高分子氢键复合物蠕变行为研究

刘泽新; 尹培阳; 黄浩; 张彩虹; 杨曙光

doi:10.11777/j.issn1000-3304.2025.25040

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高分子氢键复合物蠕变行为研究

研究论文 | 更新时间：2025-05-14

- 高分子氢键复合物蠕变行为研究
- Study on Creep Behavior of Hydrogen-bonded Polymer Complexes
- 高分子学报 2025年页码：1-11
- 作者机构：
  
  东华大学先进纤维材料全国重点实验室先进低维材料中心材料科学与工程学院上海 201620
- 作者简介：
  
  E-mail: shgyang@dhu.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 52273020)
- DOI：10.11777/j.issn1000-3304.2025.25040
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7391
- 收稿日期：2025-02-18，
  
  录用日期：2025-03-31，
  
  网络出版日期：2025-05-14，
- 稿件说明：
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刘泽新, 尹培阳, 黄浩, 张彩虹, 杨曙光. 高分子氢键复合物蠕变行为研究. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25040

Liu, Z. X.; Yin, P. Y.; Huang, H.; Zhang, C. H.; Yang, S. G. Study on creep behavior of hydrogen-bonded polymer complexes. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2025.25040
刘泽新, 尹培阳, 黄浩, 张彩虹, 杨曙光. 高分子氢键复合物蠕变行为研究. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25040 DOI： CSTR： 32057.14.GFZXB.2025.7391.

Liu, Z. X.; Yin, P. Y.; Huang, H.; Zhang, C. H.; Yang, S. G. Study on creep behavior of hydrogen-bonded polymer complexes. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2025.25040 DOI： CSTR： 32057.14.GFZXB.2025.7391.

摘要

蠕变行为对于材料的服役应用至关重要. 蠕变分析测试可以揭示高分子材料的黏弹性本质，解析高分子材料长时间尺度下的力学松弛行为. 本研究以聚丙烯酸(PAA)和聚环氧乙烷(PEO)构筑氢键复合物，并利用共价交联和金属离子配位作用增强氢键网络，研究温度和湿度这两种最主要的环境参数对复合物蠕变行为的影响. 分别通过时间-湿度叠加和时间-温度叠加构建蠕变柔量主曲线，进一步结合湿度和温度对时间的叠加，构建了更长时间尺度的主曲线，解析了长时间尺度下的力学松弛行为，指导材料实际服役和应用.

Abstract

Creep behavior is critical for the service applications of materials. Creep analysis tests can effectively reflect the viscoelastic properties of polymer materials and evaluate the mechanical relaxation behavior of polymer complexes over long time scales. In this work

polyacrylic acid (PAA) and polyethylene oxide (PEO) were used to construct hydrogen-bonded polymer complexes

and covalent cross-linking and metal ion coordination were used to strengthen the hydrogen bond network. The influence of temperature and humidity

the two main environmental parameters

on the creep behavior of these complexes were investigated. With the increase in temperat

ure or humidity

the creep deformation of the three types of films also increases. The creep compliance master curve was constructed by time-humidity superposition and time-temperature superposition respectively. The temperature shift factor (

) conforms to the Williams-Landel-Ferry (WLF) equation. The humidity shift factor (

) is shown as a piecewise linear dependence of water ratio. The coupling of environmental factors greatly affects the properties of hydrogen-bonded complexes. Further combined with the superposition of humidity and temperature on time

the main curve of a longer time scale is constructed

and the mechanical relaxation behavior under a long time scale is analyzed and expounded

so as to guide its practical service and application.

关键词

Keywords

references

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