球形木质素磺酸-酚醛树脂的制备及其对罗丹明B的吸附性能研究

何涛; 王大铮; 王春红

doi:10.11777/j.issn1000-3304.2025.25260

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球形木质素磺酸-酚醛树脂的制备及其对罗丹明B的吸附性能研究

研究论文 | 更新时间：2026-02-11

- 球形木质素磺酸-酚醛树脂的制备及其对罗丹明B的吸附性能研究
- Preparation of Spherical Lignin-sulfoacid Phenolic Resin and Its Adsorption Performance for Rhodamine B
- 高分子学报 2026年57卷第3期页码：807-818
- 作者机构：
  
  南开大学功能高分子材料教育部重点实验室化学学院高分子化学研究所天津 300071
- 作者简介：
  
  E-mail: wch2004@nankai.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2025.25260
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7523
- 收稿：2025-10-11，
  
  录用：2025-12-01，
  
  网络首发：2026-01-15，
  
  纸质出版：2026-03-20
- 稿件说明：
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何涛, 王大铮, 王春红. 球形木质素磺酸-酚醛树脂的制备及其对罗丹明B的吸附性能研究. 高分子学报, 2026, 57(3), 807-818.

He, T.; Wang, D. Z.; Wang, C. H. Preparation of spherical lignin-sulfoacid phenolic resin and its adsorption performance for rhodamine B. Acta Polymerica Sinica (in Chinese), 2026, 57(3), 807-818.
何涛, 王大铮, 王春红. 球形木质素磺酸-酚醛树脂的制备及其对罗丹明B的吸附性能研究. 高分子学报, 2026, 57(3), 807-818. DOI： 10.11777/j.issn1000-3304.2025.25260. CSTR： 32057.14.GFZXB.2025.7523.

He, T.; Wang, D. Z.; Wang, C. H. Preparation of spherical lignin-sulfoacid phenolic resin and its adsorption performance for rhodamine B. Acta Polymerica Sinica (in Chinese), 2026, 57(3), 807-818. DOI： 10.11777/j.issn1000-3304.2025.25260. CSTR： 32057.14.GFZXB.2025.7523.

摘要

针对碱性染料废水处理及木质素高值化利用的双重需求，提出了一种

通过反相悬浮聚合一步制备球形木质素磺酸-酚醛树脂型吸附剂的方法. 通过优化聚合工艺、改变木质素磺酸钠投入量、交联剂及溶剂用量，实现了较高木质素投入量下的树脂球形度和吸附量的调控. 原位聚合引入磺酸基作为吸附位点，有效避免了额外改性步骤并实现了磺酸基较高密度(≥1.24 mmol·g

-1

)的保留与均匀分布. 吸附实验结果表明，所设计的球形木质素磺酸-酚醛树脂型吸附剂在较宽的pH范围内对碱性染料罗丹明B均有较高的吸附能力，吸附量高达2156 mg·g

-1

，远超广泛应用的商品化大孔强酸性树脂D072 (1502 mg·g

-1

)；结果讨论表明，其对罗丹明B的吸附机理主要归因于离子交换、疏水效应及氢键作用，且丰富的孔道结构有利于各吸附机制发挥协同作用，为碱性染料废水处理领域开发与设计高性能应用型木质素基酚醛树脂吸附剂提供了参考.

Abstract

Addressing the dual demands of alkaline dye wastewater treatment and high-value utilization of lignin

this study proposes a one-step suspension polymerization method for the preparation of spherical sodium lignosulfonate-phenolic resin-based adsorbents. By optimizing the polymerization process

adjusting the dosage of sodium lignosulfonate

cross-linking agent

and solvent

the regulation of resin sphericity and adsorption capacity under a relatively high lignin dosage was achieved. Sulfonic acid groups were introduced as adsorption sites through

in situ

polymerization

which effectively eliminated the need for additional modification steps and enabled the retention of a high density (≥1.24 mmol·g

-1

) of sulfonic acid gro

ups with uniform distribution. Adsorption experiments demonstrated that the designed spherical sodium lignosulfonate-phenolic resin-based adsorbents exhibited excellent adsorption capacity for the alkaline dye rhodamine B over a wide pH range

with a maximum adsorption capacity of up to 2156 mg·g

-1

. This value far exceeded that of the widely used commercial macroporous strong acid resin D072 (1502 mg·g

-1

). The discussion of the results indicated that the adsorption mechanism of rhodamine B was mainly attributed to ion exchange

hydrophobic effect and hydrogen bonding

and the abundant pore structure was conducive to the synergistic effect of various adsorption mechanisms. This research provides an important reference for the development and design of high-performance and practical lignin-based phenolic resin adsorbents in the field of basic dye wastewater treatment

and at the same time contributes to the high-value conversion of lignin

a renewable biomass resource.

关键词

Keywords

references

Abdi J. ; Vossoughi M. ; Mahmoodi N. M. ; Alemzadeh I. Synthesis of metal-organic framework hybrid nanocomposites based on GO and CNT with high adsorption capacity for dye removal . Chem. Eng. J. , 2017 , 326 , 1145 - 1158 . doi: 10.1016/j.cej.2017.06.054 http://dx.doi.org/10.1016/j.cej.2017.06.054

Kumar A. ; Khan M. ; He J. ; M . C . Lo, I. Visible-light-driven magnetically recyclable terephthalic acid functionalized g-C 3 N4/TiO2 heterojunction nanophoto catalyst for enhanced degradation of PPCPs. Appl. Catal. B: Environ., 2020, 270 , 118898 . doi: 10.1016/j.apcatb.2020.118898 http://dx.doi.org/10.1016/j.apcatb.2020.118898

Shi Y. W. ; Chang Q. ; Zhang T. W. ; Song . G . B.; Sun, Y. ; Ding, G. H. A review on selec tive dye adsorption by different mechanisms. J. Environ. Chem. Eng., 2022 , 10 ( 6 ), 108639 . doi: 10.1016/j.jece.2022.108639 http://dx.doi.org/10.1016/j.jece.2022.108639

Priya P. S. ; Nandhini P. P. ; Vaishnavi S. ; Pavithra V. ; Almutairi M. H. ; Almutairi B. O. ; Arokiyaraj S. ; Pachaiappan R. ; Arockiaraj J. Rhodamine B, an organic environmental pollutant induces reproductive toxicity in parental and teratogenicity in F1 generation in vivo . Comp. Biochem. Physiol. C Toxicol. Pharmacol. , 2024 , 280 , 109898 . doi: 10.1016/j.cbpc.2024.109898 http://dx.doi.org/10.1016/j.cbpc.2024.109898

Singh S. ; Kumar A. ; Gupta H. Activated banana peel carbon: a potential adsorbent for Rhodamine B decontamination from aqueous system . Appl. Water Sci. , 2020 , 10 ( 8 ), 1 - 8 . doi: 10.1007/s13201-020-01274-4 http://dx.doi.org/10.1007/s13201-020-01274-4

Behera A. K. ; Shadangi K. P. , Sarangl P. K. ; Efficient removal of Rhodamine B dye using biochar as an adsorbent: study the performance, kinetics, thermodynamics, adsorption isotherms and its reusability . Chemosphere , 2024 , 354, 141702 . doi: 10.1016/j.chemosphere.2024.141702 http://dx.doi.org/10.1016/j.chemosphere.2024.141702

Albadarin A. B. ; Collins M. N. ; Naushad M. ; Shirazian S. ; Walker G. ; Mangwandi C. Activated lignin-chitosan extruded blends for efficient adsorption of methylene blue . Chem. Eng. J. , 2017 , 307 , 264 - 272 . doi: 10.1016/j.cej.2016.08.089 http://dx.doi.org/10.1016/j.cej.2016.08.089

Liu K. ; Chen L. H. ; Huang L. L. ; Lin S. ; Cao S. L. ; Wang H. P. Adsorption behaviors of acidic and basic dyes by thiourea-modified nanocomposite aerogels based on nanofibrillated cellulose . Bioresources , 2018 , 13 ( 3 ), 5836 - 5849 . doi: 10.15376/biores.13.3.5836-5849 http://dx.doi.org/10.15376/biores.13.3.5836-5849

Chen D. ; Liu Y. ; Qin Y. ; Wang L. ; Ma Y. H. ; Yang W. T. Dual-functionalized hollow polymer particle as a pH-responsive adsorbent for selective removal of basic dye . Chin. J. Chem. , 2017 , 35 ( 5 ), 596 - 604 . doi: 10.1002/cjoc.201600681 http://dx.doi.org/10.1002/cjoc.201600681

柴红梅 , 任宜霞 , 祝磊 , 张瑞 . 新型吸附剂的制备、表征及对罗丹明B的吸附研究 . 离子交换与吸附 , 2019 , 35 ( 03 ), 251 - 259 .

Li H. ; Zhang C. Z ; Jiang Y. H. ; Ni W. W. ; Li M. S. ; Wang , Li . UiO-66-SO 3 H@ nylon-6 membrane for rapid adsorption and removal of rhodamine B (RhB) from aqueous solutions . Langmuir , 2025 , 41 , 16022 - 16032 . doi: 10.1021/acs.langmuir.5c01157 http://dx.doi.org/10.1021/acs.langmuir.5c01157

Khan M. A. ; Momina ; Siddiqui M. R. ; Marta O. ; Alshareef S. ; Rafatullah M. Removal of rhodamine b from water using a solvent impregnated polymeric dowex 5wx8 resin: statistical optimization and batch adsorption studies . Polymers , 2020 , 12 ( 2 ), 500 . doi: 10.3390/polym12020500 http://dx.doi.org/10.3390/polym12020500

Ma H. H. ; Kong A. Q. ; Ji Y. H. ; He B. Q. ; Song Y. F. ; Li J. X. Ultrahigh adsorption capacities for anionic and cationic dyes from wastewater using only chitosan . J. Cleaner Prod. , 2019 , 214 , 89 - 94 . doi: 10.1016/j.jclepro.2018.12.217 http://dx.doi.org/10.1016/j.jclepro.2018.12.217

Hu J. B. ; Liu W. ; Xia L.J. ; Yu G.D. ; Huang H.B. ; Guo H. ; Zhang W. ; Wang Y. L. ; Xu W. L. Preparation of a cellulose-based adsorbent and its removal of Disperse Red 3B dye . Cellulose , 2021 , 28 ( 12 ), 7909 - 7924 . doi: 10.1007/s10570-021-04042-y http://dx.doi.org/10.1007/s10570-021-04042-y

Bai L. L. ; Chen Y. X. , Ma H. T. ; Meng X. Preparation and application of cellulose-bbased materials with selective adsorption of dyes . Polymers , 2025 , 17 ( 12 ), 1653 . doi: 10.3390/polym17121653 http://dx.doi.org/10.3390/polym17121653

Chio C. L. ; Sain M. ; Qin W. S. Lignin utilization: a review of lignin depolymerization from various aspects . Renew. Sust. Energ. Rev , 2019 , 107 , 232 - 249 . doi: 10.1016/j.rser.2019.03.008 http://dx.doi.org/10.1016/j.rser.2019.03.008

Rath S. ; Pradhan D. ; Du H.S. ; Mohapatra S. ; Thatoi H. Transforming lignin into value-added products: perspectives on lignin chemistry, lignin-based biocomposites, and pathways for augmenting ligninolytic enzyme production . Adv. Compos. Hybrid Mater. , 2024 , 7 ( 1 ), 27 . doi: 10.1007/s42114-024-00836-3 http://dx.doi.org/10.1007/s42114-024-00836-3

Gao Z. W. ; Lang X. L. ; Chen S. ; Zhao C. Mini-review on the synthesis of lignin-based phenolic resin . Energy Fuels , 2021 , 35 ( 22 ), 18385 - 18395 . doi: 10.1021/acs.energyfuels.1c03177 http://dx.doi.org/10.1021/acs.energyfuels.1c03177

Li P. H. ; Su W. T. ; Zheng Y. R. ; Wang M. K. ; Wang H. ; Zhou H. ; Wu W. J. Characterization and properties of phenolic resin doped modified lignin . Int. J. Biol. Macromol. , 2024 , 275 , 133430 . doi: 10.1016/j.ijbiomac.2024.133430 http://dx.doi.org/10.1016/j.ijbiomac.2024.133430

严庆 , 代娟 , 刘旺衢 , 雷建都 , 李继定 , 王璐莹 . ZIF-67改性木质素磺酸钠/聚乙烯亚胺层层自组装膜的纳滤性能研究 . 离子交换与吸附 , 2019 , 35 ( 01 ), 9 - 19 .

Aro T. ; Fatehi P. Production and application of lignosulfonates and sulfonated lignin . ChemSusChem , 2017 , 10 ( 9 ), 1861 - 1877 . doi: 10.1002/cssc.201700082 http://dx.doi.org/10.1002/cssc.201700082

Sharma V. ; Tsai M. L. ; Nargotra P. ; Chen C. W. ; Sun P. P. , Singhania R. R. ; Patel A. K. ; Dong C. D. Journey of lignin from a roadblock to bridge for lignocellulose biorefineries: a comprehensive review . Sci. Total Environ. , 2023 , 861 , 160560 . doi: 10.1016/j.scitotenv.2022.160560 http://dx.doi.org/10.1016/j.scitotenv.2022.160560

Zhou X. F. ; Zheng P. L. ; Wang L. L. ; Liu X. B. Preparation of sulfonated poly(arylene ether nitrile)-based adsorbent as a highly selective and efficient adsorbent for cationic dyes . Polymers , 2018 , 11 ( 1 ), 32 . doi: 10.3390/polym11010032 http://dx.doi.org/10.3390/polym11010032

Zhu X. D. ; Xue D. X. ; Gu L. L. ; Li W. X. ; Xie A. M. ; Wang Z. Pyrene-based sulfonated organic porous materials for rapid adsorption of cationic dyes in water . Environ. Technol. , 2023 , 44 ( 18 ), 2795 - 2806 . doi: 10.1080/09593330.2022.2044918 http://dx.doi.org/10.1080/09593330.2022.2044918

Liu X. C. ; Liu A. L. ; Liu B. J. ; Zhang M. Y. Fabrication of monodisperse magnetic polystyrene mesoporous composite microspheres for high-efficiency selective adsorption and rapid separation of cationic dyes in textile industry wastewater . Langmuir , 2024 , 40 ( 21 ), 11277 - 11286 . doi: 10.1021/acs.langmuir.4c01036 http://dx.doi.org/10.1021/acs.langmuir.4c01036

Xu B. C. ; Zheng H. L. ; Wang Y. J. ; An . Y . Y.; Luo, K. ; Zhao, C.; Xiang, W. J. Poly(2-acrylamido-2-methylpropane sulfonic acid) grafted magnetic chitosan microspheres: preparation, characterization and dye adsorption. Int. J. Bio. Macromol., 2018 , 112 , 648 - 655 . doi: 10.1016/j.ijbiomac.2018.02.024 http://dx.doi.org/10.1016/j.ijbiomac.2018.02.024

Tejado A. ; Peña C. ; Labidi J. ; Echeverria E. M. ; Mondragon I. Physico-chemical characterization of lignins from different sources for use in phenol-formaldehyde resin synthesis . Bioresour. Techno. , 2007 , 98 ( 8 ), 1655 - 1663 . doi: 10.1016/j.biortech.2006.05.042 http://dx.doi.org/10.1016/j.biortech.2006.05.042

Xue S. ; Tu B. Y. ; Li Z. H. ; Ma X. Y. ; Xu Y. Q. ; Li M. H. ; Fang C. X. ; Tao H. S. Enhanced adsorption of rhodamine B over Zoysia sinica Hance-based carbon activated by amminium chloride and sodium hydroxide treatments . Colloids Surf. A Physicochem. Eng. Aspects , 2021 , 618 , 126489 . doi: 10.1016/j.colsurfa.2021.126489 http://dx.doi.org/10.1016/j.colsurfa.2021.126489

Wang Z. H. ; Shen D. K. ; Shen F. ; Wu C. F. ; Gu S. Kinetics, equilibrium and thermodynamics studies on biosorption of Rhodamine B from aqueous solution by earthworm manure derived biochar . Int. Biodeterior. Biodegrad. , 2017 , 120 , 104 - 114 . doi: 10.1016/j.ibiod.2017.01.026 http://dx.doi.org/10.1016/j.ibiod.2017.01.026

Gao X. L. ; Zheng M. Q. ; Zhao X. D. ; Song S. F. ; Gao Z. Q. Ultra-high-capacity adsorption of rhodamine B in a carboxyl-functionalized metal-organic framework via surface adsorption . J. Chem. Eng. Data , 2020 , 66 ( 1 ), 669 - 676 . doi: 10.1021/acs.jced.0c00818 http://dx.doi.org/10.1021/acs.jced.0c00818

Dai K. ; Peng X. Q. ; Yang P. P. ; Li M. ; Tang C. L. ; Zhuang W. ; Ying H. J. ; Wu J. L. Highly selective and efficient lignin-magnesium for removing cationic dyes from wastewater . J. Environ. Chem. Eng. , 2020 , 8 ( 5 ), 104283 . doi: 10.1016/j.jece.2020.104283 http://dx.doi.org/10.1016/j.jece.2020.104283

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