光响应聚合物驱动表面微结构的动态重构机理

武博语; 吴静; 陈佳英; 陈领; 杨玉照; 冯登崇; 袁中柯; 陈旭东

doi:10.11777/j.issn1000-3304.2026.26172

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光响应聚合物驱动表面微结构的动态重构机理

综述 | 更新时间：2026-10-14

- 光响应聚合物驱动表面微结构的动态重构机理
- Dynamic Reconfiguration Mechanism of Surface Microstructures Driven by Photoresponsive Polymers
- 高分子学报 2026年页码：1-24
- 作者机构：
  
  1.广东工业大学轻工化工学院广州 510006
  2.化学与精细化工广东省实验室揭阳分中心揭阳 515200
  3.中山大学化学学院聚合物复合材料及功能材料教育部重点实验室及广东省高性能有机聚合物光电功能薄膜工程技术研究中心广州 510275
- 作者简介：
  
  杨玉照，女，1988年生. 2009年本科毕业于中山大学，2014年博士毕业于中山大学，2014~2017年在中山大学开展博士后研究，2017~2022年在暨南大学信息科学技术学院任副教授，2022年加入广东工业大学轻工化工学院. 主要研究方向为光响应聚合物在光学加密、伪装器件中的应用.
  冯登崇，男，1995年生. 分别在四川大学与中山大学化学学院取得了工学学士(2018年)和博士(2024年)学位. 目前在广东工业大学从事博士后研究，在陈旭东教授的指导下，研究材料的起皱机制及其在先进器件中的应用.
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2026.26172
  中图分类号：
- CSTR：32057.14.GFZXB.2026.7682
- 收稿：2026-05-20，
  
  录用：2026-07-02，
  
  网络首发：2026-10-14，
- 稿件说明：
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武博语, 吴静, 陈佳英, 陈领, 杨玉照, 冯登崇, 袁中柯, 陈旭东. 光响应聚合物驱动表面微结构的动态重构机理. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26172.

Wu, B. Y.; Wu, J.; Chen, J. Y.; Chen, L.; Yang, Y. Z.; Feng, D. C.; Yuan, Z. K.; Chen, X. D. Dynamic reconfiguration mechanism of surface microstructures driven by photoresponsive polymers. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26172.
武博语, 吴静, 陈佳英, 陈领, 杨玉照, 冯登崇, 袁中柯, 陈旭东. 光响应聚合物驱动表面微结构的动态重构机理. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26172. DOI： CSTR： 32057.14.GFZXB.2026.7682.

Wu, B. Y.; Wu, J.; Chen, J. Y.; Chen, L.; Yang, Y. Z.; Feng, D. C.; Yuan, Z. K.; Chen, X. D. Dynamic reconfiguration mechanism of surface microstructures driven by photoresponsive polymers. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26172. DOI： CSTR： 32057.14.GFZXB.2026.7682.

摘要

光响应聚合物驱动的表面微结构，作为可动态重构的智能微纳结构体系，凭借其非接触式调控、可大面积扩展制备等优势，成为微纳加工领域的研究热点. 本综述系统梳理了该领域的研究进展，并对2类核心表面微结构形成机理进行了阐明与比较；一是马兰戈尼流主导的流体质量迁移机理，由表面张力梯度驱动聚合物链定向流动，实现纳米级高精度图案复刻，进而揭示了表面张力、掩膜周期、自由体积与溶剂介导策略对微结构的多维度调控规律；二是模量差(梯度交联)的固体力学失稳机理，通过构建局部模量失配，驱动应力释放诱导力学屈曲，进行微米级大形变与复杂有序表面微结构的制备. 在此基础上进一步总结了上述体系在光学加密、柔性电子领域的前沿应用，最后对现存的精度瓶颈、多刺激协同调控等问题进行了展望.

Abstract

Surface microstructures driven by photoresponsive polymers

as dynamically reconfigurable intelligent micro/nanostructured systems

have emerged as a prominent research hotspot in the field of micro/nanomanufacturing

benefiting from their unique advantages including noncontact manipulation

large-area scalable fabrication and high spatiotemporal resolution. This review systematically summarizes the recent research advances in this thriving field and elaborates as well as systematically compares two core formation mechanisms of surface microstructures. The first is the fluid mass transport mechanism dominated by Marangoni flow

where surface tension gradients drive the directional migration of polymer chains to achieve nanoscale high-fidelity pattern replication. The multidimensional regulation laws of microstructures governed by key factors including surface tension

photomask periodicity

free volume and solvent-mediated strategies are comprehensively revealed. The second refers to the solid mechanical instability mechanism originating from modulus mismatch (gradient crosslinking). By constructing localized modulus mismatch in polymer films

stress relaxation is triggered to induce mechanical buckling

enabling the facile fabrication of microscale large-deformation and complex ordered surface microstructures. On this basis

the state-of-the-art applications of such photoresponsive surface microstructure systems in cutting-edge fields including optical encryption

flexible electronics are further recapitulated. Finally

the existing challenges such as precision bottlenecks and multi-stimulus synergistic regulation are prospected

offering valuable insights for the future development of this promising research area.

关键词

Keywords

references

Bowden N. ; Brittain S. ; Evans A. G. ; Hutchinson J. W. ; Whitesides G. M. Spontaneous formation of ordered structures in thin films of metals supported on an elastomeric polymer . Nature , 1998 , 393 ( 6681 ), 146 - 149 . doi: 10.1038/30193 http://dx.doi.org/10.1038/30193

Niven J. F. ; Chowdhry G. ; Sharp J. S. ; Dalnoki-Veress K. The emergence of local wrinkling or global buckling in thin freestanding bilayer films . Eur. Phys. J. E , 2020 , 43 ( 4 ), 20 . doi: 10.1140/epje/i2020-11946-y http://dx.doi.org/10.1140/epje/i2020-11946-y

Qin D. ; Xia Y. N. ; Whitesides G. M. Soft lithography for micro- and nanoscale patterning . Nat. Protoc. , 2010 , 5 ( 3 ), 491 - 502 . doi: 10.1038/nprot.2009.234 http://dx.doi.org/10.1038/nprot.2009.234

Natansohn A. ; Rochon P. Photoinduced motions in azo-containing polymers . ChemInform , 2003 , 34 ( 4 ), 200304235 . doi: 10.1002/chin.200304235 http://dx.doi.org/10.1002/chin.200304235

Ichimura K. ; Oh S. K. ; Nakagawa M. Light-driven motion of liquids on a photoresponsive surface . Science , 2000 , 288 ( 5471 ), 1624 - 1626 . doi: 10.1126/science.288.5471.1624 http://dx.doi.org/10.1126/science.288.5471.1624

Probst C. ; Meichner C. ; Kreger K. ; Kador L. ; Neuber C. ; Schmidt H. W. Athermal azobenzene-based nanoimprint lithography . Adv. Mater. , 2016 , 28 ( 13 ), 2624 - 2628 . doi: 10.1002/adma.201505552 http://dx.doi.org/10.1002/adma.201505552

Kim H. ; Li J. ; Hsieh Y. S. Y. ; Cho M. ; Ahn S. H. ; Li C. Z. Photo-programmed deformations in rigid liquid crystalline polymers triggered by body temperature . Small , 2022 , 18 ( 44 ), 2203772 . doi: 10.1002/smll.202203772 http://dx.doi.org/10.1002/smll.202203772

Li F. D. ; Hou H. H. ; Yin J. ; Jiang X. S. Multi-responsive wrinkling patterns by the photoswitchable supramolecular network . ACS Macro Lett. , 2017 , 6 ( 8 ), 848 - 853 . doi: 10.1021/acsmacrolett.7b00424 http://dx.doi.org/10.1021/acsmacrolett.7b00424

Zeng S. S. ; Liu Y. ; Li S. L. ; Shen K. Y. ; Hou Z. L. ; Chooi A. P. ; Smith A. T. ; Chen Z. ; Sun L. Y. Smart laser-writable micropatterns with multiscale photo/moisture reconstructible structure . Adv. Funct. Mater. , 2021 , 31 ( 10 ), 2009481 . doi: 10.1002/adfm.202009481 http://dx.doi.org/10.1002/adfm.202009481

Yu H. F. ; Dong C. ; Zhou W. M. ; Kobayashi T. ; Yang H. Wrinkled liquid-crystalline microparticle-enhanced photoresponse of PDLC-like films by coupling with mechanical stretching . Small , 2011 , 7 ( 21 ), 3039 - 3045 . doi: 10.1002/smll.201101098 http://dx.doi.org/10.1002/smll.201101098

Yang B. W. ; Cai F. ; Huang S. ; Yu H. F. Athermal and soft multi-nanopatterning of azopolymers: phototunable mechanical properties . Angew. Chem. Int. Ed. , 2020 , 59 ( 10 ), 4035 - 4042 . doi: 10.1002/anie.201914201 http://dx.doi.org/10.1002/anie.201914201

Han L. ; Si J. W. ; Zhu B. ; Wang R. ; Wu C. G. ; Guo M. M. A multidirectional locomotion light-driven soft crawling robot . Adv. Funct. Mater. , 2023 , 33 ( 45 ), 2305046 . doi: 10.1002/adfm.202305046 http://dx.doi.org/10.1002/adfm.202305046

Liu E. P. ; Zhang X. L. ; Ji H. P. ; Li Q. F. ; Li L. L. ; Wang J. J. ; Han X. ; Yu S. X. ; Xu F. ; Cao Y. P. ; Lu C. H. Polarization-dependent ultrasensitive dynamic wrinkling on floating films induced by photo-orientation of azopolymer . Angew. Chem. Int. Ed. , 2022 , 61 ( 31 ), e 202203715 . doi: 10.1002/anie.202203715 http://dx.doi.org/10.1002/anie.202203715

Bush K. ; Rolston N. ; Gold-Parker A. ; Manzoor S. ; Hausele J. ; Yu Z. J. ; Raiford J. A. ; Cheacharoen R. ; Holman Z. C. ; Toney M. F. ; Dauskardt R. H. ; McGehee M. D. Controlling thin-film stress and wrinkling during perovskite film formation . ACS Energy Lett. , 2018 , 3 ( 6 ), 1225 - 1232 . doi: 10.1021/acsenergylett.8b00544 http://dx.doi.org/10.1021/acsenergylett.8b00544

Chen T. L. ; Huang C. Y. ; Xie Y. T. ; Chiang Y. Y. ; Chen Y. M. ; Hsueh H. Y. Bioinspired durable superhydrophobic surface from a hierarchically wrinkled nanoporous polymer . ACS Appl. Mater. Interfaces , 2019 , 11 ( 43 ), 40875 - 40885 . doi: 10.1021/acsami.9b14325 http://dx.doi.org/10.1021/acsami.9b14325

Su P. ; Shalaginov M. ; Gu T. ; An S. S. ; Li D. H. ; Li L. ; Jiang H. ; Joo S. ; Kimerling L. ; Zhang H. L. ; Hu J. J. ; Agarwal A. Large-area optical metasurface fabrication using nanostencil lithography . Opt. Lett. , 2021 , 46 ( 10 ), 2324 - 2327 . doi: 10.1364/ol.424535 http://dx.doi.org/10.1364/ol.424535

Jeon H. ; Noh J. ; Jo M. ; Joo C. ; Jo J. ; Lee C. Layer-by-layer engineered flexible functional film fabrication with spreadability control in roll-to-roll manufacturing . Polymers , 2023 , 15 ( 11 ), 2478 . doi: 10.3390/polym15112478 http://dx.doi.org/10.3390/polym15112478

Gao X. X. ; Li J. ; Li T. T. ; Su Z. L. ; Ma X. D. ; Yin J. ; Jiang X. S. Photo-polymerization induced hierarchical pattern via self-wrinkling . Adv. Funct. Mater. , 2021 , 31 ( 49 ), 2106754 . doi: 10.1002/adfm.202106754 http://dx.doi.org/10.1002/adfm.202106754

Sarabia-Vallejos M. A. ; Cerda-Iglesias F. E. ; Pérez-Monje D. A. ; Acuña-Ruiz N. F. ; Terraza-Inostroza C. A. ; Rodríguez-Hernández J. ; González-Henríquez C. M. Smart polymer surfaces with complex wrinkled patterns: reversible, non-planar, gradient, and hierarchical structures . Polymers , 2023 , 15 ( 3 ), 612 . doi: 10.3390/polym15030612 http://dx.doi.org/10.3390/polym15030612

Su Y. ; Zhang B. L. ; Sun R. W. ; Liu W. F. ; Zhu Q. B. ; Zhang X. ; Wang R. R. ; Chen C. P. PLGA-based biodegradable microspheres in drug delivery: recent advances in research and application . Drug Deliv. , 2021 , 28 ( 1 ), 1397 - 1418 . doi: 10.1080/10717544.2021.1938756 http://dx.doi.org/10.1080/10717544.2021.1938756

Yang B. W. ; Ji Y. F. ; Cai F. ; Yu H. F. Surface morphing of azopolymers toward advanced anticounterfeiting enabled by a two-step method: light writing and then reading in liquid . ACS Appl. Mater. Interfaces , 2023 , 15 ( 19 ), 23804 - 23812 . doi: 10.1021/acsami.3c03807 http://dx.doi.org/10.1021/acsami.3c03807

Ji Y. F. ; Yang B. W. ; Cai F. ; Song T. F. ; Yu H. F. Steerable mass transport in a photoresponsive system for advanced anticounterfeiting . IScience , 2024 , 27 ( 2 ), 108790 . doi: 10.1016/j.isci.2024.108790 http://dx.doi.org/10.1016/j.isci.2024.108790

Jiang B. L. ; Liu L. T. ; Gao Z. P. ; Feng Z. Y. ; Zheng Y. Q. ; Wang W. S. Fast dual-stimuli-responsive dynamic surface wrinkles with high bistability for smart windows and rewritable optical displays . ACS Appl. Mater. Interfaces , 2019 , 11 ( 43 ), 40406 - 40415 . doi: 10.1021/acsami.9b10747 http://dx.doi.org/10.1021/acsami.9b10747

Zhou L. W. ; Ma T. J. ; Li T. T. ; Ma X. D. ; Yin J. ; Jiang X. S. Dynamic interpenetrating polymer network (IPN) strategy for multiresponsive hierarchical pattern of reversible wrinkle . ACS Appl. Mater. Interfaces , 2019 , 11 ( 17 ), 15977 - 15985 . doi: 10.1021/acsami.8b22216 http://dx.doi.org/10.1021/acsami.8b22216

Ma T. J. ; Li T. T. ; Zhou L. W. ; Ma X. D. ; Yin J. ; Jiang X. S. Dynamic wrinkling pattern exhibiting tunable fluorescence for anticounterfeiting applications . Nat. Commun. , 2020 , 11 , 1811 . doi: 10.1038/s41467-020-15600-6 http://dx.doi.org/10.1038/s41467-020-15600-6

Lim S. I. ; Jang E. ; Yu D. M. ; Koo J. ; Kang D. G. ; Lee K. M. ; Godman N. P. ; McConney M. E. ; Kim D. Y. ; Jeong K. U. When chirophotonic film meets wrinkles: viewing angle independent corrugated photonic crystal paper . Adv. Mater. , 2023 , 35 ( 1 ), 2206764 . doi: 10.1002/adma.202370004 http://dx.doi.org/10.1002/adma.202370004

Wang W. ; Gao F. ; Yao Y. ; Lin S. L. Directional photo-manipulation of self-assembly patterned microstructures . Chinese J. Polym. Sci. , 2018 , 36 ( 3 ), 297 - 305 . doi: 10.1007/s10118-018-2087-x http://dx.doi.org/10.1007/s10118-018-2087-x

Wei P. ; Zhang W. ; Zhang Y. F. ; Wang Y. Z. ; Guo Z. ; Yu H. Q. ; Xia Y. M. ; Wang Y. P. ; Wang Y. M. Direct synthesis of potentially biodegradable aromatic-aliphatic thermotropic copolyesters with photocrosslinking properties . Liq. Cryst. , 2019 , 46 ( 12 ), 1780 - 1789 . doi: 10.1080/02678292.2019.1600751 http://dx.doi.org/10.1080/02678292.2019.1600751

Chen Q. B. ; Cui L. ; Guan Y. ; Zhang Y. J. Diels-alder cross-linked, washing-free hydrogel films with ordered wrinkling patterns for multicellular spheroid generation . Biomacromolecules , 2021 , 22 ( 8 ), 3474 - 3485 . doi: 10.1021/acs.biomac.1c00570 http://dx.doi.org/10.1021/acs.biomac.1c00570

Stafford C. M. ; Harrison C. ; Beers K. L. ; Karim A. ; Amis E. J. ; VanLandingham M. R. ; Kim H. C. ; Volksen W. ; Miller R. D. ; Simonyi E. E. A buckling-based metrology for measuring the elastic moduli of polymeric thin films . Nat. Mater. , 2004 , 3 ( 8 ), 545 - 550 . doi: 10.1038/nmat1175 http://dx.doi.org/10.1038/nmat1175

Zhu P. ; Song Q. C. ; Bhagwat S. ; Mayoussi F. ; Goralczyk A. ; Nekoonam N. ; Sanjaya M. ; Hou P. L. ; Tisato S. ; Kotz-Helmer F. ; Helmer D. ; Rapp B. E. Generation of precision microstructures based on reconfigurable photoresponsive hydrogels for high-resolution polymer replication and microoptics . Nat. Commun. , 2024 , 15 , 5673 . doi: 10.1038/s41467-024-50008-6 http://dx.doi.org/10.1038/s41467-024-50008-6

Yuan W. Q. ; Deng X. L. ; Wang Z. H. ; Ma T. J. ; Yan S. Z. ; Gao X. X. ; Li J. ; Ma X. D. ; Yin J. ; Hu K. M. ; Zhang W. M. ; Jiang X. S. Photochemical design for diverse controllable patterns in self-wrinkling films . Adv. Mater. , 2024 , 36 ( 25 ), 2400849 . doi: 10.1002/adma.202400849 http://dx.doi.org/10.1002/adma.202400849

Chen S. ; Ma T. J. ; Bai J. ; Ma X. D. ; Yin J. ; Jiang X. S. Photodynamic pattern memory surfaces with responsive wrinkled and fluorescent patterns . Adv. Sci. , 2020 , 7 ( 22 ), 2002372 . doi: 10.1002/advs.202002372 http://dx.doi.org/10.1002/advs.202002372

Zhou H. W. ; Xue C. G. ; Weis P. ; Suzuki Y. ; Huang S. L. ; Koynov K. ; Auernhammer G. K. ; Berger R. ; Butt H. J. ; Wu S. Photoswitching of glass transition temperatures of azobenzene-containing polymers induces reversible solid-to-liquid transitions . Nat. Chem. , 2017 , 9 ( 2 ), 145 - 151 . doi: 10.1038/nchem.2625 http://dx.doi.org/10.1038/nchem.2625

Bin Kim C. ; Wistrom J. C. ; Ha H. ; Zhou S. X. ; Katsumata R. ; Jones A. R. ; Janes D. W. ; Miller K. M. ; Ellison C. J. Marangoni instability driven surface relief grating in an azobenzene-containing polymer film . Macromolecules , 2016 , 49 ( 18 ), 7069 - 7076 . doi: 10.1021/acs.macromol.6b01848 http://dx.doi.org/10.1021/acs.macromol.6b01848

Takeshima T. ; Liao W. Y. ; Nagashima Y. ; Beppu K. ; Hara M. ; Nagano S. ; Seki T. Photoresponsive surface wrinkle morphologies in liquid crystalline polymer films . Macromolecules , 2015 , 48 ( 18 ), 6378 - 6384 . doi: 10.1021/acs.macromol.5b01577 http://dx.doi.org/10.1021/acs.macromol.5b01577

Guan X. H. ; Sarma A. P. ; Kakarla Hamesh E. ; Yang J. Y. ; Nguyen N. ; Cerda E. ; Pocivavsek L. ; Velankar S. S. Compression-induced buckling of thin films bonded to viscous substrates: uniform wrinkles vs localized ridges . Int. J. Solids Struct. , 2022 , 254 - 255 , 111843 .

Kwak H. ; Lee J. ; Kim J. ; Jo H. ; Ki K. ; Lee A. Wrinkling of thin films in pre-stretched soft substrate trilayers . Int. J. Mech. Sci. , 2026 , 312 , 111213 . doi: 10.1016/j.ijmecsci.2026.111213 http://dx.doi.org/10.1016/j.ijmecsci.2026.111213

Usgaonkar S. S. ; Ellison C. J. ; Kumar S. Controlling surface deformation and feature aspect ratio in photochemically induced Marangoni patterning of polymer films . Langmuir , 2022 , 38 ( 24 ), 7400 - 7412 . doi: 10.1021/acs.langmuir.2c00179 http://dx.doi.org/10.1021/acs.langmuir.2c00179

Shenvi Usgaonkar S. ; Ellison C. J. ; Kumar S. Photochemically induced Marangoni patterning of polymer bilayers . Langmuir , 2023 , 39 ( 17 ), 5970 - 5978 . doi: 10.1021/acs.langmuir.2c03295 http://dx.doi.org/10.1021/acs.langmuir.2c03295

Stanley S. K. ; Bonnecaze R. T. Fundamental limits of Marangoni-driven patterning . Colloids Surf. A Physicochem. Eng. Aspects , 2020 , 603 , 125217 . doi: 10.1016/j.colsurfa.2020.125217 http://dx.doi.org/10.1016/j.colsurfa.2020.125217

Erekath S. ; Kalpathy S. K. Photochemically assisted patterning: an interfacial hydrodynamic model perspective . Int. Commun. Heat Mass Transf. , 2022 , 134 , 106031 . doi: 10.1016/j.icheatmasstransfer.2022.106031 http://dx.doi.org/10.1016/j.icheatmasstransfer.2022.106031

Bai J. ; Hu K. M. ; Zhang L. Z. ; Shi Z. X. ; Zhang W. M. ; Yin J. ; Jiang X. S. The evolution of self-wrinkles in a single-layer gradient polymer film based on viscoelasticity . Macromolecules , 2022 , 55 ( 9 ), 3563 - 3572 . doi: 10.1021/acs.macromol.1c02574 http://dx.doi.org/10.1021/acs.macromol.1c02574

Zhang L. Z. ; Jiang X. S. Time-dependent wrinkle pattern based on photo-controlled stress relaxation for multi-level information encryption and information camouflage . Adv. Funct. Mater. , 2024 , 34 ( 49 ), 2408932 . doi: 10.1002/adfm.202408932 http://dx.doi.org/10.1002/adfm.202408932

Qian J. ; Zhang L. Z. ; Wang Z. H. ; Wu S. J. ; Jiang X. S. ; Lin S. L. ; Yao Y. Multiple regulation of dynamic wrinkles based on conjugated copolymer network . Sci. China Mater. , 2024 , 67 ( 1 ), 363 - 371 . doi: 10.1007/s40843-023-2684-3 http://dx.doi.org/10.1007/s40843-023-2684-3

Liang K. X. ; Feng W. S. ; Liu Y. Y. ; Zhang J. Q. ; Tian F. ; Yao Y. ; Jiang X. S. ; Lin S. L. "All-in-one functionalization and synergic ordering" strategy enables multimode anti-counterfeiting patterns . ACS Appl. Mater. Interfaces , 2025 , 17 ( 14 ), 21866 - 21874 . doi: 10.1021/acsami.5c02062 http://dx.doi.org/10.1021/acsami.5c02062

Byun M. Periodically ordered wrinkles in gradient patterned polymer stripes . Materials , 2024 , 17 ( 24 ), 6035 . doi: 10.3390/ma17246035 http://dx.doi.org/10.3390/ma17246035

Lee J. H. ; Chang W. J. ; Choi W. Y. ; Park J. M. ; Jang J. I. ; Park W. I. Direct nanofluidic channels via hardening and wrinkling of thin polymer films . Nanoscale , 2020 , 12 ( 32 ), 16895 - 16900 . doi: 10.1039/d0nr04032k http://dx.doi.org/10.1039/d0nr04032k

Xue L. L. ; Xiong X. H. ; Krishnan B. P. ; Puza F. ; Wang S. ; Zheng Y. J. ; Cui J. X. Light-regulated growth from dynamic swollen substrates for making rough surfaces . Nat. Commun. , 2020 , 11 , 963 . doi: 10.1038/s41467-020-14807-x http://dx.doi.org/10.1038/s41467-020-14807-x

Yan S. Z. ; Deng X. L. ; Chen S. ; Ma T. J. ; Li T. T. ; Hu K. M. ; Jiang X. S. Deformation-induced photoprogrammable pattern of polyurethane elastomers based on Poisson effect . Adv. Mater. , 2024 , 36 ( 9 ), 2307445 . doi: 10.1002/adma.202307445 http://dx.doi.org/10.1002/adma.202307445

Weis P. ; Tian W. ; Wu S. Frontispiece: photoinduced liquefaction of azobenzene-containing polymers . Chem. , 2018 , 24 ( 25 ), chem . 201882562 . doi: 10.1002/chem.201882562 http://dx.doi.org/10.1002/chem.201882562

Rekola H. ; Berdin A. ; Fedele C. ; Virkki M. ; Priimagi A. Digital holographic microscopy for real-time observation of surface-relief grating formation on azobenzene-containing films . Sci. Rep. , 2020 , 10 , 19642 . doi: 10.1038/s41598-020-76573-6 http://dx.doi.org/10.1038/s41598-020-76573-6

Su X. X. ; Bei R. X. ; Feng D. C. ; Guo Q. ; Gong L. ; Yang Y. Z. ; Zhong S. L. ; Yuan Z. K. ; Zhang Z. S. ; Chen X. D. Dynamic surface gratings for optical encryption: a simple approach based on azobenzene photoisomerization and solvent engineering . Chem. Eng. J. , 2024 , 497 , 154589 . doi: 10.1016/j.cej.2024.154589 http://dx.doi.org/10.1016/j.cej.2024.154589

Xu Y. L. ; Wu S. T. ; Jin H. J. ; Wu Z. Y. ; Wu T. Y. ; Cai W. N. ; Xiao W. ; Qian Q. R. ; Chen Q. H. ; Yan Y. Flexible and self-healable fluorescent films with tunable emission via solid-phase molecular self-assembly design . Adv. Opt. Mater. , 2025 , 13 ( 4 ), 2402258 . doi: 10.1002/adom.202402258 http://dx.doi.org/10.1002/adom.202402258

Zhang L. Z. ; Bai J. ; Ma T. J. ; Yin J. ; Jiang X. S. Intelligent surface with multi-dimensional information enabled by a dual responsive pattern with fluorescence and wrinkle . Macromolecules , 2022 , 55 ( 15 ), 6405 - 6414 . doi: 10.1021/acs.macromol.2c01137 http://dx.doi.org/10.1021/acs.macromol.2c01137

Liu Q. H. ; Zheng Y. ; Wu H. T. ; Michalek L. ; Ronchini M. ; Mow R. K. ; Wang W. C. ; Park H. ; Ji X. Z. ; Yu Z. A. ; Yao Z. F. ; Nishio Y. ; Zhao C. Z. ; Pei J. ; Bao Z. N. Intrinsically stretchable complementary circuits based on direct photo-patternable polymer semiconductors . Nat. Electron. , 2026 , 9 ( 5 ), 507 - 518 . doi: 10.1038/s41928-026-01599-z http://dx.doi.org/10.1038/s41928-026-01599-z

Zhou L. W. ; Yang L. L. ; Liu Y. ; Xu Z. ; Yin J. ; Ge D. T. ; Jiang X. S. Dynamic structural color from wrinkled thin films . Adv. Opt. Mater. , 2020 , 8 ( 12 ), 2000234 . doi: 10.1002/adom.202000234 http://dx.doi.org/10.1002/adom.202000234

Hu K. M. ; Liu Y. Q. ; Zhou L. W. ; Xue Z. Y. ; Peng B. ; Yan H. ; Di Z. F. ; Jiang X. S. ; Meng G. ; Zhang W. M. Delamination-free functional graphene surface by multiscale, conformal wrinkling . Adv. Funct. Mater. , 2020 , 30 ( 34 ), 2003273 . doi: 10.1002/adfm.202003273 http://dx.doi.org/10.1002/adfm.202003273

Zhu C. Y. ; Lu Y. ; Sun J. H. ; Yu Y. L. Dynamic interfacial regulation by photodeformable azobenzene-containing liquid crystal polymer micro/nanostructures . Langmuir , 2020 , 36 ( 24 ), 6611 - 6625 . doi: 10.1021/acs.langmuir.0c00582 http://dx.doi.org/10.1021/acs.langmuir.0c00582

Rodriguez F. ; Jelken J. ; Delpouve N. ; Laurent A. ; Garnier B. ; Duvail J. L. ; Lagugné-Labarthet F. ; Ishow E. Exploiting light interferences to generate micrometer-high superstructures from monomeric azo materials with extensive orientational mobility . Adv. Opt. Mater. , 2021 , 9 ( 19 ), 2100525 . doi: 10.1002/adom.202100525 http://dx.doi.org/10.1002/adom.202100525

Wang J. J. ; Han X. ; Ji H. P. ; Lu C. H. Light-associated surface wrinkling-based metrology for the photosoftening characterization in azobenzene-polymer supramolecular complexes . Macromol. Rapid Commun. , 2021 , 42 ( 7 ), 2000704 . doi: 10.1002/marc.202000704 http://dx.doi.org/10.1002/marc.202000704

Chen C. X. ; Ji Y. F. ; Li H. M. ; Song T. F. ; Yu H. F. Unusual photo-tunable mechanical transformation of azobenzene terminated aliphatic polycarbonate . Nat. Commun. , 2025 , 16 ( 1 ), 2620 . doi: 10.1038/s41467-025-57608-w http://dx.doi.org/10.1038/s41467-025-57608-w

Park J. G. ; Jeong Y. H. ; Ji S. ; Bae J. ; Zhou Q. T. ; Kim T. Multimodal wrinkle micro-nanoarchitectonics by patterned surface material properties for transformative structural coloration . Adv. Opt. Mater. , 2023 , 11 ( 16 ), 2300279 . doi: 10.1002/adom.202300279 http://dx.doi.org/10.1002/adom.202300279

Tokudome Y. ; Kuniwaki H. ; Suzuki K. ; Carboni D. ; Poologasundarampillai G. ; Takahashi M. Thermoresponsive wrinkles on hydrogels for soft actuators . Adv. Mater. Interfaces , 2016 , 3 ( 12 ), 1500802 . doi: 10.1002/admi.201670054 http://dx.doi.org/10.1002/admi.201670054

Ji Y. F. ; Song T. F. ; Yu H. F. Assembly-induced dynamic structural color in a host-guest system for time-dependent anticounterfeiting and double-lock encryption . Angew. Chem. Int. Ed. , 2024 , 63 ( 26 ), e 202401208 . doi: 10.1002/anie.202401208 http://dx.doi.org/10.1002/anie.202401208

纪宇帆 , 蔡锋 , 于海峰 . 液晶聚合物的表面形貌光调控研究进展 . 应用化学 , 2021 , 38 ( 10 ), 1226 - 1237 . doi: 10.19894/j.issn.1000-0518.210381 http://dx.doi.org/10.19894/j.issn.1000-0518.210381

Zhong S. L. ; Zhu Z. X. ; Huo Q. Z. ; Long Y. B. ; Gong L. ; Ma Z. T. ; Yu D. S. ; Zhang Y. ; Liang W. E. ; Liu W. ; Wang C. ; Yuan Z. K. ; Yang Y. Z. ; Lu S. L. ; Chen Y. J. ; Zheng Z. K. ; Chen X. D. Designed wrinkles for optical encryption and flexible integrated circuit carrier board . Nat. Commun. , 2024 , 15 , 5616 . doi: 10.1038/s41467-024-50069-7 http://dx.doi.org/10.1038/s41467-024-50069-7

Su X. X. ; Xu H. F. ; Guo Q. ; Bei R. X. ; Gong L. ; Yang Y. Z. ; Yuan Z. K. ; Lu S. L. ; Feng D. C. ; Zhang Z. S. ; Chen X. D. Chain and condensed state structure-directed fabrication of dynamic surface gratings in azopolymers for invisible patterns and multi-modal anti-counterfeiting . Sci. China Chem. , 2025 , 68 ( 11 ), 5930 - 5941 . doi: 10.1007/s11426-025-2743-4 http://dx.doi.org/10.1007/s11426-025-2743-4

Feng D. C. ; Guo Q. ; Huang Z. J. ; Zhou B. Y. ; Gong L. ; Lu S. L. ; Yang Y. Z. ; Yu D. S. ; Zheng Z. K. ; Chen X. D. Viscoelasticity-controlled relaxation in wrinkling surface for multistage time-resolved optical information encryption . Adv. Mater. , 2024 , 36 ( 23 ), 2314201 . doi: 10.1002/adma.202314201 http://dx.doi.org/10.1002/adma.202314201

Liu J. ; Li M. F. ; Yang Y. Z. ; Xu L. R. ; Lin J. J. ; Hong W. ; Chen X. D. Metal conductive surface patterning on photoactive polyimide . Adv. Funct. Mater. , 2017 , 27 ( 33 ), 1701674 . doi: 10.1002/adfm.201701674 http://dx.doi.org/10.1002/adfm.201701674

Arshad T. A. ; Bin Kim C. ; Prisco N. A. ; Katzenstein J. M. ; Janes D. W. ; Bonnecaze R. T. ; Ellison C. J. Precision Marangoni-driven patterning . Soft Matter , 2014 , 10 ( 40 ), 8043 - 8050 . doi: 10.1039/c4sm01284d http://dx.doi.org/10.1039/c4sm01284d

Kitamura I. ; Kato K. ; Berk R. B. ; Nakai T. ; Hara M. ; Nagano S. ; Seki T. Photo-triggered large mass transport driven only by a photoresponsive surface skin layer . Sci. Rep. , 2020 , 10 ( 1 ), 12664 . doi: 10.1038/s41598-020-69605-8 http://dx.doi.org/10.1038/s41598-020-69605-8

Katzenstein J. M. ; Janes D. W. ; Cushen J. D. ; Hira N. B. ; McGuffin D. L. ; Prisco N. A. ; Ellison C. J. Patterning by photochemically directing the Marangoni effect . ACS Macro Lett. , 2012 , 1 ( 10 ), 1150 - 1154 . doi: 10.1021/mz300400p http://dx.doi.org/10.1021/mz300400p

Feng W. ; Chu L. Y. ; de Rooij M. B. ; Liu D. Q. ; Broer D. J. Photoswitching between water-tolerant adhesion and swift release by inverting liquid crystal fingerprint topography . Adv. Sci. , 2021 , 8 ( 8 ), 2004051 . doi: 10.1002/advs.202004051 http://dx.doi.org/10.1002/advs.202004051

Hou H. H. ; Yin J. ; Jiang X. S. Smart patterned surface with dynamic wrinkles . Acc. Chem. Res. , 2019 , 52 ( 4 ), 1025 - 1035 . doi: 10.1021/acs.accounts.8b00623 http://dx.doi.org/10.1021/acs.accounts.8b00623

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