基于环氧树脂相转变的耐磨超双疏表面的制备与表征

张卫红; 李午戊; 张诗影; 曹静; 曹文丽

doi:10.11777/j.issn1000-3304.2026.26153

您当前的位置：

首页 >

文章列表页 >

基于环氧树脂相转变的耐磨超双疏表面的制备与表征

研究论文 | 更新时间：2026-07-14

- 基于环氧树脂相转变的耐磨超双疏表面的制备与表征
- Preparation and Characterization of Wear-resistant Superamphiphobic Surface Based on Epoxy Resin Phase Transition
- 高分子学报 2026年页码：1-11
- 作者机构：
  
  咸阳师范学院化学与化工学院咸阳 712000
- 作者简介：
  
  E-mail: zwh10430@sina.com
- 基金信息：
  
  陕西省自然科学基础研究计划(2024JC-YBMS-119)
- DOI：10.11777/j.issn1000-3304.2026.26153
  中图分类号：
- CSTR：32057.14.GFZXB.2026.7663
- 收稿：2026-05-03，
  
  录用：2026-06-09，
  
  网络首发：2026-07-14，
- 稿件说明：
移动端阅览
张卫红, 李午戊, 张诗影, 曹静, 曹文丽. 基于环氧树脂相转变的耐磨超双疏表面的制备与表征. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26153.

Zhang, W. H.; Li, W. W.; Zhang, S. Y.; Cao, J.; Cao, W. L. Preparation and characterization of wear-resistant superamphiphobic surface based on epoxy resin phase transition. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26153.
张卫红, 李午戊, 张诗影, 曹静, 曹文丽. 基于环氧树脂相转变的耐磨超双疏表面的制备与表征. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26153. DOI： CSTR： 32057.14.GFZXB.2026.7663.

Zhang, W. H.; Li, W. W.; Zhang, S. Y.; Cao, J.; Cao, W. L. Preparation and characterization of wear-resistant superamphiphobic surface based on epoxy resin phase transition. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26153. DOI： CSTR： 32057.14.GFZXB.2026.7663.

摘要

既疏水又疏油的超双疏表面是疏液表面发展应用的重要趋势，然而，在受到外界摩擦时该类表面的微纳粗糙结构会因磨损而导致双疏性能迅速下降甚至丧失，向双疏粉体中加入高分子胶黏剂来构筑复合涂层是提高双疏表面耐磨性最为常用的方法，但往往由于双疏粉体会被胶黏剂包埋而效果不佳.本工作在自主合成出性能较佳的超双疏纳米粉体的基础上，利用溶解于良溶剂中的高分子胶黏剂加入到不良溶剂中会发生相转变而呈现出球状形貌的性质，将环氧树脂溶液滴入分散有超双疏纳米粉体的不良溶剂中，引发相转变后再通过超声处理促使双疏纳米粉体在环氧树脂相转变液滴表面紧密包裹形成细腻稳定的Pickering乳液滴，而后经喷涂固化得到由多层核壳微球组成的超双疏涂层. 双疏粉体处于核壳微球表面保证了涂层的双疏性能不因胶黏剂存在而下降，多层自相似结构又赋予了涂层较好的耐磨性. 经测试，厚度60 μm左右的涂层可在负重200 g砝码情况下耐400#砂纸表面摩擦60个循环(总行程约1650 cm)后仍保持较佳的超疏水性和一定程度的疏油性. 该方法原则上可以适用于任何能在不良溶剂中发生相转变的的高分子胶黏剂，为耐磨超疏水/超双疏涂层的制备及应用提供了借鉴方向.

Abstract

Superamphiphobic surfaces that are both hydrophobic and oleophobic represent an important trend in the development and application of liquid-repellent surfaces. However

when subjected to external friction

the micro-nano rough structure of such surfaces causes a rapid decline or even loss of their superamphiphobic properties owing to wear. The addition of high-molecular-weight adhesives to superamphiphobic powders to construct composite coatings is the most commonly used method for enhancing the wear resistance of superamphiphobic surfaces. However

the effect is often not good because the superamphiphobic powder can be embedded in the adhesive. To address this issue

in this study

superamphiphobic nanopowders with superior performance were synthesized. Then

taking advantage of the property that high-molecular-weight adhesives dissolved in good solvents undergo phase transition and form spherical morphologies when added to poor solvents

an epoxy resin solution was dropped into a poor solvent in which superamphiphobic nanopowders were dispersed to trigger the phase transition. Subsequent ultrasonic treatment promoted the tight coating of superamphiphobic nanopowders on the surface of epoxy resin phase-transition droplets

forming fine and stable Pickering emulsion droplets. A superamphiphobic coating composed of multiple core-shell microspheres was obtained after spraying and curing. The superamphiphobic powder was located on the surface of the core-shell microspheres

ensuring that the superamphiphobic properties of the coating did not decline in the presence of the adhesive. The multi-layer self-similar structure also endowed the coating with good wear resistance characteristics. Tests showed that a coating with a thickness of approximately 60 µm could withstand 60 cycles of friction on a 400# sandpaper surface under a 200-g weight without significant loss of superhydrophobicity and retained a certain degree of oleophobicity. This method can be applied to any polymer adhesive that undergoes phase transformation in poor solvents

providing a reference for the preparation and application of wear-resistant superhydrophobic/superamphiphobic coatings.

关键词

Keywords

references

Li H. J. ; Wang X. B. ; Song Y. L. ; Liu Y. Q. ; Li Q. S. ; Jiang L. ; Zhu D. B. Super-"amphiphobic" aligned carbon nanotube films . Angew. Chem. , 2001 , 113 ( 9 ), 1793 - 1796 . doi: 10.1002/1521-3757(20010504)113:9<1793::aid-ange17930>3.0.co;2-i http://dx.doi.org/10.1002/1521-3757(20010504)113:9<1793::aid-ange17930>3.0.co;2-i

Li F. ; Du M. ; Zheng Q. Dopamine/silica nanoparticle assembled, microscale porous structure for versatile superamphiphobic coating . ACS Nano , 2016 , 10 ( 2 ), 2910 - 2921 . doi: 10.1021/acsnano.6b00036 http://dx.doi.org/10.1021/acsnano.6b00036

Hegner K. I. ; Wong W. S. Y. ; Vollmer D. Ultrafast bubble bursting by superamphiphobic coatings . Adv. Mater. , 2021 , 33 ( 39 ), 2101855 . doi: 10.1002/adma.202101855 http://dx.doi.org/10.1002/adma.202101855

Zhao X. ; Duan Y. P. Improve the mechanical durability of superhydrophobic/superamphiphobic coating through multiple cross-linked mesh structure . Colloids Surf. A Physicochem. Eng. Aspects , 2022 , 642 , 128560 . doi: 10.1016/j.colsurfa.2022.128560 http://dx.doi.org/10.1016/j.colsurfa.2022.128560

Li H. J. ; Jin Q. Q. ; Li H. B. ; Tong H. ; Wang K. K. ; Chen S. R. ; Ouyang G. F. ; Wang Z. K. ; Li Y. N. Transparent superamphiphobic material formed by hierarchical nano re-entrant structure . Adv. Funct. Mater. , 2024 , 34 ( 3 ), 2309684 . doi: 10.1002/adfm.202309684 http://dx.doi.org/10.1002/adfm.202309684

Zhou N. ; Hou S. H. ; Noh I. ; Liu Q. Q. ; Wang Y. B. ; Do Kim H. ; Zhou Q. ; Ohkita H. ; Wang B. B. Constructing robust and multifunctional superamphiphobic surfaces by using two different nanostructures of silicon dioxide . Langmuir , 2025 , 41 ( 9 ), 6376 - 6388 . doi: 10.1021/acs.langmuir.5c00289 http://dx.doi.org/10.1021/acs.langmuir.5c00289

Zhang D. J. ; Wu G. Q. ; Li H. ; Cui Y. ; Zhang Y. M. Superamphiphobic surfaces with robust self-cleaning, abrasion resistance and anti-corrosion . Chem. Eng. J. , 2021 , 406 , 126753 . doi: 10.1016/j.cej.2020.126753 http://dx.doi.org/10.1016/j.cej.2020.126753

Wang C. ; An D. ; Yang T. ; Gu L. X. ; Xie M. X. ; Lin X. K. ; Han C. X. ; Song Y. Q. ; Deng Q. Y. ; Wen F. Self-cleaning and amphiphobic properties of octadecyltrichlorosilane self-assembled modified polytetrafluoroethylene films . Colloids Surf. A Physicochem. Eng. Aspects , 2024 , 684 , 133132 . doi: 10.1016/j.colsurfa.2023.133132 http://dx.doi.org/10.1016/j.colsurfa.2023.133132

Chen D. D. ; Gao F. ; Liu T. Y. ; Kang J. ; Xu R. Z. ; Cao Y. ; Xiang M. Fabrication of anti-fouling thin-film composite reverse osmosis membrane via constructing heterogeneous wettability surface . J. Appl. Polym. Sci. , 2021 , 138 ( 42 ), 51256 . doi: 10.1002/app.51256 http://dx.doi.org/10.1002/app.51256

Peng J. W. ; Yuan S. C. ; Geng H. L. ; Zhang X. G. ; Zhang M. ; Xu F. ; Lin D. ; Gao Y. Y. ; Wang H. Y. Robust and multifunctional superamphiphobic coating toward effective anti-adhesion . Chem. Eng. J. , 2022 , 428 , 131162 . doi: 10.1016/j.cej.2021.131162 http://dx.doi.org/10.1016/j.cej.2021.131162

Wang Z. C. ; Liu X. J. ; Ji J. W. ; Tao T. T. ; Zhang T. ; Xu J. M. ; Jiao Y. L. ; Liu K. Underwater drag reduction and buoyancy enhancement on biomimetic antiabrasive superhydrophobic coatings . ACS Appl. Mater. Interfaces , 2021 , 13 ( 40 ), 48270 - 48280 . doi: 10.1021/acsami.1c14342 http://dx.doi.org/10.1021/acsami.1c14342

Fakhri M. ; Rezaee B. ; Pakzad H. ; Moosavi A. Facile, scalable, and low-cost superhydrophobic coating for frictional drag reduction with anti-corrosion property . Tribol. Int. , 2023 , 178 , 108091 . doi: 10.1016/j.triboint.2022.108091 http://dx.doi.org/10.1016/j.triboint.2022.108091

Xiao Z. ; Chen C. J. ; Liu S. Q. ; Liu C. Z. ; Liu W. L. ; Cheng Z. ; Yu X. Q. ; Lu Y. ; Zhang Y. F. Endowing durable icephobicity by combination of a rough powder coating and a superamphiphobic coating . Chem. Eng. J. , 2024 , 482 , 149001 . doi: 10.1016/j.cej.2024.149001 http://dx.doi.org/10.1016/j.cej.2024.149001

Wood M. J. ; Brock G. ; Debray J. ; Servio P. ; Kietzig A. M. Robust anti-icing surfaces based on dual functionality-microstructurally-induced ice shedding with superimposed nanostructurally-enhanced water shedding . ACS Appl. Mater. Interfaces , 2022 , 14 ( 41 ), 47310 - 47321 . doi: 10.1021/acsami.2c16972 http://dx.doi.org/10.1021/acsami.2c16972

Ren G. Y. ; Qiao Z. T. ; Tuo Y. ; Zheng W. J. ; Chen X. D. ; Shang J. F. ; Xu H. T. ; Bai L. ; Cao X. ; Ma H. X. ; Gao X. H. ; Li S. Y. Graded fillers method fabricating superamphiphobic coatings with high thermal conductivity, wear resistance and durable corrosion resistance . Prog. Org. Coat. , 2024 , 189 , 108268 . doi: 10.1016/j.porgcoat.2024.108268 http://dx.doi.org/10.1016/j.porgcoat.2024.108268

Wei J. F. ; Li B. C. ; Jing L. Y. ; Tian N. ; Zhao X. ; Zhang J. P. Efficient protection of Mg alloy enabled by combination of a conventional anti-corrosion coating and a superamphiphobic coating . Chem. Eng. J. , 2020 , 390 , 124562 . doi: 10.1016/j.cej.2020.124562 http://dx.doi.org/10.1016/j.cej.2020.124562

Zhang B. B. ; Yang G. ; Xu W. C. ; Duan J. Z. ; Hou B. R. Hybrid superamphiphobic anti-corrosion coating with integrated functionalities of liquid repellency, self-cleaning, and anti-icing . J. Mater. Sci. Technol. , 2024 , 184 , 256 - 268 . doi: 10.1016/j.jmst.2023.10.042 http://dx.doi.org/10.1016/j.jmst.2023.10.042

Zhang L. G. ; Zhang P. Y. ; Guo Z. G. Advances in the durability of biomimetic superamphiphobic surfaces . Nano Today , 2025 , 62 , 102686 . doi: 10.1016/j.nantod.2025.102686 http://dx.doi.org/10.1016/j.nantod.2025.102686

Peng J. Y. ; Zhao X. J. ; Wang W. F. ; Gong X. Durable self-cleaning surfaces with superhydrophobic and highly oleophobic properties . Langmuir , 2019 , 35 ( 25 ), 8404 - 8412 .

Elzaabalawy A. ; Meguid S. A. Development of novel superhydrophobic coatings using siloxane-modified epoxy nanocomposites . Chem. Eng. J. , 2020 , 398 , 125403 . doi: 10.1016/j.cej.2020.125403 http://dx.doi.org/10.1016/j.cej.2020.125403

Zhang B. B. ; Liu X. ; Zhan T. R. ; Hou B. R. Bilayer coating fabricated on aluminum alloy substrates with superamphiphobicity, corrosion resistance, self-cleaning, and delayed icing properties . J. Mater. Res. Technol. , 2024 , 30 , 8218 - 8227 . doi: 10.1016/j.jmrt.2024.05.210 http://dx.doi.org/10.1016/j.jmrt.2024.05.210

Zheng Y. J. ; Wang K. L. ; Sun L. ; Shi H. L. ; Zhang X. Preparation of PFDTS-Kaolin/PU superamphiphobic coatings with antibacterial, antifouling and improved durability property . Prog. Org. Coat. , 2022 , 173 , 107145 . doi: 10.1016/j.porgcoat.2022.107145 http://dx.doi.org/10.1016/j.porgcoat.2022.107145

Zhang J. T. ; Yang J. Y. ; Li Q. Y. ; Ding J. ; Liu L. J. ; Sun T. ; Li H. H. Preparation of WPU-based super-amphiphobic coatings functionalized by in situ modified SiO x particles and their anti-biofilm mechanism . Biomater. Sci. , 2021 , 9 ( 22 ), 7504 - 7521 . doi: 10.1039/d1bm01285a http://dx.doi.org/10.1039/d1bm01285a

Zhou X. T. ; Liu J. ; Liu W. D. ; Steffen W. ; Butt H. J. Fabrication of stretchable superamphiphobic surfaces with deformation-induced rearrangeable structures . Adv. Mater. , 2022 , 34 ( 10 ), 2107901 . doi: 10.1002/adma.202107901 http://dx.doi.org/10.1002/adma.202107901

Xiao T. ; Wei K. ; Wang Y. D. ; Jiang L. H. ; Xiang P. ; Li X. Y. ; Tan X. Y. Transparent and durable PDMS(O)/HDTMS anti-icing surfaces derived from candle soot . Surf. Coat. Technol. , 2022 , 445 , 128717 . doi: 10.1016/j.surfcoat.2022.128717 http://dx.doi.org/10.1016/j.surfcoat.2022.128717

li J. ; Xu L. H. ; Yuan X. L. ; Pan H. ; Wang L. M. ; Shen Y. ; Li K. T. Preparation of robust and self-healing superamphiphobic cotton fabrics based on modified silica aerogel particles . Colloids Surf. A Physicochem. Eng. Aspects , 2022 , 651 , 129634 . doi: 10.1016/j.colsurfa.2022.129634 http://dx.doi.org/10.1016/j.colsurfa.2022.129634

Jiao X. ; Li M. T. ; Yu X. Q. ; Yang S. ; Zhang Y. F. Mechanically robust superamphiphobic ceramic coatings with releasable nanoparticle-capsules . Chem. Eng. J. , 2022 , 446 , 137336 . doi: 10.1016/j.cej.2022.137336 http://dx.doi.org/10.1016/j.cej.2022.137336

Zhao L. X. ; Li H. Y. ; Zhou K. ; Liu H. X. ; Wang J. ; Zhang B. B. Enhanced mechanical stability and corrosion resistance of superhydrophobic coating reinforced with inorganic binder . J. Cent. South Univ. , 2024 , 31 ( 10 ), 3502 - 3516 . doi: 10.1007/s11771-024-5577-8 http://dx.doi.org/10.1007/s11771-024-5577-8

Nakayama K. ; Koyama A. ; Zhu C. Y. ; Aoki Y. ; Habazaki H. Rapid and repeatable self-healing superoleophobic porous aluminum surface using infiltrated liquid healing agent . Adv. Mater. Interfaces , 2018 , 5 ( 19 ), 1800566 . doi: 10.1002/admi.201800566 http://dx.doi.org/10.1002/admi.201800566

Zhang J. J. ; Wei J. F. ; Li B. C. ; Zhao X. ; Zhang J. P. Long-term corrosion protection for magnesium alloy by two-layer self-healing superamphiphobic coatings based on shape memory polymers and attapulgite . J. Colloid Interface Sci. , 2021 , 594 , 836 - 847 . doi: 10.1016/j.jcis.2021.03.005 http://dx.doi.org/10.1016/j.jcis.2021.03.005

Zhao D. L. ; Du Z. K. ; Liu S. S. ; Wu Y. F. ; Guan T. ; Sun Q. L. ; Sun N. ; Ren B. Y. UV light curable self-healing superamphiphobic coatings by photopromoted disulfide exchange reaction . ACS Appl. Polym. Mater. , 2019 , 1 ( 11 ), 2951 - 2960 . doi: 10.1021/acsapm.9b00656 http://dx.doi.org/10.1021/acsapm.9b00656

Li W. ; Ni X. X. ; Zhang X. H. ; Lei Y. ; Guo J. ; Jin J. ; You B. UV-NIR dual-responsive nanocomposite coatings with healable, superhydrophobic, and contaminant-resistant properties . ACS Appl. Mater. Interfaces , 2020 , 12 ( 42 ), 48101 - 48108 . doi: 10.1021/acsami.0c12266 http://dx.doi.org/10.1021/acsami.0c12266

Meena Narayana Menon D. ; Giardino M. ; Janner D. Tunable pulsewidth nanosecond laser texturing: from environment friendly superhydrophobic to superamphiphobic surfaces . Appl. Surf. Sci. , 2023 , 610 , 155356 . doi: 10.1016/j.apsusc.2022.155356 http://dx.doi.org/10.1016/j.apsusc.2022.155356

Liu Y. ; Lu J. Z. ; Xue W. ; Zhang Z. Y. ; Zhu H. ; Xu K. ; Wu Y. C. ; Wang B. ; Lei W. N. A strategy for fabricating multi-level micro-nano superamphiphobic surfaces by laser-electrochemistry subtractive-additive hybrid manufacturing method . Colloids Surf. A Physicochem. Eng. Aspects , 2023 , 663 , 130946 . doi: 10.1016/j.colsurfa.2023.130946 http://dx.doi.org/10.1016/j.colsurfa.2023.130946

Kang S. M. ; Kim H. ; Choi J. S. ; An J. H. Bioinspired omniphobic microchamber structure . Adv. Mater. Interfaces , 2021 , 8 ( 12 ), 2100027 . doi: 10.1002/admi.202100027 http://dx.doi.org/10.1002/admi.202100027

Kim H. ; Kim H. N. ; Kang S. M. Robust fabrication of double-ring mushroom structure for reliable omniphobic surfaces . Surf. Interfaces , 2022 , 29 , 101778 . doi: 10.1016/j.surfin.2022.101778 http://dx.doi.org/10.1016/j.surfin.2022.101778

Yang Y. ; Ren Z. Y. ; Zhou C. H. ; Lin Y. X. ; Hou L. X. ; Shi L. W. ; Zhong S. C. 3 D-printed robust dual superlyophobic Ti-based porous structure for switchable oil/water emulsion separations . Adv. Funct. Mater. , 2023 , 33 ( 15 ), 2212262 . doi: 10.1002/adfm.202212262 http://dx.doi.org/10.1002/adfm.202212262

Wang D. H. ; Sun Q. Q. ; Hokkanen M. J. ; Zhang C. L. ; Lin F. Y. ; Liu Q. ; Zhu S. P. ; Zhou T. F. ; Chang Q. ; He B. ; Zhou Q. ; Chen L. Q. ; Wang Z. K. ; Ras R. H. A. ; Deng X. Design of robust superhydrophobic surfaces . Nature , 2020 , 582 ( 7810 ), 55 - 59 . doi: 10.1038/s41586-020-2331-8 http://dx.doi.org/10.1038/s41586-020-2331-8

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

磁场诱导定向提升环氧树脂复合电介质非线性电导特性与调控机理

钆-铋-环氧复合涂层制备及其射线屏蔽性能研究

环氧基封端超支化聚芳醚酮增韧双酚A环氧树脂

基于共价自适应网络重排的环氧树脂封装材料应力释放研究

乳液聚合制备Janus颗粒研究进展