二氧化碳刺激响应型聚合物的研究进展

丁明宇; 蒋钱宇; 武鹏超; 靳海宝; 杨晓玲; 林绍梁

doi:10.11777/j.issn1000-3304.2024.24250

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二氧化碳刺激响应型聚合物的研究进展

综述 | 更新时间：2025-06-17

- 二氧化碳刺激响应型聚合物的研究进展
- Advances in CO₂ Stimuli-responsive Polymers
- 高分子学报 2025年56卷第5期页码：690-704
- 作者机构：
  
  上海市先进聚合物材料重点实验室华东理工大学材料科学与工程学院上海 200237
- 作者简介：
  
  E-mail: haibaojin@ecust.edu.cn
  xlyang@ecust.edu.cn
  slin@ecust.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2024.24250
  中图分类号：
- CSTR：32057.14.GFZXB.2024.7330
- 收稿日期：2024-10-09，
  
  录用日期：2024-12-11，
  
  网络出版日期：2025-02-18，
  
  纸质出版日期：2025-05-20
- 稿件说明：
移动端阅览
丁明宇, 蒋钱宇, 武鹏超, 靳海宝, 杨晓玲, 林绍梁. 二氧化碳刺激响应型聚合物的研究进展. 高分子学报, 2025, 56(5), 690-704

Ding, M. Y.; Jiang, Q. Y.; Wu, P. C.; Jin, H. B.; Yang, X. L.; Lin, S. L. Advances in CO₂ stimuli-responsive polymers. Acta Polymerica Sinica, 2025, 56(5), 690-704
丁明宇, 蒋钱宇, 武鹏超, 靳海宝, 杨晓玲, 林绍梁. 二氧化碳刺激响应型聚合物的研究进展. 高分子学报, 2025, 56(5), 690-704 DOI： 10.11777/j.issn1000-3304.2024.24250. CSTR： 32057.14.GFZXB.2024.7330.

Ding, M. Y.; Jiang, Q. Y.; Wu, P. C.; Jin, H. B.; Yang, X. L.; Lin, S. L. Advances in CO₂ stimuli-responsive polymers. Acta Polymerica Sinica, 2025, 56(5), 690-704 DOI： 10.11777/j.issn1000-3304.2024.24250. CSTR： 32057.14.GFZXB.2024.7330.

摘要

二氧化碳(CO

)刺激响应型聚合物是指在向聚合物体系中引入或排除CO

后，聚合物物理结构与化学性质等发生可逆变化的“智能”大分子，在各科学领域具有广阔的应用前景. 本文从CO

响应基团出发，分类介绍不同种类CO

响应基团的作用机理，随后依次综述了CO

响应型聚合物的合成、表征、智能体系及其应用领域. 最后讨论与总结该类聚合物材料现存的挑战，并对其未来应用前景与发展方向进行了展望.

Abstract

is a benign

inexpensive

abundant

and non-toxic trigger for stimuli-responsive materials

and has received increasing attention in recent years. CO

stimuli-responsive polymers

as an attractive type of "smart" macromolecules

undergo a reversible transition in the physical and chemical properties of polymers when CO

is introduced or excluded from the polymer system

exhibiting broad application prospects in various scientific fields. Herein

this review summarizes the recent development of CO

-responsive polymers and introduces the working mechanisms of different types of CO

-responsive groups from chemical structures

including amidines

tertiary amines

guanidines

imidazoles

and frustrated Lewis pair (FLP). Methods for the synthesis of CO

-responsive polymers are introduced

including free radical polymerization (FRP)

reversible addition-fragmentation chain-transfer (RAFT)

atom transfer radical polymerization (ATRP)

nitroxide-mediated polymerization (NMP)

and postpolymerization modification. Subsequently

the techniques for the characterization of CO

-responsive polymers are summarized

including structural characterization using

H-NMR and FTIR

and property characterization using measurements of pH

conductivity

Zeta potential

and transmittance. Assemblies

latexes

gels

composites

and membranes with CO

responsiveness are introduced separately from the perspective of smart response systems

and the current status of these developments is summarized. Among these

research on the second generation of CO

-responsive systems is highlighted

which are based on the "dynamic gas bridge" formed between boron/phosphorus frustrated Lewis acid-base pairs and carbon dioxide gas molecules. Meanwhile

a stepwise summary of CO

-responsive polymers for CO

capture

smart catalysts

protein adsorption

controllable separation

fluorescence sensing

and drug delivery is presented. Eventually

the current challenges toward the development of CO

-responsive polymers are discussed and summarized

accompanied by an outlook of the future application prospects and development directions. Large-scale production of CO

-responsive polymers remains a significant challenge

while further investigation of the response mechanism to improve the sensitivity and cyclic stability of the response process will provide the basis for the development of CO

-responsive materials that have a broader range of applications.

关键词

Keywords

references

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