聚苯乙烯/聚苯醚/聚丙烯共混物的形态调控及其超临界CO2发泡性能研究
Studies on Morphology Control of Polystyrene/Polyphenylene Ether/ Polypropylene Blends and Their Supercritical CO2 Foaming Performance
- 高分子学报 2026年 页码：1-9
- 作者机构：
1.江南大学化学与材料工程学院 无锡 214122
2.无锡会通轻质材料股份有限公司 无锡 214101
- 作者简介：
E-mail: mqchen@jiangnan.edu.cn
- 基金信息：
DOI：10.11777/j.issn1000-3304.2026.25307
中图分类号：- CSTR：32057.14.GFZXB.2026.7559
收稿：2025-11-22，
录用：2026-01-26，
网络首发：2026-03-24，
- 稿件说明：
移动端阅览
曾佳, 何家欢, 齐力伟, 刘缓缓, 吴加俊, 朱民, 倪忠斌, 施冬健, 陈明清. 聚苯乙烯/聚苯醚/聚丙烯共混物的形态调控及其超临界CO2发泡性能研究. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.25307.
Zeng, J.; He, J. H.; Qi, L. W.; Liu, H. H.; Wu, J. J.; Zhu, M.; Ni, Z. B.; Shi, D. J.; Chen, M. Q. Studies on morphology control of polystyrene/polyphenylene ether/polypropylene blends and their supercritical CO2 foaming performance. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.25307.
曾佳, 何家欢, 齐力伟, 刘缓缓, 吴加俊, 朱民, 倪忠斌, 施冬健, 陈明清. 聚苯乙烯/聚苯醚/聚丙烯共混物的形态调控及其超临界CO2发泡性能研究. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.25307. DOI： CSTR： 32057.14.GFZXB.2026.7559.
Zeng, J.; He, J. H.; Qi, L. W.; Liu, H. H.; Wu, J. J.; Zhu, M.; Ni, Z. B.; Shi, D. J.; Chen, M. Q. Studies on morphology control of polystyrene/polyphenylene ether/polypropylene blends and their supercritical CO2 foaming performance. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.25307. DOI： CSTR： 32057.14.GFZXB.2026.7559.
摘要
在国家双碳与轻量化战略推动下，聚苯乙烯/聚苯醚(PS/PPO)共混体系因其轻质和高性能特性成为发泡材料研究热点，但由于PS/PPO分子链刚性强，在发泡过程中熔体黏度大、流动性差，导致发泡剂在PS/PPO熔体中难以均匀分散，影响发泡效果. 本工作通过熔融共混法在PS/PPO中引入聚丙烯(PP)，研究了不同PP含量下，PP在PS/PPO共混材料中的分布情况及共混体系流变性能，并结合超临界CO
2
釜式发泡技术，对PS/PPO/PP共混材料进行发泡. 通过扫描电镜观察了发泡颗粒内部的泡孔结构、泡孔密度及发泡倍率. 流变测试结果表明，PP加入基体后，改变了基体低频时的储能模量和复数黏度. 同时不同含量的PP在基体中的分散结构显著影响了PS/PPO共混材料中PP的结晶状态及发泡效果. 当PP用量为15%时，泡孔孔径最小为38 μm，泡孔密度最高为3.6×10
7
个/cm
3
，发泡倍率达7.6倍. 本工作构建的柔性-刚性两相复合结构提升了材料的发泡稳定性，为高性能工程塑料发泡提供了新途径.
Abstract
With the development of the national dual-carbon and lightweight strategy
polystyrene/polypropylene (PS/PPO) blend systems have become a research hotspot for foamed materials owing to their lightweight and high performance. However
owing to the strong rigidity of the PS/PPO molecular chains
PS/PPO has a high melt viscosity and poor fluidity during the foaming process
making it difficult to disperse the foaming agent uniformly in the PS/PPO melt
which affects the foaming effect. To address these problems and the challenges
of single-phase foaming of high-performance engineering plastics
a phase design for co-mingled foaming systems was employed. This approach optimizes the cell structure from a single phase to a composite structure of flexible and rigid immiscible phases
thereby enhancing the foaming performance of the material. Polystyrene/polyphenylene ether/polypropylene (PS/PPO/PP) blends were prepared using a melt blending method
and the distribution and rheological properties of PP in PS/PPO blends with different PP contents were studied. Using supercritical CO
2
as the foaming agent
the PS/PPO/PP blend was foamed by batch kettle foaming
and the cell structure
cell density
and foaming rate of the foamed particles were observed using scanning electron microscopy. The results show that the storage modulus and complex viscosity of the substrate at low frequencies changed when PP was added to the matrix. Simultaneously
the dispersion structure of PP with different contents in the matrix significantly affected the crystallization state and foaming effect of the PP/PPO blend and improved the foaming performance of the PS/PPO blend. When the amount of PP was 15%
the minimum pore size was 38 μm
the highest cell density was 3.6×10
7
cells/cm
3
and the foaming ratio was 7.6 times. This study constructs a flexible-rigid two-phase composite to enhance the foaming stability of the material
providing a new approach for foaming high-performance engineering plastics.
关键词
Keywords
references
Martini J. ; Waldman F. ; Suh N. P. The production and analysis of microcellular thermoplastic foams . Annual Conference-Society of Plastics Engineers , 1982 , 28 , 674 - 676 .
江俊杰 , 刘华文 , 田方伟 , 陈哔炽 , 翟文涛 . 聚合物发泡与多孔功能材料的研究与应用进展 . 科学通报 , 2024 , 69 ( 20 ), 2964 - 2977 . doi: 10.1360/TB-2024-0190 http://dx.doi.org/10.1360/TB-2024-0190
Zhai W. T. ; Jiang J. J. ; Park C. B. A review on physical foaming of thermoplastic and vulcanized elastomers . Polym. Rev. , 2022 , 62 ( 1 ), 95 - 141 . doi: 10.1080/15583724.2021.1897996 http://dx.doi.org/10.1080/15583724.2021.1897996
Xu Z. M. ; Jiang X. L. ; Liu T. ; Hu G. H. ; Zhao L. ; Zhu Z. N. ; Yuan W. K. Foaming of polypropylene with supercritical carbon dioxide . J. Supercrit. Fluids , 2007 , 41 ( 2 ), 299 - 310 . doi: 10.1016/j.supflu.2006.09.007 http://dx.doi.org/10.1016/j.supflu.2006.09.007
Yan H. K. ; Sheng H. N. ; Hua H. W. ; Zhang L. ; Yao Y. Y. ; Bao J. B. Effects of poly(propylene carbonate) on poly(butylene adipate- co -terephthalate) microcellular foams: improved expansion and reduced shrinkage . Polym. Eng. Sci. , 2025 , 65 ( 3 ), 1462 - 1473 . doi: 10.1002/pen.27101 http://dx.doi.org/10.1002/pen.27101
Jiang J. J. ; Tian F. W. ; Zhou M. N. ; Li M. Y. ; Xiong Z. J. ; Gao N. ; Liu H. W. ; Zhai W. T. Fabrication of lightweight polyphenylene oxide/high-impact polystyrene composite bead foam parts via in-mold foaming and molding technology . Adv. Eng. Mater. , 2022 , 24 ( 3 ), 2101100 . doi: 10.1002/adem.202101100 http://dx.doi.org/10.1002/adem.202101100
Li Z. L. ; Tang Y. J. ; Wang Y. Q. ; Wang X. D. ; Chen S. H. Ultrahigh compressive strength and heat resistance of polystyrene/polyphenylene oxide foams of supercritical carbon dioxide foaming . J. Appl. Polym. Sci. , 2024 , 141 ( 9 ), e 55014 . doi: 10.1002/app.55014 http://dx.doi.org/10.1002/app.55014
Tang W. H. ; Guo X. J. ; Li D. P. ; Zhu E. W. ; Yuan H. L. Simultaneous toughening of PPO/HIPS/glass fiber reinforced composites with thermoplastic rubbers . J. Appl. Polym. Sci. , 2014 , 131 ( 11 ), app . 40299 . doi: 10.1002/app.40299 http://dx.doi.org/10.1002/app.40299
Guo J. M. ; Huang H. M. Application of polybutene in modified polyphenylene ether . China Plast Indust. , 2009 , 37 ( S1 ), 7 - 9 .
吴加俊 , 曾佳 , 刘缓缓 , 朱明 , 叶明 , 郑广通 , 倪忠斌 , 陈明清 . 釜式发泡制备ABS/PTFE珠粒及成型研究 . 塑料工业 , 2023 , 51 ( 01 ), 80 - 84+162 .
Xiao P. ; Xiao M. ; Gong K. C. Preparation of exfoliated graphite/polystyrene composite by polymerization-filling technique . Polymer , 2001 , 42 ( 11 ), 4813 - 4816 . doi: 10.1016/s0032-3861(00)00819-3 http://dx.doi.org/10.1016/s0032-3861(00)00819-3
Jiang X. L. ; Zhao L. ; Feng L. F. ; Chen C. P. Microcellular thermoplastic polyurethanes and their flexible properties prepared by mold foaming process with supercritical CO 2 . J. Cell. Plast. , 2019 , 55 ( 6 ), 615 - 631 . doi: 10.1177/0021955x19864392 http://dx.doi.org/10.1177/0021955x19864392
Liu H. M. ; Wang X. D. ; Liu C. T. ; Mi H. Y. ; Wang Y. Q. ; Chen S. H. Green strategy based on supercritical-fluid foaming for fabricating rigid microcellular thermoplastic polyimide foams with ultrahigh compressive strength . Compos. Part B Eng. , 2024 , 273 , 111204 . doi: 10.1016/j.compositesb.2024.111204 http://dx.doi.org/10.1016/j.compositesb.2024.111204
翟文涛 , 江俊杰 . 热塑弹性体超临界流体间歇发泡过程中的基本问题 . 高分子学报 , 2024 , 55 ( 4 ), 369 - 395 .
吴佳杰 , 郭巍 . PP/PE-HD共混物的结晶行为和发泡性能 . 工程塑料应用 , 2022 , 50 ( 08 ), 1 - 6 . doi: 10.3969/j.issn.1001-3539.2022.08.001 http://dx.doi.org/10.3969/j.issn.1001-3539.2022.08.001
Jiang Y. X. ; Wu J. J. ; Leng J. ; Cardon L. ; Zhang J. Reinforced and toughened PP/PS composites prepared by Fused Filament Fabrication (FFF) with in-situ microfibril and shish-kebab structure . Polymer , 2020 , 186 , 121971 . doi: 10.1016/j.polymer.2019.121971 http://dx.doi.org/10.1016/j.polymer.2019.121971
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