聚合物蓝相液晶的图案化研究进展

李景辉; 王雷; 仝佳琪; 郑成林; 杨文杰; 王京霞; 江雷

doi:10.11777/j.issn1000-3304.2024.24256

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聚合物蓝相液晶的图案化研究进展

综述 | 更新时间：2025-04-28

- 聚合物蓝相液晶的图案化研究进展
- Research Progress on the Patterning of Polymer Blue-phase Liquid Crystals
- 高分子学报 2025年56卷第5期页码：705-733
- 作者机构：
  
  1.中国科学院理化技术研究所仿生材料与界面科学重点实验室北京 100190
  2.中国科学院大学未来技术学院北京 101408
- 作者简介：
  
  [ "王京霞，女，1971年生. 分别于1994年，1997年在青岛科技大学高分子专业获得学士和硕士学位. 2004年1月在清华大学材料学专业获博士学位，2004~2006年在中国科学院化学研究所有机固体实验室江雷研究员组做博士后研究，2006年8月~2014年4月在中国科学院化学研究所宋延林研究员课题组任助研、副研，期间(2012年6~9月)在加拿大阿尔伯塔大学Mike Serpe教授课题组做访问学者；2014年4月调至中国科学院理化技术研究所工作，并聘任研究员、博士生导师. 2016年聘任中国科学院大学岗位教授. 主要研究方向聚焦浸润性调控功能性光子晶体(功能性液晶材料)制备及相关传感、驱动方面的研究、宽温域蓝相液晶制备、相变过程及激光性能研究. 以第一/通讯作者在Nature Commun.，Adv. Mater.，J. Am. Chem. Soc.，Adv. Funct. Mater.等期刊发表150余篇论文，主持科技部重点研发计划课题、院国际合作项目，基金委面上项目等科研项目，拥有授权发明专利40项. 《仿生智能纳米材料》课程获中国科学院大学2020年学院级“研究生优秀课程”(第三排名)；获2016年北京市科学技术一等奖(第四排名)，2012年第十四届中国发明专利优秀奖." ]
- 基金信息：
  
  国家自然科学基金(基金号 ┣52373001;51873221);52073292,51673207,51373183,21988102┫;中国科学院和荷兰研究项目(1A1111KYSB20190072)
- DOI：10.11777/j.issn1000-3304.2024.24256
  中图分类号：
- CSTR：32057.14.GFZXB.2024.7331
- 收稿日期：2024-10-23，
  
  录用日期：2024-12-12，
  
  网络出版日期：2025-02-21，
  
  纸质出版日期：2025-05-20
- 稿件说明：
移动端阅览
李景辉, 王雷, 仝佳琪, 郑成林, 杨文杰, 王京霞, 江雷. 聚合物蓝相液晶的图案化研究进展. 高分子学报, 2025, 56(5), 705-733

Li, J. H.; Wang, L.; Tong, J. Q.; Zheng, C. L.; Yang, W. J.; Wang, J. X.; Jiang, L. Research progress on the patterning of polymer blue-phase liquid crystals. Acta Polymerica Sinica, 2025, 56(5), 705-733
李景辉, 王雷, 仝佳琪, 郑成林, 杨文杰, 王京霞, 江雷. 聚合物蓝相液晶的图案化研究进展. 高分子学报, 2025, 56(5), 705-733 DOI： 10.11777/j.issn1000-3304.2024.24256. CSTR： 32057.14.GFZXB.2024.7331.

Li, J. H.; Wang, L.; Tong, J. Q.; Zheng, C. L.; Yang, W. J.; Wang, J. X.; Jiang, L. Research progress on the patterning of polymer blue-phase liquid crystals. Acta Polymerica Sinica, 2025, 56(5), 705-733 DOI： 10.11777/j.issn1000-3304.2024.24256. CSTR： 32057.14.GFZXB.2024.7331.

摘要

蓝相液晶以其独特的三维手性结构和动态可调的结构色得到研究者的广泛关注. 本文系统综述了蓝相液晶的图案化制备策略、响应性蓝相液晶的图案研究进展及相关应用. 蓝相液晶的图案化制备策略包括化学基底图案技术、掩膜版法、喷墨打印技术、直写技术及裁剪技术. 响应性蓝相液晶的图案研究则包括蓝相液晶图案在电、光、热、机械力、溶剂与蒸气外场刺激下的响应性变化. 最后介绍了蓝相液晶的图案化应用，并探讨了蓝相液晶的图案化存在的问题及潜在的研究方向.

Abstract

Structural color has attracted significant attention due to its durability

environmental friendliness

and high saturation. Chiral structural colors

in particular

hold great promise for advanced optical control due to their tunable polarization properties

making them ideal for next-generation optical devices. Blue-phase liquid crystals (BPLC)

with their unique three-dimensional chiral structures and dynamically adjustable structural colors

have drawn considerable interest from researchers. This review summarizes the patterning strategies

responsiveness

and applications of BPLC

beginning with an overview of their concept and fundamental properties.The review first introduces the basic principles and properties of BPLC

highlighting the methods to expand their temperature range

such as polymer-polymer stabilization

molecular tuning

and inorganic material doping. Next

it explores patterning techniques for BPLC and the multiple responsive behaviors of these patterns. Key preparation methods including chemical substrate patterning

mask-based techniques

inkjet printing

direct writing and laser cutting are discussed. The responsiveness of the patterns is discussed in terms of the optical property changes and pattern transformations induced by various external stimuli

including electrical

optical

thermal

mechanical

and solvent or vapor exposure.Finally

the article discusses the optical applications of BPLC in areas such as information transmission

lasers

and sensors

while also addressing current challenges in BPLC patterning and potential future research directions.

关键词

Keywords

references

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