茂金属聚<italic style="font-style: italic">α</italic>-烯烃构效关系：从聚合催化剂结构到润滑油基础油物性

秦宇飞; 许健; 李玉莲; 刘琳; 刘欣悦; 边宇飞; 李久盛; 于佩潜; 丛蓉娟; 陈林枫; 俞越

doi:10.11777/j.issn1000-3304.2026.25329

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茂金属聚α-烯烃构效关系：从聚合催化剂结构到润滑油基础油物性

综述 | 更新时间：2026-04-23

- 茂金属聚α-烯烃构效关系：从聚合催化剂结构到润滑油基础油物性
- Structure-Property Relationships of Metallocene Polyalphaolefin: From the Molecular Structure of Catalysts to the Performance of Base Oils
- 高分子学报 2026年页码：1-17
- 作者机构：
  
  1.国家能源集团北京低碳清洁能源研究院北京 102211
  2.中国科学院上海高等研究院先进润滑材料实验室上海 201210
- 作者简介：
  
  [ "李久盛，男，1974年生，研究员/博导，享受国务院政府特殊津贴专家. 2002年毕业于上海交通大学，获材料学博士学位. 2002年~2012年于中国石油兰州润滑油研发中心工作，2012 年加入中国科学院上海高等研究院，主持建设“先进润滑材料实验室”，现任党委委员/院务委员、学术委员会副主任兼绿色化学工程技术中心主任. 主要从事高端润滑材料如合成基础油、添加剂及配方的研究，承担科技部、JKW、中科院战略先导和企业重大课题等30多项，发表SCI论文100多篇，申请专利60余项，授权30项. 先后获得江西省自然科学奖、河南省科技进步奖和山西省专利奖等，入选中科院优秀共产党员、上海市东方英才领军和浦东明珠计划领军等. 担任《摩擦学学报》、《Lubricants》期刊编委，中国表面工程协会常务理事、润滑与防锈分会副理事长，摩擦学分会理事，全国减速机标准化委员会委员、CSTM-FC98科学试验领域标委会委员等." ]
  [ "俞越，男，1986年生，高级工程师，中国青年科技工作者协会会员，北京低碳清洁能源研究院烯烃聚合催化专业首席专家、烯烃聚合催化剂研发部经理(兼). 2008年于华南理工大学获高分子材料与工程学士学位，2011年于浙江大学获化学(高分子化学与物理)硕士学位，2015年于意大利那不勒斯费德里克二世大学获化学博士学位. 2016年~2019年于法国里昂C2P2实验室(现CP2M实验室)从事博士后研究. 2020年加入国家能源集团北京低碳清洁能源研究院，核心参与筹建煤基烯烃聚合技术研发团队，并从事相关技术开发和科学研究. 其从事聚烯烃相关研究近20年，在Angew. Chem. Int. Edit.、ACS Catal.、J. Am. Chem. Soc.、Macromol. React. Eng.、Sep. Purif. Technol.、Anal. Chem.、J. Chromatogr. A等期刊发表中英文论文20余篇，撰写书籍章节1篇，申请专利近40件，已授权中国专利2件、PCT专利1件，已发布团体标准1项. 2024年获评国家能源集团“十大杰出青年”. 担任复旦大学高分子科学系行业导师、《化学反应工程与工艺》期刊青年编委." ]
- 基金信息：
  
  国家能源集团科技创新项目(GJNY-24-49)
- DOI：10.11777/j.issn1000-3304.2026.25329
  中图分类号：
- CSTR：32057.14.GFZXB.2026.7578
- 收稿：2026-02-01，
  
  录用：2026-03-13，
  
  网络首发：2026-04-22，
- 稿件说明：
移动端阅览
秦宇飞, 许健, 李玉莲, 刘琳, 刘欣悦, 边宇飞, 李久盛, 于佩潜, 丛蓉娟, 陈林枫, 俞越. 茂金属聚α-烯烃构效关系：从聚合催化剂结构到润滑油基础油物性. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.25329.

Qin, Y. F.; Xu, J.; Li, Y. L.; Liu, L.; Liu, X. Y.; Bian, Y. F.; Li, J. S.; Yu, P. Q.; Cong, R. J.; Chen, L. F.; Yu, Y. Structure-property relationships of metallocene polyalphaolefin: from the molecular structure of catalysts to the performance of base oils. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.25329.
秦宇飞, 许健, 李玉莲, 刘琳, 刘欣悦, 边宇飞, 李久盛, 于佩潜, 丛蓉娟, 陈林枫, 俞越. 茂金属聚α-烯烃构效关系：从聚合催化剂结构到润滑油基础油物性. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.25329. DOI： CSTR： 32057.14.GFZXB.2026.7578.

Qin, Y. F.; Xu, J.; Li, Y. L.; Liu, L.; Liu, X. Y.; Bian, Y. F.; Li, J. S.; Yu, P. Q.; Cong, R. J.; Chen, L. F.; Yu, Y. Structure-property relationships of metallocene polyalphaolefin: from the molecular structure of catalysts to the performance of base oils. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.25329. DOI： CSTR： 32057.14.GFZXB.2026.7578.

摘要

本综述介绍了茂金属催化剂的分子结构对茂金属聚

-烯烃(mPAO)合成基础油分子结构(立构规整性、区域规整性、分子量等)的调控机制，并归纳了mPAO基础油分子结构与其性能间的内在联系. 重点阐述了支链长度、支链数量、分子量及立体化学属性等关键结构参数对mPAO的黏度、黏度指数、倾点、结晶性、剪切稳定性及摩擦性能的影响规律. 对mPAO构效关系的理解不仅有助于完善润滑油领域的基础理论体系，更为高性能润滑油产品的设计与开发提供了重要的理论依据和支撑.

Abstract

This review comprehensively investigates how the molecular structures of metallocene catalysts govern the molecular structures of polyalphaolefins (PAOs)

focusing on stereoregularity

regioregularity

and molecular weight. It also elucidates the critical relationship between PAO molecular structures and their performance properties. Specifically

it analyzes how key molecular parameters—including branch length

branch number

molecular weight

and stereochemistry—influence essential performance of base oil such as viscosity

viscosity index

pour point

crystallizability

shear stability

and tribological behavior. By synthesizing these structure-property-performance relationships

this article establishes a systematic framework for understanding the mPAO-based lubricants and serves as a foundational reference for developing high-performance mPAO-based lubricants.

关键词

Keywords

references

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DOI：10.11777/j.issn1000-3304.2026.25329

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