杂萘联苯聚芳醚系列高性能树脂的构筑与应用

刘乾; 程习彤; 贺翼平; 石鹏; 刘程; 王锦艳; 张守海; 蹇锡高

doi:10.11777/j.issn1000-3304.2025.25283

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杂萘联苯聚芳醚系列高性能树脂的构筑与应用

专论 | 更新时间：2026-01-16

- 杂萘联苯聚芳醚系列高性能树脂的构筑与应用
- Constructions and Applications of High-performance Resins of Aromatic Polymers Containing Phthalazinone Moieties
- 高分子学报 2026年57卷第1期页码：6-22
- 作者机构：
  
  大连理工大学化工学院高分子材料系辽宁省高性能树脂材料专业技术创新中心辽宁省高分子科学与工程重点实验室大连 116024
- 作者简介：
  
  [ "张守海，男，1974年生，教授，博士生导师，大连理工大学化工学院高分子材料系系主任. 1997年于大连理工大学获高分子化工学士学位，2003年于大连理工大学获材料学博士学位. 主要从事高性能高分子材料设计、合成及分离膜的研究. 获得2003年国家技术发明二等奖、2011年国家技术发明二等奖、2019年高等学校科学研究优秀成果奖(科学技术)自然科学二等奖、2023年中国石油和化学工业联合会创新团队奖等省部级以上奖励10项. 入选国家百千万人才工程，享受国务院政府特殊津贴；入选2018年辽宁省“兴辽英才计划”创新领军人才、2016年辽宁省“百千万人才工程”百人层次、2014年辽宁省高等学校杰出青年学者成长计划和大连市杰出青年科技人才培育计划等." ]
  [ "蹇锡高，男，1946年生，中国工程院院士，有机高分子材料专家，大连理工大学化工学院高分子材料系教授，高分子材料研究所所长. 主要从事高性能高分子材料设计、合成及应用技术研究. 1969年毕业于大连理工大学高分子化工专业，1994年被评为国家级有突出贡献的中青年专家. 在高性能工程塑料、高性能树脂基复合材料、耐高温特种绝缘材料、涂料、耐高温高效功能膜等领域做出了重大创造性成就和贡献. 获2003年度国家技术发明二等奖和2011年国家技术发明二等奖、2015年中国专利金奖、2016年日内瓦国际发明展特别金奖在内的十余项省部级以上科技奖励. 获100余项发明专利，2项专利被评为世界华人重大科技成果，12项技术已产业化." ]
- 基金信息：
  
  国家自然科学基金(基金号 ┣21776030);22178043┫
- DOI：10.11777/j.issn1000-3304.2025.25283
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7532
- 收稿：2025-10-16，
  
  录用：2025-12-03，
  
  网络出版：2026-01-04，
  
  纸质出版：2026-01-20
- 稿件说明：
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刘乾, 程习彤, 贺翼平, 石鹏, 刘程, 王锦艳, 张守海, 蹇锡高. 杂萘联苯聚芳醚系列高性能树脂的构筑与应用. 高分子学报, 2026, 57(1), 6-22.

Liu, Q.; Cheng, X. T.; He, Y. P.; Shi, P.; Liu, C.; Wang, J. Y.; Zhang, S. H.; Jian, X. G. Constructions and applications of high-performance resins of aromatic polymers containing phthalazinone moieties. Acta Polymerica Sinica (in Chinese), 2026, 57(1), 6-22.
刘乾, 程习彤, 贺翼平, 石鹏, 刘程, 王锦艳, 张守海, 蹇锡高. 杂萘联苯聚芳醚系列高性能树脂的构筑与应用. 高分子学报, 2026, 57(1), 6-22. DOI： 10.11777/j.issn1000-3304.2025.25283. CSTR： 32057.14.GFZXB.2025.7532.

Liu, Q.; Cheng, X. T.; He, Y. P.; Shi, P.; Liu, C.; Wang, J. Y.; Zhang, S. H.; Jian, X. G. Constructions and applications of high-performance resins of aromatic polymers containing phthalazinone moieties. Acta Polymerica Sinica (in Chinese), 2026, 57(1), 6-22. DOI： 10.11777/j.issn1000-3304.2025.25283. CSTR： 32057.14.GFZXB.2025.7532.

摘要

高性能聚合物是航空航天、能源电子等行业发展的重要材料. 如何通过

分子设计，对聚合物功能材料的微结构和性能进行精准调控，提升目标器件的综合性能是高性能聚合物研究的重要课题与研究前沿. 本文简要介绍了作者团队在杂萘联苯聚芳醚系列高性能工程塑料的合成与性能及其在高性能树脂基复合材料、绝缘材料、耐高温功能膜、热固性树脂的增韧、电化学储能装置以及骨植入材料等领域的研究进展. 从分子设计出发，首先成功研制具有扭曲、非平面结构特点的含杂萘联苯结构的新型单体，进而与双卤单体经亲核取代逐步聚合反应合成了多系列含杂萘联苯结构新型聚芳醚类高性能工程塑料. 该系列材料兼具良好溶解性和耐热性，突破了传统高性能工程塑料耐热性和难溶解耦合技术难题，不仅实现高性能聚合物制备成本的下降，还进一步实现高性能聚合物的溶液加工. 其玻璃化转变温度达250~388 ℃，5%热失重起始温度均高于500 ℃，可溶解于

-甲基吡咯烷酮、

-二甲基乙酰胺以及氯仿等几种有机溶剂；在高温下依然保持优异的综合性能；可广泛应用于航空航天、核能、电子电气等高技术领域和国民经济众多行业.

Abstract

High-performance polymers are key material foundations for the development of industries such as aerospace and energy electronics. The precise control of the microstructure and performance of functional materials by regulating the structure and properties of polymers through molecular design

thereby enhancing the overall performance of target devices

is an important scientific issue and research frontier in the field of high-performance polymers. This feature article briefly introduces the research progress of Professor Jian's team on the synthesis and properties of the phthalazinone-containing polyarylether series of high-performance engineering plasti

as well as their applications in high-performance resin-based composite materials

insulating materials

high-temperature-resistant functional membranes

toughening of thermosetting resins

electrochemical energy storage

and bone implant materials. A new monomer with a twisted

nonplanar structure containing a naphthalene-biphenyl structure was successfully developed through molecular design. This monomer was then reacted with phthalazinone monomers through nucleophilic substitution stepwise polymerization to synthesize a series of novel polyarylether-based high-performance engineering plastics with phthalazinone structures. These materials exhibit excellent solubility and heat resistance

overcoming the technical challenges of combining thermal resistance and insolubility in traditional high-performance engineering plastics. This not only reduces the production cost of high-performance polymers but also enables their solution processing. Their glass transition temperatures range from 250 ℃ to 388 ℃

with the onset temperature of 5% thermal weight loss exceeding 500 ℃. They are soluble in organic solvents such as

-methylpyrrolidone

-dimethylacetamide and chloroform. They exhibit outstanding comprehensive performance

particularly in maintaining excellent properties at high temperatures. It is widely applied in high-tech fields such as aerospace

nuclear energy

electronics

and electrical engineering

as well as in numerous sectors of the national economy.

关键词

Keywords

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