聚丁二酸异己糖醇酯的制备与熔融缩聚反应动力学

张耀威; 陈咏; 乌婧; 王华平

doi:10.11777/j.issn1000-3304.2025.25133

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聚丁二酸异己糖醇酯的制备与熔融缩聚反应动力学

研究论文 | 更新时间：2025-08-15

- 聚丁二酸异己糖醇酯的制备与熔融缩聚反应动力学
- Preparation of Poly(isohexides succinate) and Kinetics of Its Melt Polycondensation Reaction
- 高分子学报 2025年页码：1-9
- 作者机构：
  
  1.东华大学，材料科学与工程学院，上海 201620
  2.东华大学，纺织科技创新中心，上海 201620
  3.东华大学，纤维改性材料国家重点实验室，上海 201620
- 作者简介：
  
  E-mail: wuj@dhu.edu.cn
- 基金信息：
  
  中央高校基本科研业务费专项资金(2232025A-08)
- DOI：10.11777/j.issn1000-3304.2025.25133
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7449
- 收稿日期：2025-05-23，
  
  录用日期：2025-07-11，
  
  网络出版日期：2025-08-15，
- 稿件说明：
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张耀威, 陈咏, 乌婧, 王华平. 聚丁二酸异己糖醇酯的制备与熔融缩聚反应动力学. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25133

Zhang, Y. W.; Chen, Y.; Wu, J.; Wang, H. P. Preparation of poly(isohexides succinate) and kinetics of its melt polycondensation reaction. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2025.25133
张耀威, 陈咏, 乌婧, 王华平. 聚丁二酸异己糖醇酯的制备与熔融缩聚反应动力学. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25133 DOI： CSTR： 32057.14.GFZXB.2025.7449.

Zhang, Y. W.; Chen, Y.; Wu, J.; Wang, H. P. Preparation of poly(isohexides succinate) and kinetics of its melt polycondensation reaction. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2025.25133 DOI： CSTR： 32057.14.GFZXB.2025.7449.

摘要

异己糖醇作为一种新型的生物基单体，已被广泛用于聚合物合成，但其反应活性较低，难以合成高分子量的聚合物. 为此，考察其反应动力学规律、建立动力学模型对于理解反应机理和开发更高效的合成技术是十分必要的. 本研究以异山梨醇(IS)、异甘露醇(IM)和丁二酸(SA)为单体，通过熔融酯化缩聚反应制备聚丁二酸异己糖醇酯，并构建酯化和缩聚动力学模型. 结果表明，由于氢键作用，IS/SA体系的酯化率和聚酯分子量均低于IM/SA体系. IS/SA体系的酯化和缩聚活化能分别为93.68和50.09 kJ·mol

-1

. IM/SA体系的酯化和缩聚活化能分别为51.50和64.75 kJ·mol

-1

Abstract

As a new type of bio-based monomer

isosorbide has been widely used in polymer synthesis. However

its reacti

on activity is low

which makes it difficult to produce high molecular weight polymer. Therefore

studying its reaction kinetics and developing a kinetic model are essential to understand the reaction mechanism and enhance synthesis techniques. In this study

isosorbide (IS)

isomannide (IM)

and succinic acid (SA) were used as monomers to prepare poly(isohexides succinate) by esterification and polycondensation melt reaction

and the kinetic models were established. The results show that

due to hydrogen bonding

both the esterification rate and the molecular weight of the IS/SA system are lower than those of the IM/SA system. The activation energies for esterification and polycondensation of the IS/SA system are 93.6 and 50.09 kJ·mol

-1

respectively. For the IM/SA system

the activation energies are 51.5 and 64.75 kJ·mol

-1

关键词

Keywords

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