二氧化碳/环氧丙烷/苯酐/邻苯二甲醛四元共聚物的合成及其水解

罗子琳; 刘思翃; 黄盛; 韩东梅; 王拴紧; 孟跃中; 肖敏

doi:10.11777/j.issn1000-3304.2026.26105

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二氧化碳/环氧丙烷/苯酐/邻苯二甲醛四元共聚物的合成及其水解

研究论文 | 更新时间：2026-07-24

- 二氧化碳/环氧丙烷/苯酐/邻苯二甲醛四元共聚物的合成及其水解
- Synthesis and Degradation of CO₂/Propylene Oxide/Phthalic Anhydride/o-Phthalaldehyde Copolymers
- 高分子学报 2026年57卷第8期页码：1732-1739
- 作者机构：
  
  中山大学材料科学与工程学院广东省低碳化学与过程节能重点实验室广州 510006
- 作者简介：
  
  E-mail: stsxm@mail.sysu.edu.cn
- 基金信息：
  
  广东省重点研发计划(2025B0101010005)
- DOI：10.11777/j.issn1000-3304.2026.26105
  中图分类号：
- CSTR：32057.14.GFZXB.2026.7629
- 收稿：2026-04-03，
  
  录用：2026-05-15，
  
  网络首发：2026-07-14，
  
  纸质出版：2026-08-20
- 稿件说明：
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罗子琳, 刘思翃, 黄盛, 韩东梅, 王拴紧, 孟跃中, 肖敏. 二氧化碳/环氧丙烷/苯酐/邻苯二甲醛四元共聚物的合成及其水解. 高分子学报, 2026, 57(8), 1732-1739.

Luo, Z. L.; Liu, S. H.; Huang, S.; Han, D. M.; Wang, S. J.; Meng, Y. Z.; Xiao, M. Synthesis and degradation of CO₂/propylene oxide/phthalic anhydride/o-phthalaldehyde copolymers. Acta Polymerica Sinica (in Chinese), 2026, 57(8), 1732-1739. DOI: 10.11777/j.issn1000-3304.2026.26105. CSTR: 32057.14.GFZXB.2026.7629.
罗子琳, 刘思翃, 黄盛, 韩东梅, 王拴紧, 孟跃中, 肖敏. 二氧化碳/环氧丙烷/苯酐/邻苯二甲醛四元共聚物的合成及其水解. 高分子学报, 2026, 57(8), 1732-1739. DOI： 10.11777/j.issn1000-3304.2026.26105. CSTR： 32057.14.GFZXB.2026.7629.

Luo, Z. L.; Liu, S. H.; Huang, S.; Han, D. M.; Wang, S. J.; Meng, Y. Z.; Xiao, M. Synthesis and degradation of CO₂/propylene oxide/phthalic anhydride/o-phthalaldehyde copolymers. Acta Polymerica Sinica (in Chinese), 2026, 57(8), 1732-1739. DOI: 10.11777/j.issn1000-3304.2026.26105. CSTR: 32057.14.GFZXB.2026.7629. DOI：

摘要

利用非金属催化剂三乙基硼(TEB)/四丁基氯化铵(TBACl)催化环氧丙烷(PO)/二氧化碳(CO

)/苯酐(PA)/邻苯二甲醛(OPA)四元共聚，得到具有不同链段组成的高分子量的聚(缩醛-酯-碳酸酯) (PPCP-PAc). 随后在温和的酸性条件下选择性水解聚合物链中的缩醛键，得到了一系列分子量不同、聚酯(PE)含量不同的低分子量聚(酯-碳酸酯)二元醇(PPCP-DL). 通过基质辅助激光解吸电离飞行时间质谱(MALDI-TOF MS)和

F核磁共振谱验证了PPCP-DL的两端均为羟基封端，且伯羟基含量为43%.

Abstract

In this study

a top-down strategy was adopted for the synthesis of poly(ester-carbonate) diols (PPCP-DL) by hydrolyzing high-molecular-weight poly(acetal-

-ester-

-carbonate) (PPCP-PAc). First

the nonmetal catalyst triethylborane (TEB)/tetrabutylammonium chloride (TBACl) was used to catalyze the quaternary copolymerization of propylene oxide (PO)

carbon dioxide (CO

)

phthalic anhydride (PA)

and

-phthalaldehyde (OPA)

affording high-molecular-weight PPCP-PAc with varied segmental compositions. Subsequently

the acetal linkages in the polymer backbone were selectively hydrolyzed under mild acidic conditions

yielding a series of low-molecular-weight PPCP-DLs with different molecular weights (1.6-3.3 kg/mol) and polyester (PE) contents (13 mol%-37 mol%). The end-group structures of PPCP-DL

confirmed by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) and

F nuclear magnetic resonance spectroscopy

revealed hydroxyl groups at both termini and a primary hydroxyl content of 43 wt%.

关键词

Keywords

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