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四川大学高分子科学与工程学院 高分子材料工程国家重点实验室,成都,610065
纸质出版日期:2011-11-20,
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刘葭, 丁治天, 刘正英, 冯建民, 杨伟, 杨鸣波. 辊速辊温对高密度聚乙烯拉伸微孔膜及其片晶结构的影响[J]. 高分子学报, 2011,(11):1278-1283.
LIU Jia, DING Zhitian, LIU Zhengying, FENG Jianmin, YANG Wei, YANG Mingbo. EFFECT OF ROLLER RATES AND TEMPERATURES ON THE STRUCTURE OF HDPE STRETCHED MICROPOROUS MEMBRANES AND LAMELLAE[J]. Acta Polymerica Sinica, 2011,(11):1278-1283.
刘葭, 丁治天, 刘正英, 冯建民, 杨伟, 杨鸣波. 辊速辊温对高密度聚乙烯拉伸微孔膜及其片晶结构的影响[J]. 高分子学报, 2011,(11):1278-1283. DOI: 10.3724/SP.J.1105.2011.10328.
LIU Jia, DING Zhitian, LIU Zhengying, FENG Jianmin, YANG Wei, YANG Mingbo. EFFECT OF ROLLER RATES AND TEMPERATURES ON THE STRUCTURE OF HDPE STRETCHED MICROPOROUS MEMBRANES AND LAMELLAE[J]. Acta Polymerica Sinica, 2011,(11):1278-1283. DOI: 10.3724/SP.J.1105.2011.10328.
采用熔融挤出片材退火冷拉伸热拉伸热定形的方法来制备高密度聚乙烯(HDPE)微孔膜
利用FTIR、SEM和DSC等测试方法来研究辊速辊温对HDPE拉伸微孔膜及其片晶结构的影响.研究结果表明
所选树脂的分子量、分子量分布以及弛豫时间能够满足现有加工条件
形成片晶取向度较高的预制膜;在相同辊温下
随辊速增加
退火前预置膜和退火后预制膜的片晶取向度都增加
片晶厚度都降低
拉伸微孔膜中的微孔分布区域增加
微孔结构更加均匀;在相同辊速下
90℃辊温适宜片晶结构的规整排列
在此辊温下得到的预制膜具有最大的片晶取向度、最薄的片晶厚度和最均匀的片晶厚度
拉伸时能得到孔径和微孔分布最均匀的微孔膜.
The HDPE microporous membranes were obtained by a melt-extrusion
annealing
cold stretching
hot stretching and heat setting method.The effect of roller rates and roller temperatures on the structure of the lamellae and the HDPE stretched microporous membranes was characterized by dynamic rheology
FTIR
DSC
SEM and other characterization methods.The results show that the molecular weight
molecular weight distribution and the relaxation time of the HDPE resin used in this experiment can meet the requirements of the present processing conditions for obtaining precursor films with arranged lamellar structure of larger lamellar orientation.Under the same roller temperature
the lamellar orientation of the unannealed and annealed precursor films increases
the lamellar thickness decreases
the micropores distribution regions of the microporous membranes increase and the micropores are more uniform with the roller rates increasing.The lamellar structures arrange more regularly when the roller temperature is 90℃ under the same roller rate
it is a perfect roller temperature to prepare large lamellar orientation precursor films for the resin used in this experiment.Under roller temperature of 90℃
the precursor film with the maximal lamellar orientation
the thinnest lamellar thickness and the narrower lamellar thickness distribution can be obtained
and the structures of the micropore and the micropore distribution are more uniform.
高密度聚乙烯微孔膜片晶取向度片晶厚度
High-density polyethylene(HDPE)Microporous membranesLamellar orientationLamellar thickness
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