固态聚合物电解质的最新研究进展

罗川; 胡利华; 宁春棚; 岳衎; 郭子豪

doi:10.11777/j.issn1000-3304.2025.25106

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固态聚合物电解质的最新研究进展

专论(明日之星专栏) | 更新时间：2025-06-19

- 固态聚合物电解质的最新研究进展
- Recent Advances in Solid-State Polymer Electrolytes
- 高分子学报 2025年页码：1-21
- 作者机构：
  
  华南理工大学前沿软物质学院发光材料与器件全国重点实验室广东省功能与智能杂化材料与器件重点实验室广州 510640
- 作者简介：
  
  [ "岳衎，华南理工大学前沿软物质学院华南软物质科学与技术高等研究院长聘教授、博士生导师. 2008年本科毕业于北京大学元培学院，2013年博士毕业于美国阿克伦大学高分子科学与工程学院，之后在阿克伦大学和哈佛大学医学院布莱根妇女医院从事博士后研究；2017年1月入职华南理工大学开展独立教学研究工作. 主要研究领域为功能性高分子弹性体与凝胶材料的设计、开发及应用. 目前已在国际主流期刊发表SCI论文100余篇，主持2项国家自然科学基金委面上项目和1项重大研究计划培育项目，以及其他10余项省部级项目和企业技术开发项目等. 曾入选中组部海外高层次青年人才项目(2017年)、获华南理工大学本科生教学优秀奖(2020年度)等奖励." ]
  [ "郭子豪，男，1986年生. 华南理工大学前沿软物质学院副教授、博士生导师. 2008年于南开大学化学学院获学士学位，2013年于北京大学化学与分子工程学院获博士学位(导师：裴坚教授). 2014~2016年，在美国德州农工大学化学系从事博士后研究工作(合作导师：Lei Fang教授)，2016~2018年在美国耶鲁大学环境与化工学院从事博士后研究工作(合作导师：Mingjiang Zhong教授). 2018年入职华南理工大学前沿软物质学院，主要从事共轭聚合物设计、合成及应用和锂电池固态电解质材料的研究." ]
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2025.25106
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7436
- 收稿日期：2025-04-20，
  
  录用日期：2025-06-03，
  
  网络出版日期：2025-06-19，
- 稿件说明：
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罗川, 胡利华, 宁春棚, 岳衎, 郭子豪. 固态聚合物电解质的最新研究进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25106

Luo, C.; Hu, L. H.; Ning, C. P.; Yue, K.; Guo, Z. H. Recent advances in solid-state polymer electrolytes. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2025.25106
罗川, 胡利华, 宁春棚, 岳衎, 郭子豪. 固态聚合物电解质的最新研究进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25106 DOI： CSTR： 32057.14.GFZXB.2025.7436.

Luo, C.; Hu, L. H.; Ning, C. P.; Yue, K.; Guo, Z. H. Recent advances in solid-state polymer electrolytes. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2025.25106 DOI： CSTR： 32057.14.GFZXB.2025.7436.

摘要

具备高能量密度和安全性的全固态电池技术已成为下一代先进储能体系的核心发展方向. 固态聚合物电解质(SPE)因其轻质化特征、成本效益优势、优异加工性能及本质阻燃特性，展现出替代传统液态电解质实现规模化商业应用的潜力. 然而，传统商业化SPE受限于其固有电化学性能缺陷，已难以适配当前高能量密度电池体系对电解质材料的严苛性能要求. 尽管通过杂化改性、共混优化、掺杂调控等物理工艺制备的凝胶电解质及无机复合电解质可部分满足现有锂金属电池(LMB)的应用需求，但开发兼具本征高离子电导率与宽电化学窗口的SPE仍是当前储能材料领域的关键科学命题. 本篇综述简要概述了全固态聚合物领域的最新研究进展，并系统地整理与分类了新型SPE的主流设计策略. 这些策略涵盖多维拓扑结构的设计、阴离子锚定策略、聚合物氟化工程、弱溶剂化主链构筑以及其他创新性设计理念. 各章节分别介绍了基于上述策略研发的新型SPE，并展示了其在LMB里的实际应用表现. 最后，本文为如何设计更安全、电化学性能更优异的SPE提供了个人见解与展望.

Abstract

The solid-state battery with high energy density and safety has become the popular development direction for the next-generation advanced energy storage systems. Solid-state polymer electrolytes (SPEs) have demonstrated the potential with which to replace traditional liquid electrolytes for large-scale commercial applications due to their lightweight features

cost-effectiveness

excellent processability

and intrinsic flame-retardant properties. However

traditional commercial SPEs are limited by their intrinsic electrochemical shortcomings

which make it difficult to meet the stringent performance requirements for electrolyte in current high-energy-density battery. Although gel-type electrolytes and inorganic composite electrolytes prepared by physical processes such as hybridization modification

blend optimization

and doping modulation can partially meet the application requirements of lithium metal batteries (LMBs)

the development of SPEs with intrinsically high ionic conductivity and wide electrochemical windows is still a key scientific proposition in the field of energy storage materials. This review provides a brief overview of recent advances in the field of all-solid-state polymer electrolytes as well as systematically organizes and classifies the mainstream design strategies for novel SPEs. These strategies include the design of multidimensional topologies

anion-anchoring strategies

polymer fluorination engineering

weakly-solvating mainchain construction

and other innovative design concepts. Each chapter presents the novel SPEs developed based on the above strategies and demonstrates their practical application in LMBs. Finally

the paper provides insights into the design of safer SPEs with superior electrochemical performance.

关键词

Keywords

references

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