离子液体在纤维素中的应用研究新进展

尹春春; 宋广杰; 田卫国; 张晓程; 张金明; 张军

doi:10.11777/j.issn1000-3304.2025.25300

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离子液体在纤维素中的应用研究新进展

专论 | 更新时间：2026-01-16

- 离子液体在纤维素中的应用研究新进展
- New Advances in the Application of Ionic Liquids in Cellulose
- 高分子学报 2026年57卷第1期页码：23-46
- 作者机构：
  
  1.中国科学院化学研究所工程塑料重点实验室北京 100190
  2.中国科学院大学化学科学学院北京 100049
- 作者简介：
  
  [ "张军，男，1969年生. 中国科学院化学研究所研究员，中国科学院大学岗位教授，中国科学院工程塑料重点实验室主任. 1993年，安徽师范大学化学系大学本科，1996年，哈尔滨工程大学应用化学系硕士(导师：赵书兰教授)，1999年，大连理工大学高分子材料系博士(导师：蹇锡高教授). 2014年获国家杰出青年基金资助，2015年山东省泰山产业领军人才. 获2013年度北京市科学技术一等奖和2009年度北京市科学技术二等奖.目前担任中国纤维素行业协会(CCIA)技术委员会主任，中国化学会纤维素专业委员会副主任，《纤维素科学与技术》副主编，《Polymer International》《Journal of Bioresources and Bioproducts》《高分子学报》和《科学通报》等期刊编委. 主要研究兴趣包括：天然高分子的加工与功能化的新原理和新方法；纤维素化学与物理；离子液体在高分子材料中的应用；非粮生物质的高值化利用；含棉废旧纺织物的循环利用；功能化纤维素纤维等." ]
- 基金信息：
  
  国家自然科学基金(基金号 ┣W2511049;52273099;52573239;U2004211);52173292┫;国家重点研发计划(2020YFC1910303)
- DOI：10.11777/j.issn1000-3304.2025.25300
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7533
- 收稿：2025-11-13，
  
  录用：2025-12-11，
  
  网络出版：2026-01-07，
  
  纸质出版：2026-01-20
- 稿件说明：
移动端阅览
尹春春, 宋广杰, 田卫国, 张晓程, 张金明, 张军. 离子液体在纤维素中的应用研究新进展. 高分子学报, 2026, 57(1), 23-46.

Yin, C. C.; Song, G. J.; Tian, W. G.; Zhang, X. C.; Zhang, J. M.; Zhang, J. New advances in the application of ionic liquids in cellulose. Acta Polymerica Sinica (in Chinese), 2026, 57(1), 23-46.
尹春春, 宋广杰, 田卫国, 张晓程, 张金明, 张军. 离子液体在纤维素中的应用研究新进展. 高分子学报, 2026, 57(1), 23-46. DOI： 10.11777/j.issn1000-3304.2025.25300. CSTR： 32057.14.GFZXB.2025.7533.

Yin, C. C.; Song, G. J.; Tian, W. G.; Zhang, X. C.; Zhang, J. M.; Zhang, J. New advances in the application of ionic liquids in cellulose. Acta Polymerica Sinica (in Chinese), 2026, 57(1), 23-46. DOI： 10.11777/j.issn1000-3304.2025.25300. CSTR： 32057.14.GFZXB.2025.7533.

摘要

在国家双碳目标战略和高分子材料可持续发展的大背景下，以纤维素为代表的非粮生物质材料被认为是未来化学化工、生物基材料和生物质能源的主要原料，发展前景广阔. 由于自身聚集态结构的特点，天然纤维素不熔化、难溶解，传统的纤维素加工和衍生化工艺复杂、且污染严重，极大地限制了纤维素材料的广泛应用. 通过开发有效的纤维素溶剂，实现天然纤维素的高效转化、绿色加工和功能化，是纤维素高值化利用的重要途径. 纤维素新溶剂的开发一直是纤维素科学领域最活跃的研究内容之一，而离子液体溶剂作为一类新型、高效的纤维素溶剂体系的发现，为纤维素科学的基础研究，以及加工和衍生化反应研究提供一个高效、绿色、平台型新方法，基于离子液体的纤维素科学基础研究、纤维素加工方法以及纤维素衍生化反应等诸多领域取得重要研究进展，为纤维素这一“古老”的材料带来了勃勃生机. 近年来，离子液体在纤维素材料中的应用研究更加深入和广泛，本专论将介绍我们团队在过去几年间取得的相关研究成果，主要包括纤维素在离子液体及其共溶剂中的溶解和溶液行为、纤维素结晶、低成本纤维素原料的加工以及功能化纤维素材料创制等方面的研究进展.

Abstract

Under the background of the national dual-carbon goal strategy and the sustainable development of polymers

non-food biomass materials represented by cellulose are considered the primary raw materials for the future chemical industry

bio-based materials

and biomass energy. Due to the characteristics of its supramolecular structure

natural cellulose does not melt and is difficult to dissolve. Traditional cellulose processing and derivatization processes are often complex and highly polluting

significantly limiting the widespread application of cellulose materials. Developing effective solvents for cellulose to achieve efficient conversion

green processing

and functionalization of natural cellulose is an important pathway for the high-value utilization of cellulose. The development of new cellulose solvents has always been one of the most active research topics in the field of cellulose science. The discovery of ionic liquids as a novel and efficient cellulose solvent system has provided a highly efficient

green

and platform-based new method for fundamental research on cellulose science

as well as for processing and derivatization. Significant progress has been made in various areas

bringing renewed vitality to this "ancient" material. In recent years

research on the application of ionic liquids in cellulose materials has become more in-depth and extensive. This feature article briefly summarizes the related research achievements of our group over the past few years

including progress in the dissolution and solution behavior of cellulose in ionic liquids and their co-solvents

cellulose crystallization

processing of low-cost cellulose raw materials

and the fabrication of new functional cellulose materials.

关键词

Keywords

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