镧掺杂Bi<sub>2</sub>WO<sub>6</sub>/聚丙烯腈复合纳米纤维膜的结构调控及<italic style="font-style: italic">γ</italic>射线屏蔽性能

齐阡禾; 王铁健; 范亚霖; 何良玉; 叶好; 刘勇

doi:10.11777/j.issn1000-3304.2026.26135

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镧掺杂Bi₂WO₆/聚丙烯腈复合纳米纤维膜的结构调控及γ射线屏蔽性能

研究论文 | 更新时间：2026-06-17

- 镧掺杂Bi₂WO₆/聚丙烯腈复合纳米纤维膜的结构调控及γ射线屏蔽性能
- Structural Regulation and Gamma-ray Shielding Performance of La-doped Bi₂WO₆/Polyacrylonitrile Composite Nanofibrous Membranes
- 高分子学报 2026年页码：1-12
- 作者机构：
  
  1.北京化工大学巴黎居里工程师学院北京 100029
  2.核工业北京地质研究院北京 100029
  3.北京化工大学材料科学与工程学院北京 100029
- 作者简介：
  
  E-mail: yongsd@iccas.ac.cn
- 基金信息：
  
  国家自然科学基金(基金号 ┣52433009);52403254┫;中国科学院战略性先导科技专项(XDB 0520101)
- DOI：10.11777/j.issn1000-3304.2026.26135
  中图分类号：
- CSTR：32057.14.GFZXB.2026.7628
- 收稿：2026-05-01，
  
  录用：2026-05-23，
  
  网络首发：2026-06-16，
- 稿件说明：
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齐阡禾, 王铁健, 范亚霖, 何良玉, 叶好, 刘勇. 镧掺杂Bi₂WO₆/聚丙烯腈复合纳米纤维膜的结构调控及γ射线屏蔽性能. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26135. CSTR: 32057.14.GFZXB.2026.7628.

Qi, Q. H.; Wang, T. J.; Fan, Y. L.; He, L. Y.; Ye, H.; Liu, Y. Structural regulation and gamma-ray shielding performance of La-doped Bi₂WO₆/polyacrylonitrile composite nanofibrous membranes. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26135. CSTR: 32057.14.GFZXB.2026.7628.
齐阡禾, 王铁健, 范亚霖, 何良玉, 叶好, 刘勇. 镧掺杂Bi₂WO₆/聚丙烯腈复合纳米纤维膜的结构调控及γ射线屏蔽性能. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26135. CSTR: 32057.14.GFZXB.2026.7628. DOI：

Qi, Q. H.; Wang, T. J.; Fan, Y. L.; He, L. Y.; Ye, H.; Liu, Y. Structural regulation and gamma-ray shielding performance of La-doped Bi₂WO₆/polyacrylonitrile composite nanofibrous membranes. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26135. CSTR: 32057.14.GFZXB.2026.7628. DOI：

摘要

随着个体辐射防护和柔性防护装备的发展，伽马射线屏蔽材料对轻质化、柔性化和无铅化提出了更高要求. 为提高柔性聚合物基复合材料的

射线屏蔽性能，以聚丙烯腈(PAN)为基体，制备了Bi

及不同La掺杂的复合纳米纤维膜，并结合微观表征及性能测试，系统研究了La掺杂对复合纤维膜微观结构、局域电子结构、力学性能及

射线屏蔽性能的影响. 实验结果表明，La掺杂能够显著调控Bi

的结晶行为和纤维表面无机相的生长状态，且掺杂量与复合纳米纤维膜性能之间并非简单的线性关系，适量La掺杂有利于改善无机相在纤维表面的分布均匀性并优化复合膜结构，而过量掺杂会导致含镧杂相生成及局部富集，其中10 wt% La掺杂样品表现出最佳的综合性能，在3种辐照条件下的质量衰减系数分别达到4.426、1.491和1.315 cm

·g

-1

，较未掺杂La的样品分别提高约51.6%、77.7%和151.4%. 该研究为轻质、柔性、无铅

射线屏蔽纤维材料的结构设计与性能优化提供了参考.

Abstract

With the development of personal radiation protection and flexible protective equipment

gamma-ray shielding materials face higher requirements for lightweight

flexibility

and lead-free characteristics. To improve the gamma-ray shielding performance of flexible polymer-based composites

we prepared Bi

and Bi

/PAN composite nanofibrous membranes with different La doping contents using polyacrylonitrile (PAN) as the matrix. Combined with microstructural characterization and performance testing

the effects of La doping on the microstructure

local electronic structure

mechanical properties

and gamma-ray shielding performance of the composite nanofibrous membranes were systematically investigate. The results showed that La doping significantly regulates the crystallization behavior of Bi

and the growth state of the inorganic phase on the fiber surface

and the relationship between La doping content and the properties of the composite nanofibrous membranes was not simply linear. Appropriate La doping improved the distribution uniformity of the inorganic phase on the fiber surface and optimizes the membrane structure

whereas

excessive doping caused the formation of La-containing impurity phases and local aggregation. The 10 wt% La-doped sample exhibited the best overall performance

with mass attenuation coefficients of 4.426

1.491

and 1.315 cm

·g

-1

under three irradiation conditions

which were approximately 51.6%

77.7%

and 151.4% higher than those of the undoped samples

respectively. This study provides a reference for the structural design and performance optimization of lightweight

flexible

and lead-free gamma-ray shielding fibrous materials.

关键词

Keywords

references

Kaplan D. J. ; Patel J. N. ; Liporace F. A. ; Yoon R. S. Intraoperative radiation safety in orthopaedics: a review of the ALARA (As low as reasonably achievable) principle . Patient Saf. Surg. , 2016 , 10 ( 1 ), 27 . doi: 10.1186/s13037-016-0115-8 http://dx.doi.org/10.1186/s13037-016-0115-8

Smith-Bindman R. ; Chu P. W. ; Azman Firdaus H. ; Stewart C. ; Malekhedayat M. ; Alber S. ; Bolch W. E. ; Mahendra M. ; Berrington de González A. ; Miglioretti D. L. Projected lifetime cancer risks from current computed tomography imaging . JAMA Intern. Med. , 2025 , 185 ( 6 ), 710 . doi: 10.1001/jamainternmed.2025.0505 http://dx.doi.org/10.1001/jamainternmed.2025.0505

Li H. ; Yan L. P. ; Zhou J. B. ; Wang Y. P. ; Liao X. P. ; Shi B. Flexible and wearable functional materials for ionizing radiation Protection: a perspective review . Chem. Eng. J. , 2024 , 487 , 150583 . doi: 10.1016/j.cej.2024.150583 http://dx.doi.org/10.1016/j.cej.2024.150583

孙志娟 , 王继先 , 向剑 , 赵永成 , 陈景云 , 杨晴晴 , 樊赛军 . 我国人群辐射致胃癌危险系数估算研究 . 中华放射医学与防护杂志 , 2015 , 35 ( 4 ), 282 - 286 . doi: 10.3760/cma.j.issn.0254-5098.2015.04.011 http://dx.doi.org/10.3760/cma.j.issn.0254-5098.2015.04.011

Lakhwani O. P. ; Dalal V. ; Jindal M. ; Nagala A. Radiation protection and standardization . J. Clin. Orthop. Trauma , 2019 , 10 ( 4 ), 738 - 743 . doi: 10.1016/j.jcot.2018.08.010 http://dx.doi.org/10.1016/j.jcot.2018.08.010

Asgari M. ; Afarideh H. ; Ghafoorifard H. ; Amirabadi E. A. Comparison of nano/micro lead, bismuth and tungsten on the gamma shielding properties of the flexible composites against photon in wide energy range (40 keV-662 keV) . Nucl. Eng. Technol. , 2021 , 53 ( 12 ), 4142 - 4149 . doi: 10.1016/j.net.2021.06.022 http://dx.doi.org/10.1016/j.net.2021.06.022

Al-Sarray E. ; Akkurt , Günoğlu K. ; Evcın A. ; Bezır N. Ç. Radiation shielding properties of some composite panel . Acta Phys. Pol. A , 2017 , 132 ( 3 ), 490 - 492 . doi: 10.12693/aphyspola.132.490 http://dx.doi.org/10.12693/aphyspola.132.490

Aldhuhaibat M. J. R. ; Amana M. S. ; Jubier N. J. ; Salim A. A. Improved gamma radiation shielding traits of epoxy composites: evaluation of mass attenuation coefficient, effective atomic and electron number . Radiat. Phys. Chem. , 2021 , 179 , 109183 . doi: 10.1016/j.radphyschem.2020.109183 http://dx.doi.org/10.1016/j.radphyschem.2020.109183

Li X. P. ; Yao H. S. ; Zhao Y. ; Yuan B. ; Zhai J. Y. ; Li L. ; Li H. G. ; Li X. F. Polymer-based nuclear radiation shielding materials: state-of-the-art and emerging trends for engineering applications . Front. Mater. , 2025 , 12 , 1672938 . doi: 10.3389/fmats.2025.1672938 http://dx.doi.org/10.3389/fmats.2025.1672938

Chen M. L. ; Gazze L. ; DiTraglia F. J. ; Das R. ; Nriagu J. ; Erel Y. ; Boyle E. A. ; Taylor C. M. ; Weiss D. Environmental lead risk in the 21st century . Commun. Earth Environ. , 2025 , 6 , 776 . doi: 10.1038/s43247-025-02735-x http://dx.doi.org/10.1038/s43247-025-02735-x

Özdoğan H. ; Ali Üncü Y. ; Akman F. ; Polat H. ; Kaçal M. R. Investigation of gamma ray shielding characteristics of binary composites containing polyester resin and lead oxide . Polymers , 2024 , 16 ( 23 ), 3324 . doi: 10.3390/polym16233324 http://dx.doi.org/10.3390/polym16233324

Gonzalez-Villalva A. ; Marcela R. L. ; Nelly L. V. ; Patricia B. N. ; Guadalupe M. R. ; Brenda C. T. ; Maria Eugenia C. V. ; Martha U. C. ; Isabel G. P. ; Fortoul T. I. Lead systemic toxicity: a persistent problem for health . Toxicology , 2025 , 515 , 154163 . doi: 10.1016/j.tox.2025.154163 http://dx.doi.org/10.1016/j.tox.2025.154163

董宇 , 戴耀东 , 常树全 , 康斌 , 杨小勇 . WO 3 /CeO 2 /环氧树脂基辐射防护材料的制备及性能研究 . 材料导报 , 2012 , 26 ( S1 ), 184 - 186 .

Sayyed M. I. ; Yasmin S. ; Almousa N. ; Elsafi M. Shielding properties of epoxy matrix composites reinforced with MgO micro- and nanoparticles . Materials , 2022 , 15 ( 18 ), 6201 . doi: 10.3390/ma15186201 http://dx.doi.org/10.3390/ma15186201

Atashi P. ; Rahmani S. ; Ahadi B. ; Rahmati A. Efficient, flexible and lead-free composite based on room temperature vulcanizing silicone rubber/W/Bi 2 O 3 for gamma ray shielding application . J. Mater. Sci. Mater. Electron. , 2018 , 29 ( 14 ), 12306 - 12322 . doi: 10.1007/s10854-018-9344-1 http://dx.doi.org/10.1007/s10854-018-9344-1

Kim S. ; Ahn Y. ; Song S. H. ; Lee D. Tungsten nanoparticle anchoring on boron nitride nanosheet-based polymer nanocomposites for complex radiation shielding . Compos. Sci. Technol. , 2022 , 221 , 109353 . doi: 10.1016/j.compscitech.2022.109353 http://dx.doi.org/10.1016/j.compscitech.2022.109353

赵盛 , 霍志鹏 , 钟国强 , 张宏 , 胡立群 . 改性钆/硼/聚乙烯纳米复合材料的制备及对中子和伽马射线的屏蔽性能 . 高等学校化学学报 , 2022 , 43 ( 6 ), 45 - 55 .

Kassem S. M. ; Abdel Maksoud M. I. A. ; El Sayed A. M. ; Ebraheem S. ; Helal A. I. ; Ebaid Y. Y. Optical and radiation shielding properties of PVC/BiVO4 nanocomposite . Sci. Rep. , 2023 , 13 , 10964 . doi: 10.1038/s41598-023-37692-y http://dx.doi.org/10.1038/s41598-023-37692-y

Nasrabadi M. ; Tavakoli-Anbaran H. ; Ebrahimibasabi E. Investigation of nano MgO loaded polyvinyl chloride polymer in protective clothing as a nonlead materials . Heliyon , 2024 , 10 ( 12 ), e 32711 . doi: 10.1016/j.heliyon.2024.e32711 http://dx.doi.org/10.1016/j.heliyon.2024.e32711

Mokhtari Dorostkar M. ; Abdi Saray A. Development of PMMA based polymer composite incorporating WO 3 for gamma radiation shielding using synthesis and Monte Carlo simulation . Sci. Rep. , 2025 , 15 , 27346 . doi: 10.1038/s41598-025-11155-y http://dx.doi.org/10.1038/s41598-025-11155-y

Yılmaz M. ; Akman F. Gamma radiation shielding properties for polymer composites reinforced with bismuth tungstate in different proportions . Appl. Radiat. Isot. , 2023 , 200 , 110994 . doi: 10.1016/j.apradiso.2023.110994 http://dx.doi.org/10.1016/j.apradiso.2023.110994

Gulbicim H. ; Aksu M. ; Turkan N. ; Babuz C. Gamma ray shielding properties of synthesized lanthanide borides using EGSnrc code . Nucl. Instrum. Meth. Phys. Res. Sect. B Beam Interact. Mater. At. , 2023 , 542 , 259 - 269 . doi: 10.1016/j.nimb.2023.07.008 http://dx.doi.org/10.1016/j.nimb.2023.07.008

Wei W. J. ; Hong Y. ; Yuan Y. ; Li Y. ; Cui K. ; Zhang T. Y. ; Jia X. ; Qin W. ; Wu X. H. Enhanced wide energy regions gamma ray shielding property for Bi 2O3-Gd2O(CO3)2·H2O/EP composites with strong electron cloud overlap. J. Alloys Compd. , 2023 , 938 , 168672 . doi: 10.1016/j.jallcom.2022.168672 http://dx.doi.org/10.1016/j.jallcom.2022.168672

Wu Y. H. ; Wang Z. K. Progress in ionizing radiation shielding materials . Adv. Eng. Mater. , 2024 , 26 ( 21 ), 2400855 . doi: 10.1002/adem.202400855 http://dx.doi.org/10.1002/adem.202400855

Liao Y. X. ; Mao C. Y. ; Zhang J. F. ; Wang G. W. ; Liu G. Q. ; Yan Q. ; Wu Z. X. ; Liu Y. Effects of Er 3+ doping on the crystal morphology and gamma rays shielding properties of Bi 2 WO 6 . J. Radiat. Res. Appl. Sci. , 2025 , 18 ( 3 ), 101758 . doi: 10.1016/j.jrras.2025.101758 http://dx.doi.org/10.1016/j.jrras.2025.101758

李江苏 , 戴耀东 , 张瑜 , 孙浩 , 常树全 . 聚丙烯酸钐/环氧树脂辐射防护材料的制备工艺及性能 . 原子能科学技术 , 2011 , 45 ( 1 ), 117 - 123 .

Qu X. ; Ye J. Q. ; Huang Y. Z. ; Wang C. ; Hu P. ; Zhao R. ; Liu Y. Constructing multilevel nanostructures fiber composites for NIR/UV/X-ray multiband electromagnetic protection . Carbon , 2025 , 240 , 120351 . doi: 10.1016/j.carbon.2025.120351 http://dx.doi.org/10.1016/j.carbon.2025.120351

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Structural Regulation and Gamma-ray Shielding Performance of La-doped Bi2WO6/Polyacrylonitrile Composite Nanofibrous Membranes

DOI：10.11777/j.issn1000-3304.2026.26135

摘要

Abstract

关键词

Keywords

references

镧掺杂Bi₂WO₆/聚丙烯腈复合纳米纤维膜的结构调控及γ射线屏蔽性能

Structural Regulation and Gamma-ray Shielding Performance of La-doped Bi₂WO₆/Polyacrylonitrile Composite Nanofibrous Membranes