生物基本征型自修复聚合物：构建策略与应用研究进展

李艳梅; 欧阳欣; 韩昊霖; 沈经杰; 莫伟杰; 张泽平

doi:10.11777/j.issn1000-3304.2026.26027

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生物基本征型自修复聚合物：构建策略与应用研究进展

综述 | 更新时间：2026-04-27

- 生物基本征型自修复聚合物：构建策略与应用研究进展
- Advances in Biomass-based Intrinsic Self-healing Polymers: Construction Strategies and Applications
- 高分子学报 2026年页码：1-24
- 作者机构：
  
  1.西南林业大学材料与化学工程学院云南省木竹生物质材料重点实验室国际生物质联合研究中心昆明 650224
  2.曲靖市麒麟区第一中学曲靖 655000
  3.中山大学化学学院聚合物复合材料及功能材料教育部重点实验室广州 510275
- 作者简介：
  
  [ "张泽平，男，1988年生. 2010年本科毕业于中山大学应用化学专业，2012年和2015年获中山大学高分子化学与物理专业理学硕士和理学博士学位(导师：章明秋教授). 2015年7月~2017年7月在中山大学化学与化学工程学院从事博士后研究，2017年8月~2023年7月在中山大学化学学院任特聘副研究员，2023年8月起任中山大学化学学院副教授. 主要从事基于可逆共价化学的自修复型高分子及其复合材料的设计、构筑和应用基础研究. 担任中国高分子三刊青年编委、Wiley Polymer Journals青年编委等职. 主持国家基金3项、广东省和广州市项目各2项. 在Nature Communications、Advanced Materials、Progress in Polymer Science、Advanced Functional Materials等国内外学术期刊发表SCI论文40余篇，申请中国发明专利15件." ]
- 基金信息：
  
  国家自然科学基金(基金号 ┣32501581);52373095┫
- DOI：10.11777/j.issn1000-3304.2026.26027
  中图分类号：
- CSTR：32057.14.GFZXB.2026.7588
- 收稿：2026-01-31，
  
  录用：2026-03-25，
  
  网络首发：2026-04-27，
- 稿件说明：
移动端阅览
李艳梅, 欧阳欣, 韩昊霖, 沈经杰, 莫伟杰, 张泽平. 生物基本征型自修复聚合物：构建策略与应用研究进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26027.

Li, Y. M.; Ou, Y. X.; Hang, H. L.; Shen, J. J.; Mo, W. J.; Zhang, Z. P. Advances in biomass-based intrinsic self-healing polymers: construction strategies and applications. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26027.
李艳梅, 欧阳欣, 韩昊霖, 沈经杰, 莫伟杰, 张泽平. 生物基本征型自修复聚合物：构建策略与应用研究进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26027. DOI： CSTR： 32057.14.GFZXB.2026.7588.

Li, Y. M.; Ou, Y. X.; Hang, H. L.; Shen, J. J.; Mo, W. J.; Zhang, Z. P. Advances in biomass-based intrinsic self-healing polymers: construction strategies and applications. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26027. DOI： CSTR： 32057.14.GFZXB.2026.7588.

摘要

生物基自修复聚合物结合了可再生资源的可持续性与智能自修复功能，在推动绿色材料发展方面展现出独特优势. 近年来，随着动态化学的迅速发展，基于生物质原料构建自修复材料已成为高分子领域的重要研究方向，不仅拓展了传统聚合物的功能边界，也为材料循环利用和寿命延长提供了新路径. 本文系统总结了生物基自修复聚合物的构建策略，重点阐述了动态共价键(亚胺键、二硫键、硼酸酯键等)、动态非共价键(如氢键、金属配位、静电作用)以及多重动态键协同作用的设计原理与修复机制. 在此基础上，进一步综述了以多糖(纤维素、淀粉、壳聚糖等)、木质素、植物油、蛋白质、天然橡胶与杜仲胶以及其他特色生物质(如脱氧核糖核酸、茶多酚、衣康酸、硫辛酸等)为原料开发的自修复聚合物体系，分析了它们在不同触发条件下(热、光、湿度、pH等)的修复行为与性能特点，最后，探讨了该新兴领域的挑战和发展趋势.

Abstract

Biomass-based self-healing polymers combine the sustainability of renewable resources with intelligent repair capabilities

demonst

rating unique promise for advancing green materials. In recent years

with the rapid progress in dynamic chemistry

the construction of self-healing materials from biomass has become an important research direction in polymer science

which not only expands the functional boundaries of traditional polymers but also provides new pathways for material recycling and lifespan extension. This review systematically outlines the design strategies of biomass-based self-healing polymers

focusing on the design principles and healing mechanisms of dynamic covalent bonds (

e.g.

imine

disulfide

and boronic ester bonds)

dynamic non-covalent interactions (

e.g.

hydrogen bonding

metal coordination

and electrostatic interactions)

and synergistic multi-dynamic bonding systems. Furthermore

self-healing polymer systems developed from various biomass sources

including polysaccharides (such as cellulose

starch

and chitosan)

lignin

vegetable oils

proteins

natural rubber

Eucommia ulmoides gum

and other distinctive biomaterials (

e.g.

DNA

tea polyphenols

itaconic acid

and lipoic acid)

are summarized. The healing behaviors and performance characteristics of these materials under different stimuli (

e.g.

heat

light

moisture

and pH) were analyzed. These materials have broad application potential in fields such as flexible electronics

biomedical devices

smart coatings

sensors

and sustainable packaging. Finally

the challenges and future development trends in this emerging field are discussed.

关键词

Keywords

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