6-Me2C6H3)) activated with [Ph3C]B(C6F5)4] could initiate ethylene and propylene copolymerization with high activity (7.5105g(PE)mol-1 h-1 (105Pa)-1) under the conditions of room temperature (30℃) and atomphere pressure (1.0 105 Pa).The influence of comonomer feed content and polymerization temperature on activity and the composition of the copolymers using LSc(CH2SiMe3)2/[Ph3C]B(C6F5)4] catalytic system were investigated.An increase in the initial propylene feed content leads to the increase in the incorporated propylene content of the resulting copolymer.At 30℃
the highest activity and incorporation of propylene were achieved.Determination of the reactivity ratios shows a much high reactivity for ethylene (rE=29.75 and rP=0.015).The resultant copolymers are elastomers having random sequence distibution of the two monomeric units evidenced by 13C-NMR spectroscopy and DSC analyses.
关键词
稀土配合物乙烯丙烯共聚合
Keywords
Rare earth metal complexEthylenePropyleneCopolymerization