多尺度增强体改性对聚醚醚酮复合材料摩擦磨损性能的影响

王露露; 薛键鑫; 李杰; 陆焕焕; 王帅; 刘建; 宋晨飞; 逄显娟

doi:10.11777/j.issn1000-3304.2026.26026

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多尺度增强体改性对聚醚醚酮复合材料摩擦磨损性能的影响

研究论文 | 更新时间：2026-07-08

- 多尺度增强体改性对聚醚醚酮复合材料摩擦磨损性能的影响
- Effect of Multiscale Reinforcement Modification on the Tribological Performance of Poly(ether ether ketone) Composites
- 高分子学报 2026年57卷第7期页码：1551-1565
- 作者机构：
  
  1.河南科技大学高端轴承摩擦学技术与应用国家地方联合工程实验室洛阳 471023
  2.河南科技大学化学化工学院洛阳 471023
- 作者简介：
  
  E-mail: lijie@huast.edu.cn;
  E-mail: xjpang2001@haust.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 ┣92266205);52575206┫;宁波市重点研发计划暨“揭榜挂帅”(2023Z006);河南科技大学优秀青年创新人才项目(2025HNKJDXYXQNCXRC01)
- DOI：10.11777/j.issn1000-3304.2026.26026
  中图分类号：
- CSTR：32057.14.GFZXB.2026.7591
- 收稿：2026-02-25，
  
  录用：2026-03-25，
  
  网络首发：2026-06-23，
  
  纸质出版：2026-07-20
- 稿件说明：
移动端阅览
王露露, 薛键鑫, 李杰, 陆焕焕, 王帅, 刘建, 宋晨飞, 逄显娟. 多尺度增强体改性对聚醚醚酮复合材料摩擦磨损性能的影响. 高分子学报, 2026, 57(7), 1551-1565.

Wang, L. L.; Xue, J. X.; Li, J.; Lu, H. H.; Wang, S.; Liu, J.; Song, C. F.; Pang, X. J. Effect of multiscale reinforcement modification on the tribological performance of poly(ether ether ketone) composites. Acta Polymerica Sinica (in Chinese), 2026, 57(7), 1551-1565.
王露露, 薛键鑫, 李杰, 陆焕焕, 王帅, 刘建, 宋晨飞, 逄显娟. 多尺度增强体改性对聚醚醚酮复合材料摩擦磨损性能的影响. 高分子学报, 2026, 57(7), 1551-1565. DOI： 10.11777/j.issn1000-3304.2026.26026. CSTR： 32057.14.GFZXB.2026.7591.

Wang, L. L.; Xue, J. X.; Li, J.; Lu, H. H.; Wang, S.; Liu, J.; Song, C. F.; Pang, X. J. Effect of multiscale reinforcement modification on the tribological performance of poly(ether ether ketone) composites. Acta Polymerica Sinica (in Chinese), 2026, 57(7), 1551-1565. DOI： 10.11777/j.issn1000-3304.2026.26026. CSTR： 32057.14.GFZXB.2026.7591.

摘要

针对聚醚醚酮(PEEK)在高载荷工况下承载能力不足及摩擦稳定性差的问题，本研究构建了碳纤维(CF)/碳纳米管(MWCNTs)多尺度协同增强体系，并引入聚醚酰亚胺(PEI)和第三代聚酰胺-胺(PAMAM)进行界面化学改性. 通过上浆与接枝实现MWCNTs在CF表面的均匀负载，制备了不同结构复合材料. 结果表明，改性后界面形成稳定共价键合，显著增强界面结合与载荷传递能力. 与纯PEEK相比，复合材料硬度和导热性能均得到提升，其中CF-PAMAM-MWCNTs/PEEK综合性能最优. 在130 N下，其摩擦系数和比磨损率分别降低约15.8%和31.97%，在3~9 mm/s范围内磨损率降低约65%~75%. 性能提升归因于多尺度增强体协同作用及稳定摩擦膜的形成，有效抑制纤维拔出和三体磨损.

Abstract

To address the insufficient load-bearing capacity and poor friction stability of poly(ether ether ketone) (PEEK) under severe conditions

a multiscale synergistic reinforcement system combining carbon fibers (CF) and carbon nanotubes (MWCNTs) with interfacial chemical modification was developed. Polyetherimide (PEI) and third-generation poly(amidoamine) (PAMAM) dendrimers were employed to functionalize the CF surface

enabling uniform anchoring of MWCNTs

via

sizing and grafting. The results showed that stable covalent bonding was formed at the interface

significantly enhancing interfacial adhesion and load transfer. Compared

with neat PEEK

the composites exhibited improved hardness and thermal conductivity

with CF-PAMAM-MWCNTs/PEEK showing the best overall performance. At 130 N

its friction coefficient and wear rate decreased by 15.8% and 31.97%

respectively

while the wear rate was reduced by 65%-75% within 3-9 mm·s

-1

. The enhanced tribological performance was attributed to the multiscale synergistic effect and the formation of a stable tribofilm

which effectively suppress fiber pull-out and three-body abrasion.

关键词

Keywords

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