聚硫辛酸离子凝胶的制备及在极端环境中的黏附传感应用

张恒杰; 杜威龙; 姚奇; 刘炜洁; 夏宝; 李乙文; 顾志鹏

doi:10.11777/j.issn1000-3304.2024.24277

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聚硫辛酸离子凝胶的制备及在极端环境中的黏附传感应用

研究论文 | 更新时间：2025-03-04

- 聚硫辛酸离子凝胶的制备及在极端环境中的黏附传感应用
- Preparation of Poly-Lipoic Acid Ionic Gel for Extreme Environmental Adhesion Sensing
- 高分子学报 2025年页码：1-10
- 作者机构：
  
  四川大学高分子科学与工程学院高分子材料国家重点实验室成都 610065
- 作者简介：
  
  E-mail: guzhipeng2019@scu.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 52422317┫资助‍)
- DOI：10.11777/j.issn1000-3304.2024.24277
  中图分类号：
- CSTR：32057.14.GFZXB.2024.7338
- 收稿日期：2024-11-13，
  
  录用日期：2024-12-31，
  
  网络出版日期：2025-03-02，
- 稿件说明：
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张恒杰, 杜威龙, 姚奇, 刘炜洁, 夏宝, 李乙文, 顾志鹏. 聚硫辛酸离子凝胶的制备及在极端环境中的黏附传感应用. 高分子学报, doi: 10.11777/j.issn1000-3304.2024.24277

Zhang, H. J.; Du, W. L.; Yao, Q.; Liu, W. J.; Xia, B.; Li, Y. W.; Gu, Z. P. Preparation of poly-lipoic acid ionic gel for extreme environmental adhesion sensing. Acta Polymerica Sinica, doi: 10.11777/j.‍issn1000-3304.2024.24277
张恒杰, 杜威龙, 姚奇, 刘炜洁, 夏宝, 李乙文, 顾志鹏. 聚硫辛酸离子凝胶的制备及在极端环境中的黏附传感应用. 高分子学报, doi: 10.11777/j.issn1000-3304.2024.24277 DOI： CSTR： 32057.14.GFZXB.2024.7338.

Zhang, H. J.; Du, W. L.; Yao, Q.; Liu, W. J.; Xia, B.; Li, Y. W.; Gu, Z. P. Preparation of poly-lipoic acid ionic gel for extreme environmental adhesion sensing. Acta Polymerica Sinica, doi: 10.11777/j.‍issn1000-3304.2024.24277 DOI： 10.11777/j.issn1000-3304.2024.24277. CSTR： 32057.14.GFZXB.2024.7338.

摘要

随着黏附材料深入到工业的各个领域，开发可快速制备、优异的黏附性能及可用于极端环境下的黏附传感器件，具有巨大的应用需求与潜力. 本工作利用硫辛酸(LA)在加热下快速开环聚合的特性，将具有不同化学键的离子液体作为溶剂，将硫辛酸与离子液体共聚可成功获得聚硫辛酸离子凝胶. 研究结果表明，所得离子凝胶展现出优异的黏附强度(高达120 kPa)、快速的自愈合能力(约10 s内完成)、出色的耐极端环境性能(可耐受至-196 ℃的温度)，以及良好的传感性能(响应时间仅为331 ms). 所设计的聚硫辛酸离子凝胶，不仅制备过程简便，而且适用于极端环境下的黏附传感应用，有望为开发新一代黏附材料提供新的设计思路.

Abstract

Developing adhesive sensor devices for extreme environment

s necessitates properties like fast preparation

cost-effectiveness

robust environmental adhesion

stability

and superior sensing capabilities

which are in high demand. In this research

ionic liquids with diverse chemical bonds were employed as solvents for copolymerization with lipoic acid (LA) under mild conditions to produce lipoic acid-based ionic gels

leveraging the rapid ring-opening polymerization of LA during heating. The findings indicated that the prepared poly-lipoic acid ionic gels displayed outstanding adhesive strength (120 kPa)

rapid self-healing abilities (

ca.

10 s)

exceptional resistance to extreme environmental conditions (-196 ℃)

and remarkable sensing performance (331 ms). The developed poly-lipoic acid ionic gel is easy to prepare

exhibits enduring adhesion at ultra-low temperatures

and holds promise for adhesive sensing applications in extreme environments

introducing a novel design strategy for advancing next-generation adhesive materials.

关键词

Keywords

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