Di-shun Zhao, Lin-lin Fu, Juan Zhang, He Li, Meng-shuai Liu, Jiang-tao Fu, Wei Wang. STUDY ON THE DISSOLUTION OF CELLULOSE IN N-ALLYLPYRIDINIUM CHLORIDE IONIC LIQUID AND CO-SOLVENT COMPOSITES[J]. Acta Polymerica Sinica, 2012,(9):937-942.
Di-shun Zhao, Lin-lin Fu, Juan Zhang, He Li, Meng-shuai Liu, Jiang-tao Fu, Wei Wang. STUDY ON THE DISSOLUTION OF CELLULOSE IN N-ALLYLPYRIDINIUM CHLORIDE IONIC LIQUID AND CO-SOLVENT COMPOSITES[J]. Acta Polymerica Sinica, 2012,(9):937-942. DOI: 10.3724/SP.J.1105.2012.11407.
N-allylpyridinium chloride ionic liquid ([APy]Cl) was synthesized by one-step process and its property of dissolving cellulose was investigated.The results showed that the solubility of cotton linter pulp cellulose (degree of polymerization (DP)=556) was 19.71% at 120℃
and the thermostability of regenerated cellulose (DP=223) seriously decreased.The performance of regenerated cellulose could be enhanced by adding cosolvents into [APy]Cl.Compared with other cosolvent (DMSO
DMF or pyridine)
the [APy]Cl/DMAc composite solvent exhibited a better dissolution to cotton linter pulp cellulose.The solubility was 15.03% and the DP of regenerated cellulose was 403 at 100℃ with lower cost.But the solubility of [APy]Cl/DMAc was only 1.36% at 70℃.So
the [APy]Cl/1-N-ally1-3-methylimidazolium chloride ionic liquid ([AMIM]Cl) solvent was discussed afterwards.The results showed that the solubility of cotton linter pulp was 8.78% and the DP of regenerated cellulose was 516 in [APy]Cl/[AMIM]Cl composite solvent at 70℃.Besides
[APy]Cl/DMAc and [APy]Cl/[AMIM]Cl were liquid respectively below the melting point of [APy]Cl and they were the potential cellulose solvent.The FTIR
XRD and TGA spectrograms showed that these solvents were non-derivatizing solvents for cellulose
the cellulose was changed from cellulose Ⅰ to cellulose Ⅱ during dissolution and regeneration and the thermal stability of the regenerated cellulose slightly decreased.The photographs and SEM image indicated that the regenerated cellulose membrane was homogeneous and dense.