基于二氧化碳/二醇反应环碳酸酯的合成与开环聚合

陈有华; 王家宝; 胡欣; 朱宁

doi:10.11777/j.issn1000-3304.2026.26111

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基于二氧化碳/二醇反应环碳酸酯的合成与开环聚合

综述 | 更新时间：2026-07-23

- 基于二氧化碳/二醇反应环碳酸酯的合成与开环聚合
- Synthesis and Ring-opening Polymerizations of Cyclic Carbonates Derived from Carbon Dioxide/Diol Reactions
- 高分子学报 2026年页码：1-19
- 作者机构：
  
  1.南京工业大学，生物与制药工程学院材料化学工程国家重点实验室，南京 211800
  2.南京工业大学，材料科学与工程学院，南京 211800
- 作者简介：
  
  胡欣，西安交通大学材料科学与工程博士，南京工业大学材料科学与工程学院教授. 主要从事功能高分子材料开发及微化工制备研究，加入南京工业大学至今以第一或通讯作者（含共同作者）在ACS Appl. Mater. Interfaces、ACS Macro Lett.、ACS Appl. Polym. Mater.、Chem. Eng. J.、Carbohydr. Polym.等期刊发表论文40余篇，主持国家自然科学基金面上项目和青年项目各1项、企业委托开发项目3项，获中国化工学会基础研究成果奖一等奖，入选江苏省科技副总.E-mail: xinhu@njtech.edu.cn
  朱宁，浙江大学高分子化学与物理专业博士，南京工业大学生物与制药工程学院教授.主要研究化工新材料绿色制造，加入南京工业大学以来作为第一或通讯作者（含共同）在Nat. Mater.、Angew. Chem. Int. Ed.、Adv. Funct. Mater.、AIChE J.、ACS Appl. Mater. Interfaces等期刊发表论文50余篇，授权中国发明专利50余件、美国专利5件，主持科技部项目课题1项/子课题1项、国家自然科学基金面上项目3项/青年项目1项、企业委托开发项目6项，获省部级科研奖励6项.E-mail: ningzhu@njtech.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 ┣22278223;22278205);22478188┫
- DOI：10.11777/j.issn1000-3304.2026.26111
  中图分类号：
- CSTR：32057.14.GFZXB.2026.7657
- 收稿：2026-04-14，
  
  录用：2026-06-15，
  
  网络首发：2026-07-23，
- 稿件说明：
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陈有华, 王家宝, 胡欣, 朱宁. 基于二氧化碳/二醇反应环碳酸酯的合成与开环聚合. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26111.

Chen, Y. H.; Wang, J. B.; Hu, X.; Zhu, N. Synthesis and ring-opening polymerizations of cyclic carbonates derived from carbon dioxide/diol reactions. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26111.
陈有华, 王家宝, 胡欣, 朱宁. 基于二氧化碳/二醇反应环碳酸酯的合成与开环聚合. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26111. DOI： CSTR： 32057.14.GFZXB.2026.7657.

Chen, Y. H.; Wang, J. B.; Hu, X.; Zhu, N. Synthesis and ring-opening polymerizations of cyclic carbonates derived from carbon dioxide/diol reactions. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26111. DOI： CSTR： 32057.14.GFZXB.2026.7657.

摘要

二氧化碳(CO

)转化为高附加值精细化学品和高分子材料，已成为高分子化学和绿色化学等领域的研究热点. 其中，CO

与二醇反应合成环碳酸酯是重要的方向之一，通过环碳酸酯的催化可控开环聚合可以制备不同结构和性能的聚碳酸酯材料. 本综述以1

3-二醇衍生物、1

4-二醇衍生物、1

5-二醇衍生物与CO

反应分类，介绍了六元环、七元环和八元环碳酸酯单体的合成与开环聚合研究进展，并且对相关领域所面临的机遇与挑战进行了探讨和展望.

Abstract

The high-value utilization of carbon dioxide (CO

) for the conversion into fine chemicals and polymer materials have been paid much attention in polymer science and green chemistry. Among them

the reaction of CO

with diols to produce cyclic carbonates

represents an important direction. Through the catalytic controlled ring-opening polymerizations of cyclic carbonates

polycarbonates with different structures and properties can be prepared. This review focuses on synthesis and ring-opening polymerizations of cyclic carbonates derived from CO

/diol reactions. The reactions of CO

with 1

3-diol derivatives

4-diol derivatives

and 1

5-diol derivatives were summarized in order with the target products of six-membered

seven-membered

and eight-membered cyclic carbonates. Catalytic ring-opening polymerizations of these obtained cyclic carbonates into polycarbonates were highlighted. Moreover

the challenges and opportunities in the related fields were discussed.

关键词

Keywords

references

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