A sandwich-like sample configuration of three polymer layers was designed and used for rheological probing of the chain interdiffusion of two miscible polydisperse polymers in the melt state.It was found that the interdiffusion process can be probed by the growth of the rheological responses with time as long as the polymer pair constituting the interface has an adequate difference in rheological properties and is miscible.To understand the rheological signal of the interdiffusion process

a phenomenal rheological model combined with a fitted model for the experimental data was proposed.With the two models

two important model parameters concerning the interdiffusion dynamics were discussed.The results show that the interdiffusion process can be probed by rheological properties and the dynamics of inter diffusion is greatly affected by the difference in the molecular weight between the polymer pair.The first parameter

the exponent for the time dependent behavior of the interpenetration distance

was found to be larger than the typical value of 1/2

which is ascribed to the dynamic dilution process as proposed in tube theories.While

by the other parameter

the characteristic time tc

the interdiffusion coefficient can be estimated.It is noted that these two parameters were found to be frequency-dependent

which can be mainly ascribed to the polydispersity of the molecular weight.Finally

the results indicate that the fast-mode model is reasonable for the understanding of the interdiffusion process.