高填充高分子复合材料成型加工与结构调控研究进展

叶丽军; 沈洁清; 陶莹; 洪佳晖; 李勇进

doi:10.11777/j.issn1000-3304.2025.25209

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高填充高分子复合材料成型加工与结构调控研究进展

综述 | 更新时间：2026-01-19

- 高填充高分子复合材料成型加工与结构调控研究进展
- Research Progress on Processing and Structural Regulation of High-filled Polymer Composites
- 高分子学报 2025年56卷第12期页码：2139-2158
- 作者机构：
  
  杭州师范大学材料与化学化工学院有机硅化学及材料技术教育部重点实验室杭州 311121
- 作者简介：
  
  [ "叶丽军，男，1991年生，理学博士，副教授，硕士生导师. 2013、2016年在杭州师范大学分别获得学士和硕士学位，2021年在德国马克思普朗高分子研究所获得博士学位，同年12月，加入杭州师范大学从事学术研究工作. 主要从事功能高分子及复合材料等研究工作，主持/参与国家自然科学基金项目、浙江省科技厅重点研发计划(尖兵)项目、浙江省高等学校课程思政教学研究项目等研究课题6项，入选杭州市特殊支持计划青年人才. 在Adv. Mater.、Macromolecules、Compos. Sci. Technol.等学术期刊发表SCI论文30余篇，授权国家发明专利1项. E-mail: yelij@hznu.edu.cn " ]
  [ " 李勇进，男，1973年生，工学博士，教授，博士生导师. 1996、1999年在同济大学分别获得学士和硕士学位，2002年在上海交通大学获得博士学位，2002~2003年在日本国立产业技术综合研究所从事JSPS博士后工作，2004、2008年分别晋升为研究员和终身研究员，2010年加入杭州师范大学从事学术研究工作，现任杭州师范大学科研处处长.入选教育部优秀人才计划、浙江省特殊支持计划杰出人才和浙江省海外高层次人才引进计划等，担任中国化学会应用化学学科委员会委员、中国复合材料学会导热复合材料分会委员等职务，兼任J. Polym. Eng.副主编、Compos. Sci. Technol.和Funct. Compos. Mater.等学术期刊编委. 主要从事高分子成型加工、高分子结构性能等研究. 主持国家级科研项目和企业横向合作项目30余项，在Macromolecules、Compos. Sci. Technol.等期刊发表SCI论文160余篇，获美国、日本、中国授权发明专利60余项. 获得教育部自然科学二等奖、浙江省自然科学二等奖(2次)、国际高分子加工学会Morand Lambla奖、高分子加工“新锐”创新奖等荣誉. E-mail: yongjin-li@hznu.edu.cn " ]
- 基金信息：
  
  国家自然科学基金(基金号 ┣U21A20148);52303079┫;浙江省科技厅“尖兵”研发攻关计划(基金号 2024C01047)
- DOI：10.11777/j.issn1000-3304.2025.25209
  中图分类号：
- CSTR：32057.14.GFZXB.2025.7475
- 收稿：2025-08-29，
  
  录用：2025-09-26，
  
  网络出版：2025-11-27，
  
  纸质出版：2025-12-20
- 稿件说明：
移动端阅览
叶丽军, 沈洁清, 陶莹, 洪佳晖, 李勇进. 高填充高分子复合材料成型加工与结构调控研究进展. 高分子学报, 2025, 56(12), 2139-2158

Ye, L. J.; Shen, J. Q.; Tao, Y.; Hong, J. H.; Li, Y. J. Research progress on processing and structural regulation of high-filled polymer composites. Acta Polymerica Sinica, 2025, 56(12), 2139-2158
叶丽军, 沈洁清, 陶莹, 洪佳晖, 李勇进. 高填充高分子复合材料成型加工与结构调控研究进展. 高分子学报, 2025, 56(12), 2139-2158 DOI： 10.11777/j.issn1000-3304.2025.25209. CSTR： 32057.14.GFZXB.2025.7475.

Ye, L. J.; Shen, J. Q.; Tao, Y.; Hong, J. H.; Li, Y. J. Research progress on processing and structural regulation of high-filled polymer composites. Acta Polymerica Sinica, 2025, 56(12), 2139-2158 DOI： 10.11777/j.issn1000-3304.2025.25209. CSTR： 32057.14.GFZXB.2025.7475.

摘要

高填充高分子复合材料在电子封装、生物医学等领域具有广阔应用前景. 功能填料的引入能够显著提升高分子材料的导电性、导热性、阻燃性及电磁屏蔽等性能，但高含量填料往往会降低复合材料的力学性能和加工性能. 本文综述了高填充高分子复合材料在热塑性加工与结构调控方面的研究进展，重点讨论了填料堆积密度的调控及其对成型加工的影响、热塑性加工条件下的填料网络设计，以及可逆动态化学键在基体黏度调控中的应用. 同时，阐述了热塑性高分子复合材料成型加工过程中的结构演变及其调控方法，旨在为高填充复合材料的加工工艺优化和性能提升提供理论指导.

Abstract

High-filled polymer composites hold significant potential in electronics packaging

biomedical applications

and other fields. The incorporation of functional fillers can substantially enhance the electrical conductivity

thermal conductivity

flame retardancy

and electromagnetic shielding performance of polymer materials; however

high filler content often compromises the mechanical properties and processability of the composites. This review summarizes recent advances in the thermoplastic processing and structural design of high-filled polymer composites

with a focus on controlling filler packing density and its influence on processing

the design of filler networks under thermoplastic processing conditions

and the application of reversible dynamic chemical bonds for tuning matrix viscosity. Additionally

the structural evolution during thermoplastic processing and corresponding control strategies are elucidated

aiming to provide theoretical guidance for the optimization of processing techniques and the enhancement of performance in high-filled polymer composites.

关键词

Keywords

references

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