自稳定沉淀聚合制备功能性微球及其在环保领域中的应用研究

杨柳; 舒泓艺; 陈冬; 赵长稳; 马育红; 杨万泰

doi:10.11777/j.issn1000-3304.2025.24314

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自稳定沉淀聚合制备功能性微球及其在环保领域中的应用研究

专论 | 更新时间：2025-04-17

- 自稳定沉淀聚合制备功能性微球及其在环保领域中的应用研究
- Preparation of Functional Microspheres by Self-stabilized Precipitation Polymerization and Its Application in Water Treatment
- 高分子学报 2025年页码：1-18
- 作者机构：
  
  北京化工大学材料科学与工程学院北京 100029
  2.北京怀柔实验室北京 101499
  3.广东美的厨卫电器制造有限公司佛山 528300
- 作者简介：
  
  [ "陈冬，男，1982年生. 2008年于北京化工大学取得理学博士学位，后赴日本长冈技术科学大学从事刺激响应性偶氮苯液晶材料设计和制备方面的研究工作，2013年起北京化工大学副教授，主要从事功能性聚合物微球设计制备和水溶性聚合物方面的研究. 作为项目负责人承担多项国家、省部级科研项目." ]
  [ "杨万泰，男，1956年生. 高分子化学家，中国科学院院士，北京化工大学教授，生物医用材料北京实验室主任. 1982年毕业于清华大学化工系，1985年于北京化工学院获硕士学位并留校工作，期间于1993—1996年在瑞典皇家理工学院进修学习获博士学位. 现任《高分子学报》主编，Biomacromolecules、Chinese J.Polym.Sci.、《中国化学快报》和《膜科学与技术》等期刊编委. 2000年获得国家杰出青年科学基金，2001年获得教育部“长江学者奖励计划”特聘教授，2006年获批教育部“长江学者与创新团队”计划学术带头人、国家111引智基地(2007/2012)负责人，2012年国家自然科学基金委创新研究群体学术带头人，2017年当选为中国科学院院士，荣获2019年“全国优秀教师”称号." ]
- 基金信息：
  
  国家自然科学基金(基金号 51988102)
- DOI：10.11777/j.issn1000-3304.2025.24314
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7365
- 收稿日期：2024-12-30，
  
  录用日期：2025-02-17，
  
  网络出版日期：2025-04-17，
- 稿件说明：
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杨柳, 舒泓艺, 陈冬, 赵长稳, 马育红, 杨万泰. 自稳定沉淀聚合制备功能性微球及其在环保领域中的应用研究. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.24314

Yang, L.; Shu, H. Y.; Chen, D.; Zhao, C. W.; Ma, Y. H.; Yang, W. T. Preparation of functional microspheres by self-stabilized precipitation polymerization and its application in water treatment. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2025.24314
杨柳, 舒泓艺, 陈冬, 赵长稳, 马育红, 杨万泰. 自稳定沉淀聚合制备功能性微球及其在环保领域中的应用研究. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.24314 DOI： CSTR： 32057.14.GFZXB.2025.7365.

Yang, L.; Shu, H. Y.; Chen, D.; Zhao, C. W.; Ma, Y. H.; Yang, W. T. Preparation of functional microspheres by self-stabilized precipitation polymerization and its application in water treatment. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2025.24314 DOI： CSTR： 32057.14.GFZXB.2025.7365.

摘要

随着现代工业的发展，重金属离子、染料和油类污染物等引起的环境问题日益严峻，严重影响生态环境和人类健康. 聚合物微球因具有高比表面积，吸附性能强，易于功能化等优点而被广泛应用于水处理领域，开发简便、高效、绿色的聚合新方法，制备表面具有高密度功能性基团的聚合物微球具有重要科学价值和实际意义. 近年来，本课题组提出了“自稳定沉淀聚合”(2SP聚合)的微球绿色制备技术，简单、高效地设计制备出核壳、空心、多孔等多种拓扑结构的聚合物微球，因含有大量的活性基团和发达的多级孔道结构，在环境治理领域取得了广泛的应用. 本专论主要介绍了通过2SP聚合对聚合物微球组成和拓扑结构进行设计，并利用表面活性基团进行化学改性，进一步讨论其在染料、抗生素、重金属离子吸附分离，负载型催化剂制备，膜分离(含油污水)等水处理领域的应用前景及研究进展.

Abstract

With the development of modern industry

water pollutions caused by heavy metal ions

organic dyes and oil pollutants have become more and more severe

which constituted a serious threaten to ecological environment and human health. Polymer microspheres are widely used in the field of water treatment due to their high specific surface area

good adsorption properties and easy functionalization. It is of great scientific value and practical significance to develop a facile

efficient and environmentally friendly polymerization method for the preparation of polymer microspheres with high density functional groups. In recent years

our research group has developed a novel green heterogeneous polymerization technique named "Self-Stabilized Precipitation Polymerization" (2SP polymerization)

which allows for the simple and efficient design and preparation of polymer microspheres with various topological structures

including core-shell

hollow

and porous structures. Benefiting from both high density of functional groups and abundant multilevel porous structure

these microspheres have been widely applied in water treatment. In this feature article

the design and preparation of microspheres with tunable composition and topological structure by 2SP process were discussed in detail. Furthermore

the reactive groups on the surface of the polymer microspheres can be facilely chemically modified

and these modified microspheres can be applied in water treatment fields

such as adsorption/separation of dyes

antibiotics and heavy metal ions

preparation of supported catalysts and membrane separation (for oily wastewater).

关键词

Keywords

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