东华大学材料科学与工程学院 先进纤维材料全国重点实验室 先进低维材料中心 上海 201620
E-mail: huanghao@dhu.edu.cn
E-mail: shgyang@dhu.edu.cn
收稿:2026-03-25,
录用:2026-05-26,
网络首发:2026-07-17,
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张承诺, 谭雯娟, 黄浩, 杨曙光. 多场条件下尼龙6材料力学性能. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26090.
Zhang, C. N.; Tan, W. J.; Huang, H.; Yang, S. G. Mechanical properties of nylon 6 materials under multi-field conditions. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26090.
张承诺, 谭雯娟, 黄浩, 杨曙光. 多场条件下尼龙6材料力学性能. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26090. DOI: CSTR: 32057.14.GFZXB.2026.7636.
Zhang, C. N.; Tan, W. J.; Huang, H.; Yang, S. G. Mechanical properties of nylon 6 materials under multi-field conditions. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26090. DOI: CSTR: 32057.14.GFZXB.2026.7636.
研究了尼龙6 (PA6)薄膜和鱼线在多场条件下的力学性能,系统测试了水溶液中盐浓度和温度变化对其力学性能的影响,揭示了PA6材料在盐水溶液中相较于纯水中的力学增强现象. 将PA6薄膜和鱼线浸泡于水中,模量和强度相比干态下均有降低. 升高水溶液温度,薄膜和鱼线的力学强度进一步降低. 当水溶液温度达80 ℃时,薄膜力学强度急剧下降,鱼线由于尺寸和结构影响断裂强度没有大幅降低,但力学曲线出现多段屈服现象. 加入盐后,PA6薄膜和鱼线均表现出更高的力学强度和韧性. 尤其在80 ℃盐溶液(1 mol/L NaCl)中,薄膜的强度和韧性得到大幅提高,鱼线力学曲线中多段屈服现象消失. 我们提出在盐水溶液中,盐离子通过水合层与水分子结合,限制水的迁移,减弱了水分子对高分子材料的增塑作用. 该工作呈现了多种环境参数变化下PA6样品的力学行为,为不同服役环境的应用提供指导.
This study investigated the mechanical properties of nylon 6 (PA6) films and fishing lines under multi-field conditions. The effects of salt concentration and temperature variations in aqueous solutions on their mechanical properties were systematically examined
revealing that PA6 materials exhibited enhanced mechanical strength in saline solutions compared to that in pure water. When PA6 films and fishing lines were immersed in water
their modulus and strength decreased compared to the dry state. With increasing temperature of aqueous solution
the mechanical strength of both films and fishing lines further declined. At 80 ℃ aqueous solution
the mechanical strength of the films dropped sharply. The breaking strength of fishing lines did not decrease abruptly due to their size and structural characteristics
but their mechanical curves displayed multi-stage yielding. Upon the addition of salt
in 1 mol/L NaCl solution at 80 ℃
both the strength and toughness of PA6 films were improved
and the multi-stage yielding in the mechanical curves of PA6 fishing lines disappeared. In saline solution
salt ions associated with water molecules through hydration shells
weakening the plasticizing effect of water on the material. This work presents the evolution of the mechanical properties of PA6 under various multi-field conditions
providing guidance for applications in different service environments.
Kohan M. I. Nylon Plastics Handbook. New York: Hanser Publishers , 1995 .
Li M. Z. ; Liu X. Y. ; Chi Y. B. ; Feng P. F. ; Yu H. T. ; Fan X. Y. ; Yan Z. W. ; Jian X. G. ; Song Y. J. ; Xu J. Structural regulation of polyamide 6 and interfacial dynamic networks confers the properties of self-healing and low water absorption for CF/PA6 composites . Chem. Eng. J. , 2025 , 523 , 168033 . doi: 10.1016/j.cej.2025.168033 http://dx.doi.org/10.1016/j.cej.2025.168033
张燕珠 , 刘四委 , 黄爱萍 , 张艺 , 池振国 , 许家瑞 . 热处理对尼龙6及其与聚酰胺嵌段共聚物共混体系晶体熔融行为和结晶结构的影响 . 高分子学报 , 2010 , ( 2 ), 231 - 236 .
Liu. ; Phang I. Y. ; Shen L. ; Chow S. Y. ; Zhang W. D. Morphology and mechanical properties of multiwalled carbon nanotubes reinforced nylon-6 composites . Macromolecules , 2004 , 37 ( 19 ), 7214 - 7222 . doi: 10.1021/ma049132t http://dx.doi.org/10.1021/ma049132t
Baráth M. ; Kotus M. ; Boszorádová L. ; Baláži J. ; Hrabovský L. ; Pravda Š. Effect of relative humidity on tribological and mechanical properties of PA6-based composites . Manag. Syst. Prod. Eng. , 2025 , 33 ( 3 ), 362 - 370 . doi: 10.2478/mspe-2025-0034 http://dx.doi.org/10.2478/mspe-2025-0034
张玲 , 杨建民 , 冯超伟 , 李春忠 . 表面复合纳米SiO 2 和碳纳米管玻璃纤维增强尼龙6的结构与性能 . 高分子学报 , 2010 , ( 11 ), 1333 - 1339 .
Chen K. F. ; Wang Y. J. ; Zhou L. L. ; Dai J. M. ; Chen W. X. ; Lu W. Y. Characteristics and competitive mechanisms of polycondensation and cyclization induced by end-groups in polyamide 6 melt . J. Polym. Sci. , 2024 , 62 ( 22 ), 5019 - 5029 . doi: 10.1002/pol.20240463 http://dx.doi.org/10.1002/pol.20240463
Li X. S. ; Wang Q. ; Wu D. Y. ; Li T. Q. ; Zhang P. ; Bai J. R. ; Zhang X. Effects of short-term thermal oxidation on the mechanical and thermal behavior of PA6 liner material for type IV hydrogen storage cylinders . RSC Adv. , 2025 , 15 ( 21 ), 16375 - 16391 . doi: 10.1039/d5ra02224j http://dx.doi.org/10.1039/d5ra02224j
Williams M. L. ; Landel R. F. ; Ferry J. D. The temperature dependence of relaxation mechanisms in amorphous polymers and other glass-forming liquids . J. Am. Chem. Soc. , 1955 , 77 ( 14 ), 3701 - 3707 . doi: 10.1021/ja01619a008 http://dx.doi.org/10.1021/ja01619a008
Song P. H. ; Trivedi A. R. ; Chapman D. J. ; Graham A. ; Hawkins N. ; Lukić B. ; Rack A. ; Siviour C. R. Thermomechanical and damage characterisation of short glass fibre reinforced polyamide 6 and impact-modified polyamide 6 composites . Compos. Part B Eng. , 2024 , 287 , 111767 . doi: 10.1016/j.compositesb.2024.111767 http://dx.doi.org/10.1016/j.compositesb.2024.111767
Koyanagi J. ; Hasegawa K. ; Ohtani A. ; Sakai T. ; Sakaue K. Formulation of non-linear viscoelastic-viscoplastic constitutive equation for polyamide 6 resin . Heliyon , 2021 , 7 ( 2 ), e 06335 . doi: 10.1016/j.heliyon.2021.e06335 http://dx.doi.org/10.1016/j.heliyon.2021.e06335
Shirinbayan M. ; Benfriha K. ; Ahmadifar M. ; Penavayre C. ; Nouira S. ; Fitoussi J. Effects of hygrothermal aging on the physicochemical and mechanical properties of 3D-printed PA6 . Int. J. Adv. Manuf. Technol. , 2024 , 131 ( 9 ), 4811 - 4823 . doi: 10.1007/s00170-024-13323-2 http://dx.doi.org/10.1007/s00170-024-13323-2
Sharma P. ; Diebels S. A mixture theory for the moisture transport in polyamide . Continuum Mech. Thermodyn. , 2021 , 33 ( 4 ), 1891 - 1905 . doi: 10.1007/s00161-021-01019-x http://dx.doi.org/10.1007/s00161-021-01019-x
Frank B. ; Frübing P. ; Pissis P. Water sorption and thermally stimulated depolarization currents in nylon-6 . J. Polym. Sci. B Polym. Phys. , 1996 , 34 ( 11 ), 1853 - 1860 . doi: 10.1002/(sici)1099-0488(199608)34:11<1853::aid-polb2>3.0.co;2-t http://dx.doi.org/10.1002/(sici)1099-0488(199608)34:11<1853::aid-polb2>3.0.co;2-t
Zhou S. M. ; Tashiro K. ; Ii T. Moisture effect on structure and mechanical property of nylon 6 as studied by the time-resolved and simultaneous measurements of FT-IR and dynamic viscoelasticity under the controlled humidity at constant scanning rate . Polym. J. , 2001 , 33 ( 4 ), 344 - 355 . doi: 10.1295/polymj.33.344 http://dx.doi.org/10.1295/polymj.33.344
Li H. ; Donovan J. A. Salt embrittlement of nylon 6 . Eng. Fract. Mech. , 2013 , 101 , 91 - 95 . doi: 10.1016/j.engfracmech.2012.07.028 http://dx.doi.org/10.1016/j.engfracmech.2012.07.028
de Cindio B. ; Migliaresi C. ; Acierno D. Viscosity measurements on nylon-6/ethyl alcohol solutions in presence of inorganic salts . Polymer , 1978 , 19 ( 5 ), 526 - 530 . doi: 10.1016/0032-3861(78)90276-8 http://dx.doi.org/10.1016/0032-3861(78)90276-8
Valenti B. ; Bianchi E. ; Greppi G. ; Tealdi A. ; Ciferri A. Bulk properties of synthetic polymer-inorganic salt systems. Melting behavior of salted poly(caproamide) . J. Phys. Chem. , 1973 , 77 ( 3 ), 389 - 395 . doi: 10.1021/j100622a017 http://dx.doi.org/10.1021/j100622a017
Mikhailov N. V. ; Maiboroda V. I. ; Prokof'eva A. S. ; Krasova I. I. ; Gorbacheva V. O. Structural modification of the properties of polyamide fibres . Polym. Sci. U S S R , 1966 , 8 ( 12 ), 2294 - 2300 . doi: 10.1016/0032-3950(66)90233-4 http://dx.doi.org/10.1016/0032-3950(66)90233-4
Uematsu H. ; Ishikawa M. ; Yamaguchi A. ; Sugihara S. ; Nishitsuji S. ; Nishimura F. ; Yamane M. ; Kawabe K. ; Ozaki Y. ; Tanoue S. Enhancement of flexural properties of carbon fiber-reinforced polyamide 6 via oriented crystallization of polyamide 6 among carbon fibers . Compos. Part A Appl. Sci. Manuf. , 2024 , 176 , 107837 . doi: 10.1016/j.compositesa.2023.107837 http://dx.doi.org/10.1016/j.compositesa.2023.107837
Kuram E. Micro-machinability of injection molded polyamide 6 polymer and glass-fiber reinforced polyamide 6 composite . Compos. Part B Eng. , 2016 , 88 , 85 - 100 . doi: 10.1016/j.compositesb.2015.11.004 http://dx.doi.org/10.1016/j.compositesb.2015.11.004
Cai Z. Q. ; Ye J. Q. ; Zhang Y. F. ; Nie D. L. ; Ouyang J. L. The phase transition of polyamide 6 with pre-stretching process at different temperatures . Phys. Scr. , 2021 , 96 ( 12 ), 125732 . doi: 10.1088/1402-4896/ac437e http://dx.doi.org/10.1088/1402-4896/ac437e
Skorupska M. ; Kulczyk M. ; Przybysz S. ; Skiba J. ; Mizeracki J. ; Ryszkowska J. Mechanical reinforcement of polyamide 6 by cold hydrostatic extrusion . Materials , 2021 , 14 ( 20 ), 6045 . doi: 10.3390/ma14206045 http://dx.doi.org/10.3390/ma14206045
Wang X. S. ; Wang Z. L. ; Liang S. M. ; Jin Y. ; Lotz B. ; Yang S. G. Surface nano-structure of polyamide 6 film by hydrothermal treatment . Appl. Surf. Sci. , 2018 , 442 , 595 - 601 . doi: 10.1016/j.apsusc.2018.02.135 http://dx.doi.org/10.1016/j.apsusc.2018.02.135
Cravero F. ; Arrigo R. ; Frache A. Processing/microstructure relationships in melt compounded polyamide 6 with different molecular weights: effect of screw speed and viscosity ratio. Polym. Eng. Sci. , 2025 , 65 ( 5 ), 2525 - 2538 . doi: 10.1002/pen.27165 http://dx.doi.org/10.1002/pen.27165
Arrhenius G. X-ray diffraction procedures for polycrystalline and amorphous materials . J. Chem. Educ. , 1955 , 32 ( 4 ), 228 . doi: 10.1021/ed032p228.2 http://dx.doi.org/10.1021/ed032p228.2
Illers K. H. ; Haberkorn H. ; Simak P. Untersuchungen über die γ -struktur in unverstrecktem und verstrecktem 6-polyamid . Macromol. Chem. Phys. , 1972 , 158 ( 1 ), 285 - 311 . doi: 10.1002/macp.1972.021580123 http://dx.doi.org/10.1002/macp.1972.021580123
D'Alò B. ; Coppola G. ; Pallesi B. Studies of crystalline forms of nylon-6 by X-ray and I.r. Spectrophotometry . Polymer , 1974 , 15 ( 3 ), 130 - 132 . doi: 10.1016/0032-3861(74)90189-x http://dx.doi.org/10.1016/0032-3861(74)90189-x
Lin X. T. ; Liu Y. J. ; Jin R. J. ; Peng Y. Structure evolution and properties enhancement of polyamide-6/polyamide-1010 films under uniaxial and biaxial stretching . J. Appl. Polym. Sci. , 2023 , 140 ( 32 ), e 54253 . doi: 10.1002/app.54253 http://dx.doi.org/10.1002/app.54253
Pepin J. ; Gaucher V. ; Lefebvre J. M. ; Stroeks A. Biaxial stretching behavior as a probe of H-bond organization in semi-crystalline polyamides . Polymer , 2016 , 101 , 217 - 224 . doi: 10.1016/j.polymer.2016.08.078 http://dx.doi.org/10.1016/j.polymer.2016.08.078
Gao Y. Y. ; Dong X. ; Wang L. L. ; Liu G. M. ; Liu X. G. ; Tuinea-Bobe C. ; Whiteside B. ; Coates P. ; Wang D. J. ; Han C. C. Flow-induced crystallization of long chain aliphatic polyamides under a complex flow field: inverted anisotropic structure and formation mechanism . Polymer , 2015 , 73 , 91 - 101 . doi: 10.1016/j.polymer.2015.07.029 http://dx.doi.org/10.1016/j.polymer.2015.07.029
Zhang Y. Z. ; Zhang Y. ; Liu S. W. ; Huang A. P. ; Chi Z. G. ; Xu J. R. ; Economy J. Phase stability and melting behavior of the α and γ phases of nylon 6 . J. Appl. Polym. Sci. , 2011 , 120 ( 4 ), 1885 - 1891 . doi: 10.1002/app.33047 http://dx.doi.org/10.1002/app.33047
王晓春 , 杨桂生 , 郑强 . 尼龙6与半芳香性非晶尼龙原位共混物的结构与性能 . 高分子学报 , 2007 , ( 9 ), 796 - 801 .
张彩虹 , 王伟杰 , 黄浩 , 刘泽新 , 杨曙光 . 湿度对高分子氢键复合物纤维力学行为的影响 . 高分子学报 , 2023 , 54 ( 11 ), 1772 - 1783 .
刘泽新 , 尹培阳 , 黄浩 , 张彩虹 , 杨曙光 . 高分子氢键复合物蠕变行为研究 . 高分子学报 , 2025 , 56 ( 7 ), 1223 - 1233 .
Zhang Z. Y. ; Tang Z. Y. ; Kobayashi Y. ; Ito H. ; Okazaki S. Microscopic mechanism of accelerated aging in swollen polylactic acid by water: tensile test experiments and molecular dynamics calculations . Polymer , 2025 , 332 , 128582 . doi: 10.1016/j.polymer.2025.128582 http://dx.doi.org/10.1016/j.polymer.2025.128582
Kehrer L. ; Keursten J. ; Hirschberg V. ; Böhlke T. Dynamic mechanical analysis of PA 6 under hydrothermal influences and viscoelastic material modeling . J. Thermoplast. Compos. Mater. , 2023 , 36 ( 11 ), 4630 - 4664 . doi: 10.1177/08927057231155864 http://dx.doi.org/10.1177/08927057231155864
Fabre V. ; Quandalle G. ; Billon N. ; Cantournet S. Time-Temperature-Water content equivalence on dynamic mechanical response of polyamide 6 , 6 . Polymer, 2018, 137 , 22 - 29 . doi: 10.1016/j.polymer.2017.10.067 http://dx.doi.org/10.1016/j.polymer.2017.10.067
Wu Y. J. ; Xu Y. Z. ; Wang D. J. ; Zhao Y. ; Weng S. F. ; Xu D. F. ; Wu J. G. FT-IR spectroscopic investigation on the interaction between nylon 66 and lithium salts . J. Appl. Polym. Sci. , 2004 , 91 ( 5 ), 2869 - 2875 . doi: 10.1002/app.13495 http://dx.doi.org/10.1002/app.13495
Zhang R. ; Zhang Y. P. ; Antila H. S. ; Lutkenhaus J. L. ; Sammalkorpi M. Role of salt and water in the plasticization of PDAC/PSS polyelectrolyte assemblies . J. Phys. Chem. B , 2017 , 121 ( 1 ), 322 - 333 . doi: 10.1021/acs.jpcb.6b12315 http://dx.doi.org/10.1021/acs.jpcb.6b12315
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