Wu Ho-jung, Wang Bin-fang, Hu Fu-zhen, LI Shi-jin. DETERMINATION OF FUSION THERMODYNAMIC PARAMETERS OF CRYSTALLINE POLYEPICHLOROHYDRIN[J]. Acta Polymerica Sinica, 1985,(1):47-49.
Wu Ho-jung, Wang Bin-fang, Hu Fu-zhen, LI Shi-jin. DETERMINATION OF FUSION THERMODYNAMIC PARAMETERS OF CRYSTALLINE POLYEPICHLOROHYDRIN[J]. Acta Polymerica Sinica, 1985,(1):47-49.DOI:
The thermodynamic parameters of fusion of polyepichlorohydrin were investigated by Flory's method based on the melting point decrease for polymer diluent mixtures. Toluene
α-chloronahthalene and nitrobenzene were used as diluents.The equilibrium melting temperature was obtained by extrapolating the "kinetic" melting points
measured on polymers crystallized at various temperatures.The equilibrium melting temperature
fusion enthalpy and fusion entropy obtained are 116℃