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纸质出版日期:1964-4-20,
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邓澧儒, 钱人元. 声速法测定纤维的取向度[J]. 高分子学报, 1964,6(2):117-123.
DENG LI-RHU, CHIEN JEN-YUAN. DETERMINATION OF THE DEGREE OF ORIENTATION OF NYLON 6 FIBRES BY SOUND VELOCITY METHOD[J]. Acta Polymerica Sinica, 1964,6(2):117-123.
纤维具有声学的各向异性
声波通过纤维的速度与纤维中高分子链的取向程度有关。测定声波沿纤维轴方向的传播速度可以计算纤维的取向度α: α=1-C2u/C2其中C及Cu分别为声波通过取向及无规取向纤维的速度。 实验仪器采用每秒100次的脉冲电流输至高音喇叭的音圈
纤维通过弹簧夹子与喇叭振膜的中心相耦合。脉冲电流激发喇叭振膜振动系统
使产生逐渐衰减的固有频率振动(约4000赫)。离振源200厘米处的纤维另一端有拾音器
其输出讯号接至由脉冲电压触发扫描的脉冲示波器
从示波器可以观察到从振源到拾音器的距离间声波在纤维中的传播时间
由此计算出声波通过纤维的速度。 纤维的吸湿性与所受张力不同对其力学性貭均有影响
因此研究了相对湿度与张力对纤维中声速的影响
并选择了在室温(约30℃)
相对湿度为60%和在小于纤维的临界杨氏模量的作用张力下进行声速法测定纤维的取向度。 研究了不同拉伸程度单纤维样品的声波传播速度
并外推到长度拉伸比为1时作为声波通过无规取向纤维的速度。实验结果表明
尼龙6纤维的取向度经拉伸与后处理逐渐增大至80%左右。 测定了不同品种的尼龙6纤维的取向度
具有较大强度的纤维其取向度较大。
The sound velocity in a fibre shows a pronounced anisotropy,that is,the sound velo-city along the axis of an oriented fibre is much greater than that perpendicular to it,and therefore it may be used as a measure of the molecular orientation a in the fibre, α=1-C2u-C2 where C and Cu are velocities of sound along an oriented fibre and a completely un-oriented fibre respectively.The apparatus used consisted of a pulse generator which sends a pulse of 70~tsec duration with a repetition frequency of 100 times per second to the moving coil of a loud speaker.The fibre was coupled to the vibrating membrane through a spring clamp.When exited by the pulse,the system underwent damped oscillation with a natural frequency of about 4000 Hz.At the other end of the fibre,about 200 cm from the clamp,a crystal pick-up was located,the output of which was sent to an oscilloscope with the sweep circuit triggered by the pulse voltage.The time of propagation of the longitudinal vibration along the fibre from the clamp to the pick-up was observed from the oscilloscope record,and the sound velocity in.the fibre calculated. Since the mechanical properties of fibre depend considerably on the moisture regain and tension,the effect of relative humidity and tension in the fibre on the sound velocity were studied.The best choice of the experimental conditions for the determination of molecular orientation by the sound velocity method appears to be the following:room tempera-ture,28—30℃;relative humidity,60%;and under a tension somewhat below the cri-tical Young’s modulus of the fibre.The sound velocities in the fibres of different draw ratios (r) were determined and extrapolated to r=1 to give the value for Gu Experimental results indicate that the degree of molecular orientation of monofils of Nylon 6 increases to approximately 80% after drawing and after-treatment.The degree of orientation for several products of Nylon 6 fibre such as yarns,mono-fils,and cords was determined.Fibres that possess greater breaking length show higher degree of orientation.
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