CHEN CHIH-CHING. THE CONDITION OF GELATION FOR THREE DIMENSIONAL POLYCONDENSATION AND COPOLYCONDENSATION REACTIONS[J]. Acta Polymerica Sinica, 1964,6(2):124-129.
CHEN CHIH-CHING. THE CONDITION OF GELATION FOR THREE DIMENSIONAL POLYCONDENSATION AND COPOLYCONDENSATION REACTIONS[J]. Acta Polymerica Sinica, 1964,6(2):124-129.DOI:
A simple and general method for evaluating the condition of gelation for three dimensional polycondensation and copolycondensation reactions is presented. By reasonable development of Flory's method
the author suggested a new concept for the critical condition of gelation
namely
that the probability for a central branch point to be connected to themselves attains unity. According to this concept without referring to the molecular size distribution function
equations for the gel point for various generalized reaction types were obtained
which include almost all types of reactions encountered in practce. The results previously obtained by other authors appear as special cases of this paper.