新型<italic style="font-style: italic">β</italic>-酮亚胺钛配合物异构体的合成及催化乙烯聚合性能

王蝶; 周明; 雷禄; 李哲; 唐万军; 谢光勇; 李琳

doi:10.11777/j.issn1000-3304.2026.26007

您当前的位置：

首页 >

文章列表页 >

新型β-酮亚胺钛配合物异构体的合成及催化乙烯聚合性能

研究论文 | 更新时间：2026-05-06

- 新型β-酮亚胺钛配合物异构体的合成及催化乙烯聚合性能
- Synthesis of a Kind of Novel β-Ketoimine Titanium Complex Isomers and Their Catalytic Performance for Ethylene Polymerization
- 高分子学报 2026年页码：1-13
- 作者机构：
  
  1.中南民族大学化学与材料科学学院武汉 430074
  2.百色学院化学与环境工程学院百色 533000
- 作者简介：
  
  E-mail: xiegy@scuec.edu.cn
  lilinchem@mail.scuec.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 21172269)
- DOI：10.11777/j.issn1000-3304.2026.26007
  中图分类号：
- CSTR：32057.14.GFZXB.2026.7570
- 收稿：2026-01-11，
  
  录用：2026-03-02，
  
  网络首发：2026-05-06，
- 稿件说明：
移动端阅览
王蝶, 周明, 雷禄, 李哲, 唐万军, 谢光勇, 李琳. 新型β-酮亚胺钛配合物异构体的合成及催化乙烯聚合性能. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26007.

Wang, D.; Zhou, M.; Lei, L.; Li, Z.; Tang, W. J.; Xie, G. Y.; Li, L. Synthesis of a kind of novel β-ketoimine titanium complex isomers and their catalytic performance for ethylene polymerization. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26007.
王蝶, 周明, 雷禄, 李哲, 唐万军, 谢光勇, 李琳. 新型β-酮亚胺钛配合物异构体的合成及催化乙烯聚合性能. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26007. DOI： CSTR： 32057.14.GFZXB.2026.7570.

Wang, D.; Zhou, M.; Lei, L.; Li, Z.; Tang, W. J.; Xie, G. Y.; Li, L. Synthesis of a kind of novel β-ketoimine titanium complex isomers and their catalytic performance for ethylene polymerization. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26007. DOI： CSTR： 32057.14.GFZXB.2026.7570.

摘要

合成了2对含羟基的不对称

-酮亚胺异构体及相应的三齿钛配合物异构体

Ti1

Ti2

和

Ti3

Ti4

，通过傅里叶红外光谱(FTIR)、核磁共振氢谱(

H-NMR)、核磁共振碳谱(

C-NMR)、元素分析以及单晶X射线衍射(XRD)等表征证实了异构的配体和配合物的结构. 在助催化剂甲基铝氧烷(MAO)作用下，2对钛配合物异构体均能高活性地催化乙烯聚合以及乙烯与

-烯烃共聚. 边臂靠近主链上苯基的配合物

Ti2

和

Ti4

催化乙烯(共)聚合的活性均明显高于边臂靠近羟基苯的对应异构体

Ti1

和

Ti3

的活性. 在催化乙烯聚合时，具有甲硫基苯胺边臂的配合物

Ti4

的活性最高，是它的异构体

Ti3

的3倍，是类似结构的含甲硫基乙胺边臂的配合物

Ti2

以及不含羟基的对照钛配合物

Ti5

的2倍以上；此外，

Ti4

还具有极高的热稳定性，在1.0 MPa的乙烯压力和100 ℃高温下仍保持10

g·mol

-1

·h

-1

以上的极高活性，并且在120 ℃时仍具有较高活性. 在乙烯与

-烯烃(1-己烯、1-辛烯)共聚中，含甲硫基苯胺边臂的配合物

Ti3

和

Ti4

的共聚活性及共聚单体插入率均显著高于甲硫基乙胺边臂的配合物

Ti1

和

Ti2

，共聚活性均达10

g·mol

-1

·h

-1

以上.

Ti4

表现出最高的乙烯共聚活性，而

Ti3

所得共聚物中共聚单体插入率最高. 采用密度泛函理论(DFT)计算对

-酮亚胺钛配合物进行结构优化，计算结果与配合物催化乙烯(共)聚合活性和配合物热稳定性的趋势一致，配合物

Ti4

只需要克服较少的活化能势垒就能完成链的增长，具有最高的催化活性及最强的热稳定性.

Abstract

Two pairs of asymmetric

-ketoimine isomers containing a hydroxyl group and the corresponding tridentate titanium complex isomers

Ti1

Ti2

and

Ti3

Ti4

were synthesized

and the isomeric ligands and complexes were confirmed by FTIR

H-NMR

C-NMR

elemental analysis

and single-crystal X-ray diffraction (XRD) characterization. Under the action of the cocatalyst MAO

both pairs of titanium complex isomers exhibited high activity for ethylene polymerization and copolymerization with

-olefins. Furthermore

the ethylene (co)polymerization activities of complexes

Ti2

and

Ti4

with the side arm near the phenyl group were significantly higher than those of the corresponding isomers

Ti1

and

Ti3

with the side arm near the hydroxyphenyl group. For ethylene polymerization

the activity of complex

Ti4

with the methioaniline side arm was the highest

which was three times that of its isomer

Ti3

and more than twice that of the similar structural complex

Ti2

with the methioethylamine side arm and the control titanium complex

Ti5

without the hydroxyl group. Moreover

Ti4

showed extremely high thermal stability

which can maintain extremely high activity above 10

g·mol

-1

·h

-1

at an ethylene pressure of 1.0 MPa and a high temperature of 100 ℃

and still had high activity at 120 ℃. In the copolymerization of ethylene and

-olefins (1-hexene and 1-octene)

the copolymerization activity and insertion rate of the comonomer catalyzed by the complexes

Ti3

and

Ti4

containing methylaniline side arms were significantly higher than those catalyzed by

Ti1

and

Ti2

with methioethylamine side arms

with a copolymerization activity of over 10

g·mol

-1

·h

-1

Ti4

exhibited the highest copolymerization activity

whereas the comonomer insertion rate obtained using

Ti3

was the highest. The structure optimization of the

-ketoimine titanium complex isomers was calculated using density functional theory (DFT)

and the results were consistent with the trend o

f the ethylene (co)polymerization activity and the thermal stability of the complexes. The complex

Ti4

only required overcoming a relatively small activation energy barrier to complete chain growth

exhibiting the highest catalytic activity and strongest thermal stability.

关键词

Keywords

references

Mahmood Q. ; Hu Z. X. ; Ren G. ; Sun W. H. Recent advances in nickel catalysis for thermoplastic polyethylene elastomers: synthesis strategies, properties, and future perspectives . Coord. Chem. Rev. , 2025 , 541 , 216833 . doi: 10.1016/j.ccr.2025.216833 http://dx.doi.org/10.1016/j.ccr.2025.216833

Chen C. L. Designing catalysts for olefin polymerization and copolymerization: beyond electronic and steric tuning . Nat. Rev. Chem. , 2018 , 2 ( 5 ), 6 - 14 . doi: 10.1038/s41570-018-0003-0 http://dx.doi.org/10.1038/s41570-018-0003-0

Bariashir C. ; Huang C. B. ; Solan G. A. ; Sun W. H. Recent advances in homogeneous chromium catalyst design for ethylene tri-, tetra-, oligo- and polymerization . Coord. Chem. Rev. , 2019 , 385 , 208 - 229 . doi: 10.1016/j.ccr.2019.01.019 http://dx.doi.org/10.1016/j.ccr.2019.01.019

Yuan S. F. ; Yan Y. ; Solan G. A. ; Ma Y. P. ; Sun W. H. Recent advancements in N -ligated group 4 molecular catalysts for the (co)polymerization of ethylene . Coord. Chem. Rev. , 2020 , 411 , 213254 . doi: 10.1016/j.ccr.2020.213254 http://dx.doi.org/10.1016/j.ccr.2020.213254

Makio H. ; Terao H. ; Iwashita A. ; Fujita T. FI catalysts for olefin polymerization: a comprehensive treatment . Chem. Rev. , 2011 , 111 ( 3 ), 2363 - 2449 . doi: 10.1021/cr100294r http://dx.doi.org/10.1021/cr100294r

Redshaw C. ; Tang Y. Tridentate ligands and beyond in group Ⅳ metal α -olefin homo-/ co-polymerization catalysis . Chem. Soc. Rev. , 2012 , 41 ( 12 ), 4484 - 4510 . doi: 10.1039/c2cs35028a http://dx.doi.org/10.1039/c2cs35028a

Antonov A. A. ; Bryliakov K. P. Post-metallocene catalysts for the synthesis of ultrahigh molecular weight polyethylene: recent advances . Eur. Polym. J. , 2021 , 142 , 110162 . doi: 10.1016/j.eurpolymj.2020.110162 http://dx.doi.org/10.1016/j.eurpolymj.2020.110162

Alzamly A. ; Bakiro M. ; Hussein Ahmed S. ; Siddig L. A. ; Nguyen H. L. Linear α -olefin oligomerization and polymerization catalyzed by metal-organic frameworks . Coord. Chem. Rev. , 2022 , 462 , 214522 . doi: 10.1016/j.ccr.2022.214522 http://dx.doi.org/10.1016/j.ccr.2022.214522

Mu H. L. ; Zhou G. L. ; Hu X. Q. ; Jian Z. B. Recent advances in nickel mediated copolymerization of olefin with polar monomers . Coord. Chem. Rev. , 2021 , 435 , 213802 . doi: 10.1016/j.ccr.2021.213802 http://dx.doi.org/10.1016/j.ccr.2021.213802

Ghana P. ; Xiong S. Y. ; Tekpor A. ; Bailey B. C. ; Spinney H. A. ; Henderson B. S. ; Agapie T. Catalyst editing via post-synthetic functionalization by phosphonium generation and anion exchange for nickel-catalyzed ethylene/acrylate copolymerization . J. Am. Chem. Soc. , 2024 , 146 ( 28 ), 18797 - 18803 . doi: 10.1021/jacs.4c03416 http://dx.doi.org/10.1021/jacs.4c03416

Medina J. T. ; Tran Q. H. ; Hughes R. P. ; Wang X. Q. ; Brookhart M. ; Daugulis O. Ethylene polymerizations catalyzed by fluorinated "sandwich" diimine-nickel and palladium complexes . J. Am. Chem. Soc. , 2024 , 146 ( 22 ), 15143 - 15154 . doi: 10.1021/jacs.4c01322 http://dx.doi.org/10.1021/jacs.4c01322

Liu Y. ; Wang C. Q. ; Mu H. L. ; Jian Z. B. Aqueous coordination-insertion copolymerization for producing high molecular weight polar polyolefins . Angew. Chem. Int. Ed. , 2024 , 63 ( 23 ), e 202404392 . doi: 10.1002/anie.202404392 http://dx.doi.org/10.1002/anie.202404392

Goller A. ; Obenauf J. ; Kretschmer W. P. ; Kempe R. The highly controlled and efficient polymerization of ethylene . Angew. Chem. Int. Ed. , 2023 , 62 ( 8 ), e 202216464 . doi: 10.1002/anie.202216464 http://dx.doi.org/10.1002/anie.202216464

Yang J. S. ; Tang Z. X. ; Zhang Y. X. ; Jian Z. B. A facile and scalable α -diimine platform for nickel-catalyzed ethylene polymerization . Angew. Chem. Int. Ed. , 2025 , 64 ( 41 ), e 202512735 . doi: 10.1002/anie.202512735 http://dx.doi.org/10.1002/anie.202512735

Zou C. ; Si G. F. ; Chen C. L. A general strategy for heterogenizing olefin polymerization catalysts and the synthesis of polyolefins and composites . Nat. Commun. , 2022 , 13 , 1954 . doi: 10.1038/s41467-022-29533-9 http://dx.doi.org/10.1038/s41467-022-29533-9

Li J. ; Peng D. ; Tan C. ; Chen C. L. Outer-shell self-supported nickel catalysts for the synthesis of polyolefin composites . Angew. Chem. Int. Ed. , 2023 , 62 ( 18 ), e 202300359 . doi: 10.1002/anie.202300359 http://dx.doi.org/10.1002/anie.202300359

Lin F. ; Voccia M. ; Odenwald L. ; Göttker-Schnetmann I. ; Falivene L. ; Caporaso L. ; Mecking S. Origin of suppressed chain transfer in phosphinephenolato Ni(Ⅱ)-catalyzed ethylene polymerization . J. Am. Chem. Soc. , 2023 , 145 ( 51 ), 27950 - 27957 . doi: 10.1021/jacs.3c06597 http://dx.doi.org/10.1021/jacs.3c06597

Xie G. Y. ; Qian C. T. Dramatic electronic effect of fluoro substituents on the olefin polymerization activity of mono β -diiminato titanium complexes . J. Polym. Sci. A Polym. Chem. , 2008 , 46 ( 1 ), 211 - 217 . doi: 10.1002/pola.22373 http://dx.doi.org/10.1002/pola.22373

Xie G. Y. ; Li Y. X. ; Sun J. ; Qian C. T. Titanium complexes with β -ketoiminate chelate ligands for ethylene polymerization: the significant influence of substituents on structures and catalytic activities . Inorg. Chem. Commun. , 2009 , 12 ( 8 ), 796 - 799 . doi: 10.1016/j.inoche.2009.06.012 http://dx.doi.org/10.1016/j.inoche.2009.06.012

Xie G. Y. ; Li T. C. ; Zhang A. Q. Highly active and selective ethylene oligomerization catalysts: asymmetric 2 , 6 -bis(imino)pyridyl iron (Ⅱ) complexes with alkyl and halogen substitutients. Inorg. Chem. Commun., 2010, 13 ( 10 ), 1199 - 1202 . doi: 10.1016/j.inoche.2010.07.003 http://dx.doi.org/10.1016/j.inoche.2010.07.003

Xie G. Y. ; Zhang X. ; Li T. C. ; Li L. ; Liu G. Y. ; Zhang A. Q. Preparation of linear low-density polyethylene from ethylene by tandem catalysis of iron and titanium non-metallocene catalysts . J. Mol. Catal. A Chem. , 2014 , 383 - 384 , 121 - 127 . doi: 10.1016/j.molcata.2013.11.024 http://dx.doi.org/10.1016/j.molcata.2013.11.024

Xie G. Y. ; Liu G. Y. ; Li L. ; Li T. C. ; Zhang A. Q. ; Feng J. W. Tandem catalysis of iron and titanium non-metallocene catalysts for the production of branched polyethylene . Catal. Commun. , 2014 , 45 , 7 - 10 . doi: 10.1016/j.catcom.2013.10.029 http://dx.doi.org/10.1016/j.catcom.2013.10.029

Qin Y. W. ; Li T. C. ; Chen X. ; Li J. ; Meng X. ; You Q. L. ; Xie G. Y. Asymmetric bis-salicylaldiminato binuclear titanium complexes for ethylene polymerization and copolymerization . New J. Chem. , 2021 , 45 ( 25 ), 11390 - 11398 . doi: 10.1039/d1nj01049b http://dx.doi.org/10.1039/d1nj01049b

Li J. ; Wang L. W. ; Qin Y. W. ; You Q. L. ; Li T. C. ; Sun L. ; Li X. D. ; Xie G. Y. Binuclear titanium complexes coordinated by rigid p -phenylene linked bis- β -carbonylenamine: synthesis, structure, ethylene polymerization and copolymerization with 1,5-hexadiene . Appl. Organomet. Chem. , 2020 , 34 ( 9 ), e 5772 . doi: 10.1002/aoc.5772 http://dx.doi.org/10.1002/aoc.5772

Luo Y. N. ; Li J. ; Luo D. R. ; You Q. L. ; Yang Z. F. ; Li T. C. ; Li X. D. ; Xie G. Y. Methylene-bridged tridentate salicylaldiminato binuclear titanium complexes as copolymerization catalysts for the preparation of LLDPE through [Fe]/[Ti] tandem catalysis . Polymers , 2019 , 11 ( 7 ), 1114 . doi: 10.3390/polym11071114 http://dx.doi.org/10.3390/polym11071114

Chen X. ; Zeng Y. ; Lan Z. ; You Q. L. ; Li T. C. ; Li X. D. ; Zhang D. H. ; Xie G. Y. A Methylene-bridged salicylaldiminato tridentate [ONS] binuclear titanium complex for ethylene-norbornene copolymerization . J. Macromol. Sci. Part A , 2018 , 55 ( 6 ), 489 - 495 . doi: 10.1080/10601325.2018.1470467 http://dx.doi.org/10.1080/10601325.2018.1470467

Luo D. R. ; Zeng Y. ; Chen X. ; Xia P. ; Xie G. Y. ; You Q. L. ; Zhang L. ; Li T. C. ; Li X. D. ; Zhang A. Q. Synthesis, characterization and olefin polymerization behaviors of phenylene-bridged bis- β -carbonylenamine binuclear titanium complexes . RSC Adv. , 2018 , 8 ( 13 ), 6954 - 6964 . doi: 10.1039/c8ra00071a http://dx.doi.org/10.1039/c8ra00071a

Zhang L. ; Chen X. ; Xiao X. ; Luo D. R. ; Zeng Y. ; Li T. C. ; Li X. D. ; Zhang A. Q. ; Xie G. Y. A novel tridentate [ONS] binuclear titanium complex bearing oxo-bridged macrocyclic structure for ethylene polymerization . J. Organomet. Chem. , 2018 , 856 , 50 - 55 . doi: 10.1016/j.jorganchem.2017.12.024 http://dx.doi.org/10.1016/j.jorganchem.2017.12.024

Li T. C. ; Lan Z. ; Xie G. Y. ; Luo D. R. ; Li L. ; Xiong S. F. ; Zhang L. ; Ouyang L. P. ; Zhang A. Q. Binuclear titanium catalysts based on methylene-bridged tridentate salicylaldiminato ligands for ethylene homo- and copolymerization . Catal. Lett. , 2017 , 147 ( 4 ), 996 - 1005 . doi: 10.1007/s10562-017-1985-9 http://dx.doi.org/10.1007/s10562-017-1985-9

Xue M. Y. ; Luo Y. N. ; Ren S. L. ; Li T. C. ; You Q. L. ; Xie G. Y. Phenyl-bridged bis-salicylaldiminato binuclear titanium complexes for ethylene (co)polymerization . J. Polym. Res. , 2022 , 30 ( 1 ), 28 . doi: 10.1007/s10965-022-03410-x http://dx.doi.org/10.1007/s10965-022-03410-x

Xue M. Y. ; Lei L. ; Ren S. L. ; Li T. C. ; You Q. L. ; Xie G. Y. Significant cooperative effects in binuclear titanium complexes based on trifluoromethyl substituted bis- β -carbonylenamine ligands for ethylene (co)polymerization . Polymer , 2023 , 277 , 125995 . doi: 10.1016/j.polymer.2023.125995 http://dx.doi.org/10.1016/j.polymer.2023.125995

Ren S. L. ; Xiao X. ; Huang P. Z. ; Zhou M. ; Li T. C. ; You Q. L. ; Xie G. Y. Synthesis, characterization and ethylene (co)polymerization of binuclear vanadium(Ⅳ) catalysts based on xanthene-bridged bis-salicylaldiminato ligands . Eur. Polym. J. , 2024 , 202 , 112660 . doi: 10.1016/j.eurpolymj.2023.112660 http://dx.doi.org/10.1016/j.eurpolymj.2023.112660

Zhou M. ; Xue M. Y. ; Huang P. Z. ; Li T. C. ; You Q. L. ; Xie G. Y. Design and synthesis of bis- β -ketoimine binuclear titanium complex isomers to probe bimetallic synergistic effect for ethylene polymerization . Chinese J. Polym. Sci. , 2025 , 43 ( 5 ), 756 - 768 . doi: 10.1007/s10118-025-3312-z http://dx.doi.org/10.1007/s10118-025-3312-z

Huang P. Z. ; Tang W. J. ; Xue M. Y. ; Zhou M. ; Tu W. ; Li T. C. ; Xie G. Y. Synthesis, characterization, and catalytic properties of regioisomeric β -ketoimine titanium complexes for ethylene polymerization . Appl. Organomet. Chem. , 2025 , 39 ( 2 ), e 7967 . doi: 10.1002/aoc.7967 http://dx.doi.org/10.1002/aoc.7967

Tu W. ; Tang W. J. ; Xue M. Y. ; Lei L. ; Li T. C. ; Xie G. Y. Synthesis of isomeric bis- β -ketoimine binuclear titanium complexes for ethylene homo- and copolymerization . Polymer , 2025 , 340 , 129244 . doi: 10.1016/j.polymer.2025.129244 http://dx.doi.org/10.1016/j.polymer.2025.129244

杨明萱 , 郭新星 , 陈龙 , 孙俊芬 , 李明远 , 蔡正国 . 基于二胺配体的钛配合物催化乙烯共聚合研究 . 高分子学报 , 2025 , 56 ( 10 ), 1791 - 1800 .

岳静峰 , 胡小强 , 齐佳俊 , 王玉银 , 简忠保 . 电子和空间位阻协同的 α -二亚胺镍催化制备聚乙烯弹性体 . 高分子学报 , 2025 , 56 ( 9 ), 1505 - 1517 .

杨佳豪 , 冯春玉 , 周浩添 , 涂广水 , 郑涵斗 , 高海洋 . 桥连[OSSO]型铪催化4-甲基-1-戊烯等规聚合研究 . 高分子学报 , 2025 , 56 ( 8 ), 1383 - 1391 .

Wang C. ; Ma Z. ; Sun X. L. ; Gao Y. ; Guo Y. H. ; Tang Y. ; Shi L. P. Synthesis and characterization of titanium(Ⅳ) complexes bearing monoanionic [O-NX ] (=OX, S, Se) tridentate ligands and their behaviors in ethylene homo- and copolymerizaton with 1-hexene. Organometallics , 2006 , 25 ( 13 ), 3259 - 3266 . doi: 10.1021/om060062j http://dx.doi.org/10.1021/om060062j

Gao M. L. ; Wang C. ; Sun X. L. ; Qian C. T. ; Ma Z. ; Bu S. Z. ; Tang Y. ; Xie Z. W. Ethylene-norbornene copolymerization by new titanium complexes bearing tridentate ligands. sidearm effects on catalytic activity . Macromol. Rapid Commun. , 2007 , 28 ( 15 ), 1511 - 1516 . doi: 10.1002/marc.200700305 http://dx.doi.org/10.1002/marc.200700305

Yang X. H. ; Liu C. R. ; Wang C. ; Sun X. L. ; Guo Y. H. ; Wang X. K. ; Wang Z. ; Xie Z. W. ; Tang Y. [ O - NS R ] TiCl 3 -ca talyzed copolymerization of ethylene with functionalized olefins . Angew. Chem. , 2009 , 121 ( 43 ), 8243 - 8246 . doi: 10.1002/ange.200903334 http://dx.doi.org/10.1002/ange.200903334

Chen Z. ; Li J. F. ; Tao W. J. ; Sun X. L. ; Yang X. H. ; Tang Y. Copolymerization of ethylene with functionalized olefins by [ONX] titanium complexes . Macromolecules , 2013 , 46 ( 7 ), 2870 - 2875 . doi: 10.1021/ma400283p http://dx.doi.org/10.1021/ma400283p

Li X. F. ; Dai K. ; Ye W. P. ; Pan L. ; Li Y. S. New titanium complexes with two β -enaminoketonato chelate ligands: syntheses , structures, and olefin polymerization activities. Organometallics, 2004 , 23 ( 6 ), 1223 - 1230 . doi: 10.1021/om030396y http://dx.doi.org/10.1021/om030396y

Hong M. ; Liu J. Y. ; Li B. X. ; Li Y. S. Facile functionalization of polyethylene via click chemistry . Macromolecules , 2011 , 44 ( 14 ), 5659 - 5665 . doi: 10.1021/ma2010537 http://dx.doi.org/10.1021/ma2010537

Yang G. F. ; Hong M. ; Li Y. S. ; Yu S. J. Synthesis of novel bis( β -enaminoketonato)titanium catalyst with high activity and excellent ability to copolymerize olefins . Macromol. Chem. Phys. , 2012 , 213 ( 21 ), 2311 - 2318 . doi: 10.1002/macp.201200350 http://dx.doi.org/10.1002/macp.201200350

Wang X. B. ; Lin F. ; Qu J. P. ; Hou Z. M. ; Luo Y. DFT studies on styrene polymerization catalyzed by cationic rare-earth-metal complexes: origin of ligand-dependent activities . Organometallics , 2016 , 35 ( 18 ), 3205 - 3214 . doi: 10.1021/acs.organomet.6b00558 http://dx.doi.org/10.1021/acs.organomet.6b00558

Chan M. S. W. ; Deng L. Q. ; Ziegler T. Density functional study of neutral salicylaldiminato nickel(Ⅱ) complexes as olefin polymerization catalysts . Organometallics , 2000 , 19 ( 14 ), 2741 - 2750 . doi: 10.1021/om000055+ http://dx.doi.org/10.1021/om000055+

Sun L. L. ; Zhang S. F. ; Han Q. Z. ; Zhao Y. H. ; Hao W. Density functional theory study on the mechanism and thermochemistry of olefins addition to nickel dithiolenes . Mol. Simul. , 2011 , 37 ( 10 ), 813 - 823 . doi: 10.1080/08927022.2011.557830 http://dx.doi.org/10.1080/08927022.2011.557830

Zhang H. ; Zhang Z. Y. ; Cai Z. G. ; Li M. Y. ; Liu Z. Influence of silica-supported alkylaluminum on heterogeneous zwitterionic anilinonaphthoquinone nickel and palladium-catalyzed ethylene polymerization and copolymerization with polar monomers . ACS Catal. , 2022 , 12 ( 15 ), 9646 - 9654 . doi: 10.1021/acscatal.2c02705 http://dx.doi.org/10.1021/acscatal.2c02705

浏览量

107

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

基于二胺配体的钛配合物催化乙烯共聚合研究

三苯甲基取代的α-二亚胺镍催化乙烯聚合制备聚烯烃弹性体

电子和空间位阻协同的α-二亚胺镍催化制备聚乙烯弹性体

单一催化剂制备烯烃嵌段共聚物(OBCs)

免疫治疗药物传输材料

新型β-酮亚胺钛配合物异构体的合成及催化乙烯聚合性能

Synthesis of a Kind of Novel β-Ketoimine Titanium Complex Isomers and Their Catalytic Performance for Ethylene Polymerization

DOI：10.11777/j.issn1000-3304.2026.26007

摘要

Abstract

关键词

Keywords

references