氯化聚氯乙烯：从改性塑料到功能化应用的研究进展

张龙; 柯其宁; 刘乐文; 陈延安; 邹声文; 秦朋; 郭少云

doi:10.11777/j.issn1000-3304.2025.25109

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氯化聚氯乙烯：从改性塑料到功能化应用的研究进展

综述 | 更新时间：2025-09-25

- 氯化聚氯乙烯：从改性塑料到功能化应用的研究进展
- Advances in Chlorinated Poly(vinyl chloride): from Modification to Functional Applications
- 高分子学报 2025年页码：1-28
- 作者机构：
  
  1.四川大学高分子研究所先进高分子材料全国重点实验室成都 610065
  2.金发科技股份有限公司广州 510663
- 作者简介：
  
  [ "张龙，男，1993年生. 2016年6月于四川大学高分子材料与工程专业毕业，获得学士学位. 2021年6月于华南理工大学材料科学与工程学院毕业，获得博士学位. 2021~2024年在四川大学高分子研究所与金发科技股份有限公司进行联合博士后培养，后在金发科技股份有限公司从事研发工作. 当前研究方向为高分子复合材料的加工及应用，主要围绕(氯化)聚氯乙烯材料的加工应用及其功能化研究." ]
  [ "郭少云，男，1962年生，1992年获四川大学(原成都科技大学)工学博士学位，1993年破格晋升副教授，1995年破格晋升教授，1996年到加拿大Laval大学化工系作高访学者；2005年被评为四川省学术和技术带头人，2016年获国务院政府特殊津贴。作为项目负责人主持了国家自然科学基金重大仪器基金/重点项目/面上项目、国家863、973、国家支撑计划、国防科工委项目、企业合作项目等百余项。主要从事高分子材料加工新技术、新理论研究，尤其在高分子力化学、聚合物成型加工过程中的形态调控、聚合物加工新方法领域取得了系统性的应用研究成果，如：发明了PVC力化学自增塑技术以及PVC力化学原位增容技术；发明了交替层叠复合共挤出技术，实现了高分子功能与结构一体化构造的“中国智造”等." ]
- 基金信息：
  
  广州市/黄埔区博士后科研项目资助
- DOI：10.11777/j.issn1000-3304.2025.25109
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7432
- 收稿日期：2025-04-25，
  
  录用日期：2025-05-27，
  
  网络出版日期：2025-09-25，
- 稿件说明：
移动端阅览
张龙, 柯其宁, 刘乐文, 陈延安, 邹声文, 秦朋, 郭少云. 氯化聚氯乙烯：从改性塑料到功能化应用的研究进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25109

Zhang, L.; Ke, Q. N.; Liu, L. W.; Chen, Y. A.; Zou, S. W.; Qin, P.; Guo, S. Y. Advances in chlorinated poly(vinyl chloride): from modification to functional applications. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2025.25109
张龙, 柯其宁, 刘乐文, 陈延安, 邹声文, 秦朋, 郭少云. 氯化聚氯乙烯：从改性塑料到功能化应用的研究进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25109 DOI： CSTR： 32057.14.GFZXB.2025.7432.

Zhang, L.; Ke, Q. N.; Liu, L. W.; Chen, Y. A.; Zou, S. W.; Qin, P.; Guo, S. Y. Advances in chlorinated poly(vinyl chloride): from modification to functional applications. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2025.25109 DOI： CSTR： 32057.14.GFZXB.2025.7432.

摘要

氯化聚氯乙烯材料由于其独特的物理化学性能，在工业界和学术研究领域都引起了广泛的研究兴趣. 本文从氯化聚氯乙烯的合成与氯化反应机理、早期作为改性塑料的研究、及近期报道氯化聚氯乙烯的功能化应用研究这3个方面展开综述. 重点回顾了国内外氯化聚氯乙烯材料的发展概况，并介绍了氯化聚氯乙烯通过合金化改性的相关研究进展，及其近期在纤维领域、微孔膜、聚合物电解质及在废弃锂电池中金属回收处理等功能化应用中的研究进展，为相关氯化聚氯乙烯材料的研究工作者，及不同应用领域的科研人员开阔新的研究思路. 最后，本文还对氯化聚氯乙烯材料在未来的发展上做出了相应的展望，以促进氯化聚氯乙烯在上游合成领域及下游应用研究领域的多元化、高质量发展.

Abstract

Chlorinated poly(vinyl chloride) (CPVC)

owing to its unique physicochemical properties

has garnered extensive research interest in both industrial and academic fields. This review systematically summarizes CPVC from three key perspectives: (1) synthesis and chlorination mechanisms

(2) early-stage research as a modified plastic

and (3) recent advances in functional applications. A comprehensive overview of the development of CPVC materials globally

chlorination mechanisms

and typical production process (including solution method

gas-solid phase method

and aqueous suspension method) of CPVC have been briefly introduced. Research on the processing and molding of CPVC was summarized. Studies on the physical blending modification of CPVC with various polymers (such as PVC

ABS

and PMMA) were comprehensively reviewed

while progress in chemical modification via graft copolymerization was briefly presented. Additionally

the pyrolysis behavior

flame retardancy

smoke suppression

and aging resistance of CPVC materials were discussed. More importantly

highlighting progress in emerging functional applications

including CPVC fiber and its derivative carbon fiber

CPVC microporous membranes

CPVC-based solid polymer electrolytes

and metal recovery from spent lithium-ion batteries have been systematically reviewed

which indicates that CPVC play a critical role among multidisciplinary research fields. These insights aim to inspire researchers working on CPVC materials and scientists across various application fields. Finally

in this review

an outlook on the future development of CPVC has been proposed

emphasizing the need for diversification and high-quality advancements in both upstream synthesis and downstream applications.

关键词

Keywords

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