含胺基功能基团单体的聚合研究——Ⅸ.脂肪叔胺基N-取代丙烯酰胺作为氧化还原引发体系组分的研究

李福绵; 丁一卫; 王林; 冯新德

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含胺基功能基团单体的聚合研究——Ⅸ.脂肪叔胺基N-取代丙烯酰胺作为氧化还原引发体系组分的研究

研究简报 | 更新时间：2021-03-19

- 含胺基功能基团单体的聚合研究——Ⅸ.脂肪叔胺基N-取代丙烯酰胺作为氧化还原引发体系组分的研究
- STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUPS Ⅸ. Study on the use of aliphatic tertiary ammo-group N-substituted acrylamides as a component of redox initiator system
- 高分子学报 1985年第5期页码：393-396
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- 纸质出版日期：1985-10-20，
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李福绵, 丁一卫, 王林, 冯新德. 含胺基功能基团单体的聚合研究——Ⅸ.脂肪叔胺基N-取代丙烯酰胺作为氧化还原引发体系组分的研究[J]. 高分子学报, 1985,(5):393-396.

LI Fu-mian, DING Yi-wei, WANG Lin, FENG Xin-de. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUPS Ⅸ. Study on the use of aliphatic tertiary ammo-group N-substituted acrylamides as a component of redox initiator system[J]. Acta Polymerica Sinica, 1985,(5):393-396.
李福绵, 丁一卫, 王林, 冯新德. 含胺基功能基团单体的聚合研究——Ⅸ.脂肪叔胺基N-取代丙烯酰胺作为氧化还原引发体系组分的研究[J]. 高分子学报, 1985,(5):393-396. DOI：

LI Fu-mian, DING Yi-wei, WANG Lin, FENG Xin-de. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO GROUPS Ⅸ. Study on the use of aliphatic tertiary ammo-group N-substituted acrylamides as a component of redox initiator system[J]. Acta Polymerica Sinica, 1985,(5):393-396. DOI：

摘要

Abstract

Aliphatic tertiary amino-group N'-substituted acrylamides

N-acryl-N'-methylpipe-razine(AMP)

N-methacryl-N'-methylpiperazine(MAMP) display better antithromboge necity by the recalcification testing method. Even though AMP and MAMP hardly proceed the polymerization initiated with BPO

but at lower concentration would form redox system with BPO to initiate the polymerization of MMA readily. The rate equation of the polymerization of MMA initiated by MAMP-BPO system was given as Rp= K

(MMA) (MAMP)I/2(BPO)1/2 and the overall activation energy was determined as low as 10.2Kcal/mol. The analysis of the obtained polymers confirmed that MAMP not only initiated the polymerization of MMA by combining with BPO

but also took part in the polymer chains with better antithrombogenecity.

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