSTR： 32057.14.GFZXB.2025.7513.

摘要

随着高端光学器件的快速发展，对传统商业化环烯烃聚合物(COPs)提出了更高的性能与功能型要求. 本研究设计并合成了一类兼具低折射率且界面性能(疏水性)可调的高玻璃化转变温度(

)的功能型环烯烃聚合物. 通过开环易位聚合(ROMP)及后续氢化处理，将含冰片结构的降冰片烯衍生物与含氟四环十二烯衍生物进行共聚，实现了氟含量在7.3 wt%~25.1 wt%的范围内可调. 环烯烃聚合物体系在589 nm波长处的折射率(

589nm

)为1.4789~1.5121，阿贝数超过59，在可见光至近紫外区域均具备优异透光性. 同时，材料还展现出优异的热稳定性(

100 ℃，热分解温度(

)

246 ℃)，良好的力学性能、成膜性及宽热加工窗口(

143 ℃). 此外，通过调节共聚物中功能单体的组成，材料在保持高透明性和无定形结构同时，还实现了界面性能(疏水性)随氟含量线性可调的特性. 得益于氟原子和冰片结构的引入，该材料在医用光学镜头的抗生物污染等领域也表现出潜在的应用价值.

Abstract

With the rapid advancement of high-end optical devices

conventional commercial cycloolefin polymers (COPs) are facing increasing demands for enhanced performance and functional requirements. In this study

a series of functional cycloolefin polymers with low refractive index and tunable interfacial properties (hydrophobicity) as well as high glass transition temperatures (

) were designed and synthesized. N

orbornene derivatives with a borneol framework and fluorinated tetracyclododecene derivatives were copolymerized

via

ring-opening metathesis polymerization (ROMP) followed by hydrogenation

enabling fluorine contents adjustable from 7.3 wt% to 25.1 wt%. The resulting cycloolefin polymers exhibited refractive index (

589 nm

) of 1.4789-1.5121 at 589 nm and Abbe numbers exceeding 59

along with excellent transmittance in the visible to near-ultraviolet region. These materials also demonstrated superior thermal stability (

100 ℃

thermal decomposition temperature

246 ℃)

favorable mechanical strength

film-forming ability

and a wide thermal processing window (

143 ℃). Furthermore

by tuning the comonomer composition

the polymers maintained high transparency and amorphous characteristics while achieving a linear dependence of interfacial hydrophobicity on fluorine content. Benefiting from the incorporation of fluorine atoms and borneol units

the materials hold great potential for applications in biomedical optical lenses with anti-biofouling properties.

关键词

Keywords

references

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