西北师范大学化学化工学院 生态功能高分子材料教育部重点实验室 兰州 730070
[ "张亚苹,女,1996年生,西北师范大学化学化工学院讲师,硕士研究生导师. 2024年在西北师范大学获理学博士学位. 已发表论文20余篇,授权国家发明专利3件. 主持甘肃省高校教师创新基金项目、甘肃省优秀博士生项目. 作为骨干成员参与国家自然科学基金2项. 主要研究方向为MOF基高分子智能材料的构建及抗菌机制、光电功能水处理材料和环境功能材料的设计与制备." ]
[ "宋鹏飞,男,1978年生,西北师范大学化学化工学院教授,博士研究生导师. 2001年本科毕业于西北师范大学化学化工学院,2004年在西北师范大学获理学硕士学位,2008年在中山大学获工学博士学位,2011~2012年北京大学访问学者. 2001年至今,在西北师范大学化学化工学院工作. 中国化学会高级会员,甘肃省化学会常务理事,甘肃省材料学会理事,获甘肃省高等学校青年教师成才奖(2020年). 主要从事环境功能高分子材料、可降解高分子材料、含硫高分子材料制备和应用方面的研究工作." ]
收稿:2026-02-21,
录用:2026-03-23,
网络首发:2026-04-22,
移动端阅览
李亭瑶, 孙小娟, 李太宇, 王锴, 张亚苹, 宋鹏飞. 金属有机框架基高分子抗菌材料的合成及应用研究进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26051.
Li, T. Y.; Sun, X. J.; Li, T. Y.; Wang, K.; Zhang, Y. P.; Song, P. F. Research progress on the synthesis and application of metal-organic framework-based polymeric antibacterial materials. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26051.
李亭瑶, 孙小娟, 李太宇, 王锴, 张亚苹, 宋鹏飞. 金属有机框架基高分子抗菌材料的合成及应用研究进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26051. DOI: CSTR: 32057.14.GFZXB.2026.7580.
Li, T. Y.; Sun, X. J.; Li, T. Y.; Wang, K.; Zhang, Y. P.; Song, P. F. Research progress on the synthesis and application of metal-organic framework-based polymeric antibacterial materials. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26051. DOI: CSTR: 32057.14.GFZXB.2026.7580.
金属有机框架材料(MOF)具有高度有序的多孔结构和超大比表面积,在材料领域备受关注. 然而,其在抗菌应用中仍面临结构稳定性不足、生物相容性有限及释放行为难以精准调控等挑战. 将MOF与高分子材料有效结合,不仅可以增强MOF的抗菌性能,而且可改善其加工性能、降低生物毒性. 因而,制备MOF基高分子可有效扩大MOF应用领域. 本文综述了近五年来MOF基高分子抗菌材料在合成、抗菌机制及抗菌应用方面的研究进展,为高性能MOF基抗菌材料的设计与开发提供参考.
Metal-organic frameworks (MOFs) have highly ordered porous structures and ultra-large specific surface areas
attracting extensive attention in materials science. However
challenges remain in their antibacterial applications
such as insufficient structural stability
limited biocompatibility
and difficulty in precisely controlling the release behavior. Integrating MOFs with polymeric materials can enhance their antibacterial performance
improve processability
and reduce biological toxicity. Therefore
the preparation of MOF-based polymers can effectively expand the scope of MOF applications. This paper reviews the research progress on MOF-based polymeric antibacterial materials over the past five years in terms of synthesis strategies
antibacterial mechanisms
and applications
providing a reference for designing and developing high-performance MOF-based antibacterial materials.
Robson R. The historical development of the concepts underlying the design and construction of targeted coordination polymers/MOFs: a personal account . Chem. Rec. , 2024 , 24 ( 5 ), e 202400038 . doi: 10.1002/tcr.202400038 http://dx.doi.org/10.1002/tcr.202400038
Li H. L. ; Eddaoudi M. ; O'Keeffe M. ; Yaghi O. M. Design and synthesis of an exceptionally stable and highly porous metal-organic framework . Nature , 1999 , 402 ( 6759 ), 276 - 279 . doi: 10.1038/46248 http://dx.doi.org/10.1038/46248
Huang Q. Y. ; Chen Y. ; Ye M. ; Zhuang S. Z. ; Zhong A. G. ; Liu J. Q. ; Maduraiveeran G. ; Peng Y. Q. ; Huang Y. Metal-organic framework-based dressings: application and opportunities in wound healing . Mater. Today Chem. , 2024 , 40 , 102235 . doi: 10.1016/j.mtchem.2024.102235 http://dx.doi.org/10.1016/j.mtchem.2024.102235
Jun H. J. ; Yoo D. K. ; Jhung S. H. Metal-organic framework (MOF-808) functionalized with ethyleneamines: selective adsorbent to capture CO 2 under low pressure . J. CO 2 Util. , 2022 , 58 , 101932 . doi: 10.1016/j.jcou.2022.101932 http://dx.doi.org/10.1016/j.jcou.2022.101932
Wang H. ; Pan M. Q. ; Wang Y. F. ; Chen C. ; Xu J. ; Gao Y. Y. ; Qi C. S. ; Li W. ; Bu X. H. Post-synthetic modifications of MOFs by different bolt ligands for controllable release of cargoes . Chinese Chem. Lett. , 2024 , 35 ( 10 ), 109581 . doi: 10.1016/j.cclet.2024.109581 http://dx.doi.org/10.1016/j.cclet.2024.109581
Sastre G. ; Daeyaert F. In AI-Guided Design and Property Prediction for Zeolites and Nanoporous Materials . 1 st Ed . Hoboken : John Wiley & Sons , 2023 , 201 - 232 . doi: 10.1002/9781119819783 http://dx.doi.org/10.1002/9781119819783
Moosavi S. M. ; Nandy A. ; Jablonka K. M. ; Ongari D. ; Janet J. P. ; Boyd P. G. ; Lee Y. ; Smit B. ; Kulik H. J. Understanding the diversity of the metal-organic framework ecosystem . Nat. Commun. , 2020 , 11 ( 1 ), 4068 . doi: 10.1038/s41467-020-17755-8 http://dx.doi.org/10.1038/s41467-020-17755-8
Jones C. W. Metal-organic frameworks and covalent organic frameworks: emerging advances and applications . JACS Au , 2022 , 2 ( 7 ), 1504 - 1505 . doi: 10.1021/jacsau.2c00376 http://dx.doi.org/10.1021/jacsau.2c00376
Moghadam P. Z. ; Li A. ; Wiggin S. B. ; Tao A. D. ; Maloney A. G. P. ; Wood P. A. ; Ward S. C. ; Fairen-Jimenez D. Development of a Cambridge structural database subset: a collection of metal-organic frameworks for past, present, and future . Chem. Mater. , 2017 , 29 ( 7 ), 2618 - 2625 . doi: 10.1021/acs.chemmater.7b00441 http://dx.doi.org/10.1021/acs.chemmater.7b00441
Xie X. J. ; Zhou M. Y. ; Zeng H. ; Lu W. ; Li D. Pore Engineering in metal-organic frameworks for enhanced hydrocarbon adsorption and separation . Acc. Mater. Res. , 2025 , 6 ( 2 ), 195 - 209 . doi: 10.1021/accountsmr.4c00336 http://dx.doi.org/10.1021/accountsmr.4c00336
Wang J. H. ; Kong F. Y. ; Liu B. F. ; Ren N. Q. ; Ren H. Y. Preparation strategies of waste-derived MOF and their applications in water remediation: a systematic review . Coord. Chem. Rev. , 2025 , 533 , 216534 . doi: 10.1016/j.ccr.2025.216534 http://dx.doi.org/10.1016/j.ccr.2025.216534
Achenbach B. ; Yurdusen A. ; Stock N. ; Maurin G. ; Serre C. Synthetic aspects and characterization needs in MOF chemistry-from discovery to applications . Adv. Mater. , 2025 , 37 ( 52 ), 2411359 . doi: 10.1002/adma.202411359 http://dx.doi.org/10.1002/adma.202411359
Li H. Y. ; Wang Z. A. ; Yang M. M. ; Ge B. ; Wang L. P. ; Li G. Polymer decorated Zn-MOF (ZIF-8-NH 2 ) for the fabrication of superhydrophobic material via metal-free atom transfer radical polymerization . Chinese J. Polym. Sci. , 2025 , 43 ( 10 ), 1850 - 1862 . doi: 10.1007/s10118-025-3390-y http://dx.doi.org/10.1007/s10118-025-3390-y
Cai Y. Y. ; Dong T. ; Bian Z. H. ; Liu H. ; Liu X. ; Liu A. H. Metal-organic frameworks based fluorescent sensing: mechanisms and detection applications . Coord. Chem. Rev. , 2025 , 529 , 216470 . doi: 10.1016/j.ccr.2025.216470 http://dx.doi.org/10.1016/j.ccr.2025.216470
Zhu W. J. ; Zhu H. ; Zhang T. Y. ; Qin L. X. ; Kang S. Z. ; Li X. Q. Surface engineering of 2D metal‐porphyrin metal-organic frameworks Z‐scheme heterostructure for boosting and stable photocatalytic hydrogen evolution . Small , 2025 , 21 ( 40 ), 2408806 . doi: 10.1002/smll.202408806 http://dx.doi.org/10.1002/smll.202408806
Rani P. ; Kasneryk V. ; Opanasenko M. MOF-inorganic nanocomposites: bridging a gap with inorganic materials . Appl. Mater. Today , 2022 , 26 , 101283 . doi: 10.1016/j.apmt.2021.101283 http://dx.doi.org/10.1016/j.apmt.2021.101283
Kuang G. L. ; Wang Z. C. ; Bilal M. ; Wang Z. Y. ; Feng Y. X. ; Du Y. J. ; Cui J. D. Metal‐organic frameworks: a potential platform from enzyme immobilization to mimetic enzyme . Aggregate , 2025 , 6 ( 3 ), e 724 . doi: 10.1002/agt2.724 http://dx.doi.org/10.1002/agt2.724
Stanley P. M. ; Haimerl J. ; Shustova N. B. ; Fischer R. A. ; Warnan J. Merging molecular catalysts and metal-organic frameworks for photocatalytic fuel production . Nat. Chem. , 2022 , 14 ( 12 ), 1342 - 1356 . doi: 10.1038/s41557-022-01093-x http://dx.doi.org/10.1038/s41557-022-01093-x
Wang F. X. ; Zhang Z. C. ; Wang C. C. Selective oxidation of aqueous organic pollutants over MOFs-based catalysts: a mini review . Chem. Eng. J. , 2023 , 459 , 141538 . doi: 10.1016/j.cej.2023.141538 http://dx.doi.org/10.1016/j.cej.2023.141538
Cai D. M. ; Yang Z. X. ; Tong R. ; Huang H. M. ; Zhang C. K. ; Xia Y. D. Binder‐free MOF‐based and MOF‐derived nanoarrays for flexible electrochemical energy storage: progress and perspectives . Small , 2024 , 20 ( 12 ), 2305778 . doi: 10.1002/smll.202305778 http://dx.doi.org/10.1002/smll.202305778
周存银 , 黄娟 , 王琼 , 唐浩 , 胡云楚 , 王文磊 . MOFs基光电化学传感界面及其应用 . 化学进展 , 2024 , 36 ( 6 ), 893 - 903 .
Wang W. ; Li P. F. ; Xie R. ; Ju X. J. ; Liu Z. ; Chu L. Y. Designable micro‐/nano‐structured smart polymeric materials . Adv. Mater. , 2022 , 34 ( 46 ), 2107877 . doi: 10.1002/adma.202107877 http://dx.doi.org/10.1002/adma.202107877
Guo H. X. ; Ding Y. T. ; Lu X. R. ; Li L. W. ; Kuang T. R. Precisely anchored amphiphilic metal-organic frameworks at polymer interfaces for robust biodegradable blends . Chem. Mater. , 2025 , 37 ( 18 ), 7398 - 7409 . doi: 10.1021/acs.chemmater.5c01768 http://dx.doi.org/10.1021/acs.chemmater.5c01768
Liu X. G. ; Zhang Y. ; Guo X. T. ; Pang H. Electrospun metal-organic framework nanofiber membranes for energy storage and environmental protection . Adv. Fiber Mater. , 2022 , 4 ( 6 ), 1463 - 1485 . doi: 10.1007/s42765-022-00214-y http://dx.doi.org/10.1007/s42765-022-00214-y
Lee J. ; Lee J. ; Kim J. Y. ; Kim M. Covalent connections between metal-organic frameworks and polymers including covalent organic frameworks . Chem. Soc. Rev. , 2023 , 52 ( 18 ), 6379 - 6416 . doi: 10.1039/d3cs00302g http://dx.doi.org/10.1039/d3cs00302g
Chai W. W. ; Chen X. C. ; Liu J. ; Zhang L. Y. ; Liu C. Y. ; Li L. ; Honiball J. R. ; Pan H. B. ; Cui X. ; Wang D. P. Recent progress in functional metal-organic frameworks for bio-medical application . Regen. Biomater. , 2023 , 11 , rbad 115 . doi: 10.1093/rb/rbad115 http://dx.doi.org/10.1093/rb/rbad115
Zhang Z. P. ; Zhou R. Y. ; Ke L. J. ; Li J. ; Jayan H. ; El-Seedi H. R. ; Zou X. B. ; Guo Z. M. Development of multifunctional metal-organic frameworks (MOFs)-based nanofiller materials in food packaging: a comprehensive review . Trends Food Sci. Technol. , 2024 , 154 , 104771 . doi: 10.1016/j.tifs.2024.104771 http://dx.doi.org/10.1016/j.tifs.2024.104771
Luo X. Y. ; Zhang M. ; Hu Y. B. ; Xu Y. ; Zhou H. F. ; Xu Z. J. ; Hao Y. X. ; Chen S. ; Chen S. F. ; Luo Y. W. ; Lin Y. L. ; Zhao J. J. Wrinkled metal-organic framework thin films with tunable Turing patterns for pliable integration . Science , 2024 , 385 ( 6709 ), 647 - 651 . doi: 10.1126/science.adn8168 http://dx.doi.org/10.1126/science.adn8168
Mohanty B. ; Kumari S. ; Yadav P. ; Kanoo P. ; Chakraborty A. Metal-organic frameworks (MOFs) and MOF composites based biosensors . Coord. Chem. Rev. , 2024 , 519 , 216102 . doi: 10.1016/j.ccr.2024.216102 http://dx.doi.org/10.1016/j.ccr.2024.216102
Wang Y. L. ; Liu Z. F. ; Li J. J. ; Ge C. Y. ; Ye X. ; Xie Y. X. ; Zhao P. C. ; Fei J. J. Polyaniline-on-MOF protects the MOF structure during carbonization for the construction of a portable sensor to detect tert-butylhydroquinone . Nano Energy , 2025 , 135 , 110655 . doi: 10.1016/j.nanoen.2025.110655 http://dx.doi.org/10.1016/j.nanoen.2025.110655
Ling W. ; Shang X. ; Liu J. C. ; Tang T. A skin-mountable flexible biosensor based on Cu-MOF/PEDOT composites for sweat ascorbic acid monitoring . Biosens. Bioelectron. , 2025 , 267 , 116852 . doi: 10.1016/j.bios.2024.116852 http://dx.doi.org/10.1016/j.bios.2024.116852
Cherian R. ; Binish C. J. , Vijayasankar A. V. Eco-frameworks for a cleaner planet: harnessing next-gen MOFs for pollution and plastic waste remediation . Polym. Degrad. Stabil. , 2025 , 238 , 111349 . doi: 10.1016/j.polymdegradstab.2025.111349 http://dx.doi.org/10.1016/j.polymdegradstab.2025.111349
Zhou S. N. ; Marcelino K. R. ; Wongkiew S. ; Sun L. P. ; Guo W. Z. ; Khanal S. K. ; Lu H. Untapped potential: applying microbubble and nanobubble technology in water and wastewater treatment and ecological restoration . ACS ES&T Eng. , 2022 , 2 ( 9 ), 1558 - 1573 . doi: 10.1021/acsestengg.2c00117 http://dx.doi.org/10.1021/acsestengg.2c00117
Feng J. Y. ; Xu L. W. ; Qi L. L. ; Fu Z. W. ; Hu Q. L. Polydopamine‐mediated metal-organic frameworks modification for improved biocompatibility . Macromol. Biosci. , 2024 , 24 ( 7 ), 2400071 . doi: 10.1002/mabi.202400071 http://dx.doi.org/10.1002/mabi.202400071
Liu X. G. ; Zhang Y. ; Guo X. T. ; Pang H. Electrospun metal-organic framework nanofiber membranes for energy storage and environmental protection . Adv. Fiber Mater. , 2022 , 4 ( 6 ), 1463 - 1485 . doi: 10.1007/s42765-022-00214-y http://dx.doi.org/10.1007/s42765-022-00214-y
Liu J. H. ; Wu D. ; Zhu N. ; Wu Y. N. ; Li G. L. Antibacterial mechanisms and applications of metal-organic frameworks and their derived nanomaterials . Trends Food Sci. Technol. , 2021 , 109 , 413 - 434 . doi: 10.1016/j.tifs.2021.01.012 http://dx.doi.org/10.1016/j.tifs.2021.01.012
Dassouki K. ; Dasgupta S. ; Dumas E. ; Steunou N. Interfacing metal organic frameworks with polymers or carbon-based materials: from simple to hierarchical porous and nanostructured composites . Chem. Sci. , 2023 , 14 ( 45 ), 12898 - 12925 . doi: 10.1039/d3sc03659f http://dx.doi.org/10.1039/d3sc03659f
Sun X. J. ; Li H. ; Qi L. J. ; Wang F. ; Hou Y. C. ; Li J. A. ; Guan S. K. Construction and biocompatibility evaluation of MOF/S-HA composite coating on the surface of magnesium alloy vascular stent . Prog. Org. Coat. , 2024 , 187 , 108177 .
Jia B. ; Li G. W. ; Cao E. T. ; Luo J. L. ; Zhao X. ; Huang H. Y. Recent progress of antibacterial hydrogels in wound dressings . Mater. Today Bio. , 2023 , 19 , 100582 .
Sathishkumar G. ; Gopinath K. ; Zhang K. ; Kang E. T. ; Xu L. Q. ; Yu Y. L. Recent progress in tannic acid-driven antibacterial/antifouling surface coating strategies . J. Mater. Chem. B , 2022 , 10 ( 14 ), 2296 - 2315 . doi: 10.1039/d1tb02073k http://dx.doi.org/10.1039/d1tb02073k
杨敏 , 韦平 , 刘文浩 , 陈敬华 . 聚多肽囊泡声动力抗菌平台的构建及协同抗菌效果研究 . 高分子学报 , 2025 , 56 ( 7 ), 1170 - 1179 .
Wang C. Q. ; Xu P. ; Li X. X. ; Zheng Y. H. ; Song Z. M. Research progress of stimulus-responsive antibacterial materials for bone infection . Front. Bioeng. Biotechnol. , 2022 , 10 , 1069932 . doi: 10.3389/fbioe.2022.1069932 http://dx.doi.org/10.3389/fbioe.2022.1069932
Dridi D. ; Vu N. N. ; Singh J. ; Eesaee M. ; Saidi A. ; Elkoun S. ; Nguyen-Tri P. Recent advances on engineering of silver related nanocomposites toward antibacterial applications . Nano Struct. Nano Objects , 2024 , 38 , 101195 . doi: 10.1016/j.nanoso.2024.101195 http://dx.doi.org/10.1016/j.nanoso.2024.101195
Ladhari S. ; Vu N. N. ; Boisvert C. ; Saidi A. ; Nguyen-Tri P. Recent development of polyhydroxyalkanoates (PHA)-based materials for antibacterial applications: a review . ACS Appl. Bio Mater. , 2023 , 6 ( 4 ), 1398 - 1430 . doi: 10.1021/acsabm.3c00078 http://dx.doi.org/10.1021/acsabm.3c00078
Yan L. ; Gopal A. ; Kashif S. ; Hazelton P. ; Lan M. H. ; Zhang W. J. ; Chen X. F. Metal organic frameworks for antibacterial applications . Chem. Eng. J. , 2022 , 435 , 134975 .
Zhang H. T. ; Yuan S. G. ; Zheng B. Y. ; Wu P. ; He X. M. ; Zhao Y. ; Zhong Z. F. ; Zhang X. F. ; Guan J. ; Wang H. J. ; Yang L. ; Zheng X. F. Lubricating and dual-responsive injectable hydrogels formulated from ZIF-8 facilitate osteoarthritis treatment by remodeling the microenvironment . Small , 2025 , 21 ( 3 ), 2407885 . doi: 10.1002/smll.202407885 http://dx.doi.org/10.1002/smll.202407885
Doan T. D. ; Vu N. N. ; Hoang T. L. G. ; Nguyen-Tri P. Metal-organic framework (MOF)-based materials for photocatalytic antibacterial applications . Coord. Chem. Rev. , 2025 , 523 , 216298 . doi: 10.1016/j.ccr.2024.216298 http://dx.doi.org/10.1016/j.ccr.2024.216298
Zhou Z. L. ; Li P. Z. ; Chen R. X. ; Cai X. Y. ; Zhang W. J. ; Fan P. H. ; Su J. Y. A review of curcumin-mediated photodynamic bactericidal technology for food preservation: limitations and improvement strategies . Food Microbiol. , 2025 , 131 , 104802 . doi: 10.1016/j.fm.2025.104802 http://dx.doi.org/10.1016/j.fm.2025.104802
Jeong S. H. ; Cheong S. ; Kim T. Y. ; Choi H. ; Hahn S. K. Supramolecular hydrogels for precisely controlled antimicrobial peptide delivery for diabetic wound healing . ACS Appl. Mater. Interfaces , 2023 , 15 ( 13 ), 16471 - 16481 . doi: 10.1021/acsami.3c00191 http://dx.doi.org/10.1021/acsami.3c00191
Men C. L. ; Wu C. C. ; Wang L. ; Liu S. ; Ning C. ; Liu C. H. ; Zheng L. A novel LA@Cu-MOF film with dual response to pH and humidity: preparation, antibacterial activity, and fruit preservation . Food Chem. , 2025 , 475 , 143304 . doi: 10.1016/j.foodchem.2025.143304 http://dx.doi.org/10.1016/j.foodchem.2025.143304
Kuang T. R. ; Guo H. X. ; Guo W. ; Liu W. X. ; Li W. ; Saeb M. R. ; Vatankhah-Varnosfaderani M. ; Sheiko S. S. Boosting the strength and toughness of polymer blends via ligand‐modulated MOFs . Adv. Sci. , 2024 , 11 ( 45 ), 2407593 . doi: 10.1002/advs.202407593 http://dx.doi.org/10.1002/advs.202407593
Sharma A. ; Thakur A. Synthesis, characterization and in vitro drug delivery applications of a tin-based metal-organic framework . J. Inorg. Organomet. Polym. Mater. , 2025 , 35 ( 4 ), 2597 - 2611 . doi: 10.1007/s10904-024-03397-6 http://dx.doi.org/10.1007/s10904-024-03397-6
Mohsin S. ; Amin M. N. Superbugs: a constraint to achieving the sustainable development goals . Bull. Natl. Res. Cent. , 2023 , 47 ( 1 ), 63 . doi: 10.1186/s42269-023-01036-7 http://dx.doi.org/10.1186/s42269-023-01036-7
耿玘薇 , 班雅慧 , 张剑铎 , 季修文 , 张珍坤 . 金属有机框架/聚合物复合材料的制备方法 . 离子交换与吸附 , 2024 , 40 ( 3 ), 196 - 209 .
Wang R.X. ; Fu R. R. ; Wang C. H. ; Wang J. N. ; Peng R. F. ; Zhu X. F. ; Yan X. ; Kang H. Y. ; Mao Y. L. ; Kim M. ; Yamauchi Y. Sustainable application of MOF electrospinning in the environment . J. Environ. Chem. Eng. , 2025 , 13 ( 3 ), 117022 .
Guo M. M. ; Shen M. F. ; Zhu Y. H. ; Sogore T. ; Ding T. Ultra-small gold nanoparticles embedded cyclodextrin metal-organic framework composite membrane to achieve antibacterial and humidity-responsive functions . Carbohydr. Polym. , 2024 , 340 , 122200 . doi: 10.1016/j.carbpol.2024.122200 http://dx.doi.org/10.1016/j.carbpol.2024.122200
Ananthi P. ; Naveen R. V. ; Hemkumar K. ; Praveen A. ; Anitha P. Fluorescence resonance energy transfer in gelatin-based MOF/N-CDs films for superior photodynamic antibacterial packaging materials . ACS Sustainable Chem. Eng. , 2025 , 13 ( 8 ), 3052 - 3065 . doi: 10.1021/acssuschemeng.4c06496 http://dx.doi.org/10.1021/acssuschemeng.4c06496
戴李宗 . 高分子加工 . 北京 : 化学工业出版社 , 2021 .
Pander M. ; Gil-San-Millan R. ; Delgado P. ; Perona-Bermejo C. ; Kostrzewa U. ; Kaczkowski K. ; Kubicki D. J. ; Navarro J. A. R. ; Bury W. MOF/polymer hybrids through in situ free radical polymerization in metal-organic frameworks . Mater. Horiz. , 2023 , 10 ( 4 ), 1301 - 1308 . doi: 10.1039/d2mh01202b http://dx.doi.org/10.1039/d2mh01202b
Ren Y. X. ; Hersch S. J. ; He X. ; Zhou R. F. ; Dong T. G. ; Lu Q. Y. A lightweight, mechanically strong, and shapeable copper-benzenedicarboxylate/cellulose aerogel for dye degradation and antibacterial applications . Sep. Purif. Technol. , 2022 , 283 , 120229 . doi: 10.1016/j.seppur.2021.120229 http://dx.doi.org/10.1016/j.seppur.2021.120229
Li Z. Y. ; Li H. T. ; Jin C. L. ; Li J. B. ; Bao J. J. ; Zhang X. P. ; Zhang N. ; He G. H. ; Chen C. ; Song Y. C. Confined in situ synthesis of uniformly distributed mixed matrix membranes via solvent evaporation for efficient CO 2 capture . Adv. Funct. Mater. , 2025 , 35 ( 20 ), 2420713 . doi: 10.1002/adfm.202570118 http://dx.doi.org/10.1002/adfm.202570118
Yu Z. Q. ; Li X. Y. ; Li X. H. ; Zheng B. R. ; Li D. Z. ; Xu D. K. ; Wang F. H. Nacre‐inspired metal‐organic framework coatings reinforced by multiscale hierarchical cross‐linking for integrated antifouling and anti‐microbial corrosion . Adv. Funct. Mater. , 2023 , 33 ( 47 ), 2305995 . doi: 10.1002/adfm.202305995 http://dx.doi.org/10.1002/adfm.202305995
Kalaj M. ; Bentz K. C. ; Ayala S. Jr .; Palomba, J. M.; Barcus, K. S.; Katayama, Y.; Cohen, S. M. MOF-polymer hybrid materials: from simple composites to tailored architectures. Chem. Rev., 2020 , 120 ( 16 ), 8267 - 8302 . doi: 10.1021/acs.chemrev.9b00575 http://dx.doi.org/10.1021/acs.chemrev.9b00575
Gu Y. W. ; Huang M. J. ; Zhang W. X. ; Pearson M. A. ; Johnson J. A. PolyMOF nanoparticles: dual roles of a multivalent polyMOF ligand in size control and surface functionalization . Angew. Chem. , Int. Ed., 2019 , 58 ( 46 ), 16676 - 16681 . doi: 10.1002/anie.201910542 http://dx.doi.org/10.1002/anie.201910542
Ayala S. ; Bentz K. C. ; Cohen S. M. Block co-polyMOFs: morphology control of polymer-MOF hybrid materials . Chem. Sci. , 2019 , 10 ( 6 ), 1746 - 1753 . doi: 10.1039/c8sc04250k http://dx.doi.org/10.1039/c8sc04250k
Huang D. R. ; Wu L. ; Kang Q. ; Shen Z. Y. ; Huang Q. S. ; Lin W. J. ; Pei F. ; Huang Y. H. Amino-modified UiO-66-NH 2 reinforced polyurethane based polymer electrolytes for high-voltage solid-state lithium metal batteries . Nano Res. , 2024 , 17 ( 11 ), 9662 - 9670 . doi: 10.1007/s12274-024-6886-9 http://dx.doi.org/10.1007/s12274-024-6886-9
Wang R. T. ; Lei Y. H. ; Ke L. L. ; Bai L. ; Zheng Y. ; Xu Z. J. ; Li T. C. ; Chen S. F. ; Zhang D. H. Construction of self-healing multifunctional hyper-crosslinked hyperbranched polymer@metal-organic polyhedra (HHMOP) membranes . Eur. Polym. J. , 2024 , 211 , 112966 . doi: 10.1016/j.eurpolymj.2024.112966 http://dx.doi.org/10.1016/j.eurpolymj.2024.112966
Lv J. C. ; Yang X. ; Zheng Z. L. ; Wang Z. G. ; Hong R. ; Liu Y. ; Luo E. ; Gou J. X. ; Li L. L. ; Yuan B. ; Xu J. Z. ; Li Z. M. Engineering surface-adaptive metal-organic framework armor to promote infected wound healing . ACS Appl. Mater. Interfaces , 2025 , 17 ( 1 ), 776 - 789 . doi: 10.1021/acsami.4c20219 http://dx.doi.org/10.1021/acsami.4c20219
Xiong Y. B. ; Cui J. N. ; Liu X. D. , Shu H. B. ; Cao P. Antifouling mussel-inspired hydrogel with furanone-loaded ZIF-8 for quorum sensing-mediated marine antifouling . Gels , 2025 , 11 ( 6 ), 466 . doi: 10.3390/gels11060466 http://dx.doi.org/10.3390/gels11060466
Wei F. M. ; Rees T. W. ; Liao X. X. ; Ji L. N. , Chao H. Oxygen self-sufficient photodynamic therapy . Coord. Chem. Rev. , 2021 , 432 , 213714 . doi: 10.1016/j.ccr.2020.213714 http://dx.doi.org/10.1016/j.ccr.2020.213714
Li R. ; Chen S. S. ; Zhang X. G. ; Zeng F. ; Song X. Y. ; Yin J. ; Jiang C. Z. Synergistic photothermal effect and nanoenzyme for efficient antibacterial activity . Sci. China Mater. , 2024 , 67 ( 9 ), 2985 - 2994 . doi: 10.1007/s40843-023-2816-6 http://dx.doi.org/10.1007/s40843-023-2816-6
Gao J. ; Hao L. W. ; Jiang R. J. ; Liu Z. ; Tian L. M. ; Zhao J. ; Ming W. H. ; Ren L. Q. Surprisingly fast assembly of the MOF film for synergetic antibacterial phototherapeutics . Green Chem. , 2022 , 24 ( 15 ), 5930 - 5940 . doi: 10.1039/d2gc00226d http://dx.doi.org/10.1039/d2gc00226d
He C. N. ; Feng P. P. ; Hao M. M. ; Tang Y. ; Wu X. ; Cui W. G. ; Ma J. Y. ; Ke C. H. Nanomaterials in antibacterial photodynamic therapy and antibacterial sonodynamic therapy . Adv. Funct. Mater. , 2024 , 34 ( 38 ), 2402588 . doi: 10.1002/adfm.202402588 http://dx.doi.org/10.1002/adfm.202402588
Li J. ; Song S. ; Meng J. S. ; Tan L. ; Liu X. M. ; Zheng Y. F. ; Li Z. Y. ; Yeung K. W. K. ; Cui Z. D. ; Liang Y. Q. ; Zhu S. L. ; Zhang X. C. ; Wu S. L. 2 D MOF periodontitis photodynamic ion therapy . J. Am. Chem. Soc. , 2021 , 143 ( 37 ), 15427 - 15439 . doi: 10.1021/jacs.1c07875 http://dx.doi.org/10.1021/jacs.1c07875
Xie L. ; Yang H. ; Wu X. Z. ; Wang L. Y. ; Zhu B. H. ; Tang Y. J. ; Bai M. R. ; Li L. ; Cheng C. ; Ma T. Ti-MOF-based biosafety materials for efficient and long-life disinfection via synergistic photodynamic and photothermal effects . Biosaf. Health , 2022 , 4 ( 2 ), 135 - 146 . doi: 10.1016/j.bsheal.2022.02.001 http://dx.doi.org/10.1016/j.bsheal.2022.02.001
Li P. ; Li J. Z. ; Feng X. ; Li J. ; Hao Y. C. ; Zhang J. W. ; Wang H. ; Yin A. X. ; Zhou J. W. ; Ma X. J. ; Wang B. Metal-organic frameworks with photocatalytic bactericidal activity for integrated air cleaning . Nat. Commun. , 2019 , 10 , 2177 . doi: 10.1038/s41467-019-10218-9 http://dx.doi.org/10.1038/s41467-019-10218-9
Li J. W. ; Chu Z. J. ; Wang S. M. ; Liu H. P. ; Dong B. Study on synergistic mechanism of Cu-TCPP@ MnO 2 composites for photothermal/photodynamic/chemodynamic treatment of infected wound healing . Chem. Eng. J. , 2025 , 512 , 162334 . doi: 10.1016/j.cej.2025.162334 http://dx.doi.org/10.1016/j.cej.2025.162334
Han X. ; Boix G. ; Balcerzak M. ; Moriones O. H. ; Cano‐Sarabia M. ; Cortés P. ; Bastús N. ; Puntes V. ; Llagostera M. ; Imaz I. ; Maspoch D. Antibacterial films based on MOF composites that release iodine passively or upon triggering by near‐infrared light . Adv. Funct. Mater. , 2022 , 32 ( 19 ), 2112902 . doi: 10.1002/adfm.202112902 http://dx.doi.org/10.1002/adfm.202112902
Huang Z. L. ; Fan L. L. ; Chen B. ; Zhou S. F. ; Huang J. L. ; Li Q. B. ; Zhan G. W. Confined growth of MOF nanocrystals using a "locked" metal ion source . J. Mater. Chem. A , 2021 , 9 ( 7 ), 3976 - 3984 . doi: 10.1039/d0ta08285f http://dx.doi.org/10.1039/d0ta08285f
He C. H. ; Liu C. ; Li M. Y. ; Li M. ; Yin J. L. ; Han S. M. ; Xia J. ; Chen D. Y. ; Cao W. B. ; Lu Q. P. ; Rosei F. 3D hierarchical Cu-MOF nanosheets-based antibacterial mesh . Chem. Eng. J. , 2022 , 446 , 137381 . doi: 10.1016/j.cej.2022.137381 http://dx.doi.org/10.1016/j.cej.2022.137381
Li R. ; Chen T. T. ; Pan X. L. Metal-organic-framework-based materials for antimicrobial applications . ACS Nano , 2021 , 15 ( 3 ), 3808 - 3848 . doi: 10.1021/acsnano.0c09617 http://dx.doi.org/10.1021/acsnano.0c09617
Qian Y. W. ; Wang C. X. ; Xu R. R. ; Wang J. ; Chen Q. Y. ; Zhu Z. R. ; Hu Q. ; Shen Q. Y. ; Shen J. W. Copper-based metal-organic frameworks for antitumor application . J. Nanobiotechnol. , 2025 , 23 ( 1 ), 135 . doi: 10.1186/s12951-025-03220-5 http://dx.doi.org/10.1186/s12951-025-03220-5
Zheng M. H. ; Huang Y. L. ; Hu W. W. ; Li R. ; Wang J. Y. ; Han M. F. ; Li Z. H. Evaluation of the antibacterial, anti-inflammatory, and bone-promoting capacity of UiO-66 loaded with thymol or carvacrol . ACS Appl. Mater. Interfaces , 2024 , 16 ( 28 ), 36017 - 36029 . doi: 10.1021/acsami.4c04139 http://dx.doi.org/10.1021/acsami.4c04139
Obulapuram P. K. ; Arfin T. ; Mohammad F. ; Kumari K. ; Khiste S. K. ; Al-Lohedan H. A. ; Chavali M. Surface-enhanced biocompatibility and adsorption capacity of a zirconium phosphate-coated polyaniline composite . ACS Omega , 2021 , 6 ( 49 ), 33614 - 33626 . doi: 10.1021/acsomega.1c04490 http://dx.doi.org/10.1021/acsomega.1c04490
Pander M. ; Gil-San-Millan R. ; Delgado P. ; Perona-Bermejo C. ; Kostrzewa U. ; Kaczkowski K. ; Kubicki D. J. ; Navarro J. A. R. ; Bury W. MOF/polymer hybrids through in situ free radical polymerization in metal-organic frameworks . Mater. Horiz. , 2023 , 10 ( 4 ), 1301 - 1308 . doi: 10.1039/d2mh01202b http://dx.doi.org/10.1039/d2mh01202b
Fan Y. L. ; Liu H. J. ; Wang Z. L. ; Wang Z. L. ; Zhu L. L. ; Wang Y. Z. ; Song F. A one-nano MOF-two-functions strategy toward self-healing, anti-inflammatory, and antibacterial hydrogels for infected wound repair . Chem. Eng. J. , 2024 , 497 , 155037 . doi: 10.1016/j.cej.2024.155037 http://dx.doi.org/10.1016/j.cej.2024.155037
Yue N. ; Umer S. ; Subramaniam R. ; Teoh W. Y. ; Yang C. P. Emerging metal-polymer frameworks: structure, applications, and perspectives . Adv. Funct. Mater. , 2025 , 35 ( 41 ), 2425506 . doi: 10.1002/adfm.202425506 http://dx.doi.org/10.1002/adfm.202425506
Wang Y. Q. ; Su P. P. ; Lin Z. ; Li X. L. ; Chen K. B. ; Ye T. T. ; Li Y. P. ; Zou Y. ; Wang W. A Tribo/piezoelectric nanogenerator based on bio‐MOFs for energy harvesting and antibacterial wearable device . Adv. Mater. , 2025 , 37 ( 9 ), 2418207 . doi: 10.1002/adma.202418207 http://dx.doi.org/10.1002/adma.202418207
Ma H. Y. ; Zhang W. ; Yang K. ; Liu Z. L. S. ; Zhang W. W. Bimetallic MOF nanoparticles decorated on polyacrylonitrile-based electrospun nanofiber membranes for synergistic antibacterial activity and organic dye adsorption . J. Environ. Manage. , 2025 , 376 , 124465 . doi: 10.1016/j.jenvman.2025.124465 http://dx.doi.org/10.1016/j.jenvman.2025.124465
Pejman M. ; Dadashi Firouzjaei M. ; Aghapour Aktij S. ; Das P. ; Zolghadr E. ; Jafarian H. ; Arabi Shamsabadi A. ; Elliott M. ; Sadrzadeh M. ; Sangermano M. ; Rahimpour A. ; Tiraferri A. A. In situ Ag-MOF growth on pre-grafted zwitterions imparts outstanding antifouling properties to forward osmosis membranes . ACS Appl. Mater. Interfaces , 2020 , 12 ( 32 ), 36287 - 36300 . doi: 10.1021/acsami.0c12141 http://dx.doi.org/10.1021/acsami.0c12141
Zhou Y. H. ; Chen Z. X. ; Zhao D. ; Li D. ; He C. L. ; Chen X. S. A pH-triggered self-unpacking capsule containing zwitterionic hydrogel-coated MOF nanoparticles for efficient oral exendin-4 delivery . Adv. Mater. , 2021 , 33 ( 32 ), 2102044 . doi: 10.1002/adma.202102044 http://dx.doi.org/10.1002/adma.202102044
Zhang Y. P. ; Zhang D. X. ; He Y. F. ; Wang Z. Y. ; Song P. F. ; Wang R. M. Construction of hexagonal spindle-shaped Fe-MOFs induced by cationic copolymer and its application for effective wastewater treatment . Environ. Sci. Pollut. Res. Int. , 2023 , 30 ( 33 ), 80279 - 80292 . doi: 10.1007/s11356-023-28121-8 http://dx.doi.org/10.1007/s11356-023-28121-8
Zhang Y. P. ; Zhang D. X. ; Geng Y. Z. ; He Y. F. ; Song P. F. ; Wang R. M. Construction of self-propelled micromotor for "hunting bacteria" . Biomater. Sci. , 2023 , 11 ( 20 ), 6775 - 6780 . doi: 10.1039/d3bm01175e http://dx.doi.org/10.1039/d3bm01175e
Tovar G. I. ; Valverde A. ; Mendes-Felipe C. ; Wuttke S. ; Fidalgo-Marijuan A. ; Larrea E. S. ; Lezama L. ; Zheng F. Y. ; Reguera J. ; Lanceros-Méndez S. ; Arriortua M. I. ; Copello G. ; de Luis R. F. Chitin/metal-organic framework composites as wide‐range adsorbent . ChemSusChem , 2021 , 14 ( 14 ), 2892 - 2901 . doi: 10.1002/cssc.202100675 http://dx.doi.org/10.1002/cssc.202100675
Miao D. T. ; Wei Y. ; Wu Q. ; Miron R. J. ; Chai J. H. ; Zhang Y. F. Light-driven double-layer polydopamine-coated flexible metal-organic frameworks: balancing antibacterial and regenerative functions . ACS Nano , 2025 , 19 ( 36 ), 32869 - 32890 . doi: 10.1021/acsnano.5c11831 http://dx.doi.org/10.1021/acsnano.5c11831
Sun S. R. ; Liu X. Y. ; Meng X. D. ; Yang Z. ; Zhang X. J. ; Dong H. F. Bimetallic metal-organic framework microneedle array for wound healing through targeted reactive oxygen species generation and electron transfer disruption . ACS Nano , 2025 , 19 ( 15 ), 15109 - 15119 . doi: 10.1021/acsnano.5c02923 http://dx.doi.org/10.1021/acsnano.5c02923
Gao J. ; Hao L. W. ; Jiang R. J. ; Liu Z. ; Tian L. M. ; Zhao J. ; Ming W. H. ; Ren L. Q. Surprisingly fast assembly of the MOF film for synergetic antibacterial phototherapeutics . Green Chem. , 2022 , 24 ( 15 ), 5930 - 5940 . doi: 10.1039/d2gc00226d http://dx.doi.org/10.1039/d2gc00226d
Yu Z. Q. ; Li X. Y. ; Wang Z. X. ; Fan Y. Q. ; Zhao W. J. ; Li D. Z. ; Xu D. K. ; Gu T. Y. ; Wang F. H. Robust chiral metal-organic framework coatings for self‐activating and sustainable biofouling mitigation . Adv. Mater. , 2024 , 36 ( 45 ), 2407409 . doi: 10.1002/adma.202407409 http://dx.doi.org/10.1002/adma.202407409
Tian Y. ; Yang Q. L. ; Liu Y. C. ; Shi W. ; Guo P. ; Yang Q. ; Yi X. L. ; Tuo W. B. ; Xiong S. W. ; Zhao J. ; He Y. N. ; Qu Y. Multimodal antibacterial microneedles with nanozymes mediated ROS-scavenging and oxygen-generation synergistic photothermal/photodynamic therapy to promote diabetic ulcer healing . Mater. Today Bio , 2025 , 35 , 102368 . doi: 10.1016/j.mtbio.2025.102368 http://dx.doi.org/10.1016/j.mtbio.2025.102368
Xiao Y. X. ; Jiang J. J. ; Cai R. ; Fu J. J. ; Xiang S. F. ; Zhao S. J. ; Fu F. Y. ; Diao H. Y. ; Liu X. D. A novel L-Cys@Cu MOF embedding onto cotton fiber surfaces to exert excellent antiviral and antibacterial effects . Adv. Fiber Mater. , 2024 , 6 ( 2 ), 444 - 457 . doi: 10.1007/s42765-023-00365-6 http://dx.doi.org/10.1007/s42765-023-00365-6
陈海明 , 董侠 , 赵莹 , 王笃金 . 废弃一次性医用口罩的回收利用与化学升级再造 , 高分子学报 , 2020 , 51 ( 12 ), 1295 - 1306 . doi: 10.11777/j.issn1000-3304.2020.20136 http://dx.doi.org/10.11777/j.issn1000-3304.2020.20136
Li W. L. ; Yu Z. ; Zhang Y. X. ; Lv C. ; He X. X. ; Wang S. ; Wang Z. X. ; He B. ; Yuan S. X. ; Xin J. W. ; Liu Y. T. ; Zhou T. Z. ; Li Z. X. ; Tan S. C. ; Wei L. Scalable multifunctional MOFs-textiles via diazonium chemistry . Nat. Commun. , 2024 , 15 ( 1 ), 5297 . doi: 10.1038/s41467-024-49636-9 http://dx.doi.org/10.1038/s41467-024-49636-9
Du J. ; Wang H. Y. , Shi Y. C. ; Song H. P. Research progress on coating application and mechanism based on MOF materials . Acta Mater. Compos. Sin. , 2024 , 41 ( 3 ), 1093 - 1108 .
Xu M. ; He S. M. ; Wang Y. ; Li R. K. ; Wei L. ; Guo R. B. ; Liu N. J. ; Mo Z. L. Development of fluorine-free superhydrophobic antibacterial and antifouling coatings: a multifunctional composite system for biomedical materials and metal protection . Chem. Eng. J. , 2025 , 522 , 167747 . doi: 10.1016/j.cej.2025.167747 http://dx.doi.org/10.1016/j.cej.2025.167747
Khan M. J. ; Hafeez F. ; Islam M. R. ; Zhu C. G. ; Xianyu Y. L. Advanced antibacterial packaging for food preservation through multifunctional metal-organic framework nanocomposite . Small , 2025 , 21 ( 23 ), 2501111 . doi: 10.1002/smll.202501111 http://dx.doi.org/10.1002/smll.202501111
Li P. N. ; Deng Y. Q. ; Zou W. C. ; Ma Z. Q. ; Yang X. D. ; Zhao Q. Biosafe Cu-MOF loaded chitosan/gelatin-based multifunctional packaging film for monitoring shrimp freshness . Food Hydrocoll. , 2025 , 160 , 110721 . doi: 10.1016/j.foodhyd.2024.110721 http://dx.doi.org/10.1016/j.foodhyd.2024.110721
Kathuria A. ; El Badawy A. ; Al-Ghamdi S. ; Hamachi L. S. ; Kivy M. B. Environmentally benign bioderived, biocompatible, thermally stable MOF suitable for food contact applications. Trends Food Sci. Technol ., 2023 , 138 , 323 - 338 . doi: 10.1016/j.tifs.2023.06.024 http://dx.doi.org/10.1016/j.tifs.2023.06.024
Ji A.Q. ; Shafique B. ; Xu J. ; Xie J. ; Ding Z. Y. Recent developments in synthesis, functionality, and sustainability of metal-organic framework films for fruits and vegetables packaging . Trends Food Sci. Technol. , 2025 , 166 , 105392 . doi: 10.1016/j.tifs.2025.105392 http://dx.doi.org/10.1016/j.tifs.2025.105392
Wang Y. Q. ; Su P. P. ; Lin Z. ; Li X. L. ; Chen K. B. ; Ye T. T. ; Li Y. P. ; Zou Y. ; Wang W. A tribo/piezoelectric nanogenerator based on bio-MOFs for energy harvesting and antibacterial wearable device . Adv. Mater. , 2025 , 37 ( 9 ), 2418207 . doi: 10.1002/adma.202418207 http://dx.doi.org/10.1002/adma.202418207
0
浏览量
0
下载量
0
CSCD
关联资源
相关文章
相关作者
相关机构

京公网安备11010802046899号