高透光率咔唑类聚合物空穴传输材料用于反式钙钛矿太阳能电池

何瑾; 张春雷; 孙祥浪; 朱宗龙; 李楠; 李忠安

doi:10.11777/j.issn1000-3304.2025.25299

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高透光率咔唑类聚合物空穴传输材料用于反式钙钛矿太阳能电池

研究论文 | 更新时间：2026-01-14

- 高透光率咔唑类聚合物空穴传输材料用于反式钙钛矿太阳能电池
- Highly Transparent Carbazole-based Polymer Hole Transporting Materials for Inverted Perovskite Solar Cells
- 高分子学报 2026年页码：1-13
- 作者机构：
  
  1.(1.华中科技大学化学与化工学院武汉 430074) (香港城市大学
  2.香港城市大学化学系香港 999077
  3.香港城市大学材料科学与工程系香港 999077
  4.深圳华中科技大学研究院深圳 518063
- 作者简介：
  
  E-mail: nanli75@cityu.edu.hk
  lizha@hust.edu.cn
- 基金信息：
  
  国家重点研发计划(2023YFE0210900);深圳市科技计划基础研究项目(JCYJ20230807143608019;JCYJ20230807115000002);国家自然科学基金(基金号 52403249);湖北省自然科学基金创新群体项目(2024AFA012)
- DOI：10.11777/j.issn1000-3304.2025.25299
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7544
- 收稿：2025-11-10，
  
  录用：2025-12-18，
  
  网络出版：2026-01-14，
- 稿件说明：
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何瑾, 张春雷, 孙祥浪, 朱宗龙, 李楠, 李忠安. 高透光率咔唑类聚合物空穴传输材料用于反式钙钛矿太阳能电池. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25299.

He, J.; Zhang, C. L.; Sun, X. L.; Zhu, Z. L.; Li, N.; Li, Z. A. Highly transparent carbazole-based polymer hole transporting materials for inverted perovskite solar cells. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2025.25299.
何瑾, 张春雷, 孙祥浪, 朱宗龙, 李楠, 李忠安. 高透光率咔唑类聚合物空穴传输材料用于反式钙钛矿太阳能电池. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25299. DOI： CSTR： 32057.14.GFZXB.2025.7544.

He, J.; Zhang, C. L.; Sun, X. L.; Zhu, Z. L.; Li, N.; Li, Z. A. Highly transparent carbazole-based polymer hole transporting materials for inverted perovskite solar cells. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2025.25299. DOI： CSTR： 32057.14.GFZXB.2025.7544.

摘要

针对反式钙钛矿太阳能电池中聚合物空穴传输层存在的寄生吸收问题，以咔唑与3

3″-苯并[

]

环戊[

]

吲哚取代的对三联苯为共聚单元，设计并合成了一类新型高透光率聚合物空穴传输材料(HTMs)，即PBN-3

6-Cz和PBN-2

7-Cz. 2种聚合物HTMs均具有合适的能级水平和空穴迁移率，且在350~450 nm范围内的平均透过率超过94%，显著高于对比材料PTAA (82.3%)，有效降低了界面寄生吸收引起的光损失. 此外，通过调控咔唑的连接位点，实现了对聚合物电荷传输性能及钙钛矿薄膜结晶行为的调控. 基于PBN-2

7-Cz的反式钙钛矿电池实现了18.21%的能量转换效率和24.33 mA·cm

-2

的短路电流密度，均优于对比PTAA的器件(18.07%，24.03 mA·cm

-2

Abstract

In this study

a new class of highly transparent hole transporting materials (HTMs)

namely PBN-3

6-Cz and PBN-2

7-Cz

were been designed and synthesized by copolymerizing carbazole with 3

3″-benzo[

]

-cyclopenta[

]

indole-substituted

-terphenyl units. This molecular design aimed to mitigate parasitic absorption in the hole transport layer of inverted perovskite solar cells (PSCs). Both polymer HTMs exhibited appropriate energy levels and high hole mobility

while achieving optical average transmittance values exceeding 94% in the 350-450 nm range

significantly higher than that of the reference PTAA (82.3%). This high transparency effectively minimized the optical losses from i

nterfacial parasitic absorption. By tailoring the substitution sites of the carbazole units

we further regulated the charge transport properties of the polymers and the crystallization behavior of the perovskite films. As a result

the inverted PSCs based on PBN-2

7-Cz achieved a power conversion efficiency of 18.21% and a short-circuit current density of 24.33 mA·cm

-2

surpassing the performance of the reference PTAA-based devices (18.07% and 24.03 mA·cm

-2

关键词

Keywords

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