Visible Light Photoiniferter Polymerization

Ling-qi Meng; Xiu-hui Tang; Ze-sheng An

doi:10.11777/j.issn1000-3304.2026.25326

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Visible Light Photoiniferter Polymerization

Feature Article | 更新时间：2026-05-08

- Visible Light Photoiniferter Polymerization
- Acta Polymerica Sinica Vol. 57, Issue 5, Pages: 1093-1107(2026)
- 作者机构：
  
  吉林大学化学学院超分子结构与材料全国重点实验室长春 130012
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2026.25326
  CLC：
- CSTR：32057.14.GFZXB.2026.7555
- Received：24 December 2025，
  
  Accepted：09 January 2026，
  
  Online First：27 February 2026，
  
  Published：20 May 2026
- 稿件说明：
移动端阅览
孟令齐, 汤秀慧, 安泽胜. 可见光光解调控聚合. 高分子学报, 2026, 57(5), 1093-1107.

Meng, L. Q.; Tang, X. H.; An, Z. S. Visible light photoiniferter polymerization. Acta Polymerica Sinica (in Chinese), 2026, 57(5), 1093-1107.
孟令齐, 汤秀慧, 安泽胜. 可见光光解调控聚合. 高分子学报, 2026, 57(5), 1093-1107. DOI： 10.11777/j.issn1000-3304.2026.25326. CSTR： 32057.14.GFZXB.2026.7555.

Meng, L. Q.; Tang, X. H.; An, Z. S. Visible light photoiniferter polymerization. Acta Polymerica Sinica (in Chinese), 2026, 57(5), 1093-1107. DOI： 10.11777/j.issn1000-3304.2026.25326. CSTR： 32057.14.GFZXB.2026.7555.

摘要

光解调控聚合以光为外场调控手段，无需外加引发剂与催化剂，凭借其可精确控制反应发生时间与空间位置的特点，以及高聚合活性，已发展为一种重要的合成工具. 然而，该技术仍面临聚合速率与可控度之间矛盾、高能量光源依赖、对氧气敏感、以及引发转移终止剂种类有限等挑战. 我们近年来结合理论计算与实验验证，发展了一系列新型引发转移终止剂，对光解调控聚合机理有了较为深入的理解，建立了快速、可控、耐氧的三重态增强的光解调控聚合(TEPP)新方法. 本文系统总结了基于二硫代氨基甲酸酯类引发转移终止剂的多类新型光控聚合体系，在实现超高分子量可控聚合、长波长驱动、高效耐氧等方面表现出显著优势，并对设计理念与聚合性能进行了深入阐述，以期为光控自由基聚合技术的进一步发展提供参考.

Abstract

Photoiniferter polymerization has evolved into an important reversible deactivation radical polymerization technique. It employs an iniferter as the sole agent for initiation

transfer

and termination under light irradiation

demonstrating a high polymerization rate and high end-group fidelity owing to the absence of exogenous radical sources. However

this technique still faces significant challenges

such as the trade-off between the polymerization rate and controllability

reliance on high-energy light

high oxygen sensitivity

and a limited variety of iniferters. In this Feature Article

we summarize our work on the development of various efficient visible-light-controlled photoiniferter polymerization systems. Specifically

by combining theoretical calculations with experimental validation

we gained important insights into the structure-property-polymerization relationships of these photoiniferters and established a novel triplet-enhanced photoiniferter polymerization (TEPP) method

which exhibits a high polymerization rate

intrinsic oxygen tolerance

high end-group fidelity

and excellent biocompatibility owing to the high quantum yield and energy of the triplet state

enhanced chain transfer kinetics

and improved reversible combination of pyrazole-based iniferters. These novel photoiniferter polymerization systems are expected to find widespread applications in bioconjugation

3D printing

and hydrogel preparation.

关键词

Keywords

references

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