可见光光解调控聚合

孟令齐; 汤秀慧; 安泽胜

doi:10.11777/j.issn1000-3304.2026.25326

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可见光光解调控聚合

专论 | 更新时间：2026-05-08

- 可见光光解调控聚合
- Visible Light Photoiniferter Polymerization
- 高分子学报 2026年57卷第5期页码：1093-1107
- 作者机构：
  
  吉林大学化学学院超分子结构与材料全国重点实验室长春 130012
- 作者简介：
  
  [ "安泽胜，男，1974年生. 1997年获得山东大学化学学士学位，2000年获得该校化学硕士学位，2005年获得佐治亚理工学院理学博士学位，随后在加州大学圣芭芭拉分校从事博士后研究. 2008年于上海大学参加工作，并于2010年晋升为教授. 2019年入职吉林大学化学学院超分子结构与材料全国重点实验室，其研究聚焦于可控自由基聚合、酶催化及超分子化学领域. 现为吉林大学“唐敖庆学者”杰出教授，承担国家十四五重点研发计划项目、国家自然科学基金重大项目课题以及面上项目等，获得英国皇家化学会会士、吉林省长白山特聘领军人才等荣誉. 担任《高分子学报》副主编、中国化学会高分子学科委员会委员、吉林省化学会理事.E-mail: anzesheng@jlu.edu.cn" ]
- 基金信息：
  
  国家重点研发计划(2021YFA1501600);国家自然科学基金(基金号 ┣22193020;22193024);22371089┫
- DOI：10.11777/j.issn1000-3304.2026.25326
  中图分类号：
- CSTR：32057.14.GFZXB.2026.7555
- 收稿：2025-12-24，
  
  录用：2026-01-09，
  
  网络首发：2026-02-27，
  
  纸质出版：2026-05-20
- 稿件说明：
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孟令齐, 汤秀慧, 安泽胜. 可见光光解调控聚合. 高分子学报, 2026, 57(5), 1093-1107.

Meng, L. Q.; Tang, X. H.; An, Z. S. Visible light photoiniferter polymerization. Acta Polymerica Sinica (in Chinese), 2026, 57(5), 1093-1107.
孟令齐, 汤秀慧, 安泽胜. 可见光光解调控聚合. 高分子学报, 2026, 57(5), 1093-1107. DOI： 10.11777/j.issn1000-3304.2026.25326. CSTR： 32057.14.GFZXB.2026.7555.

Meng, L. Q.; Tang, X. H.; An, Z. S. Visible light photoiniferter polymerization. Acta Polymerica Sinica (in Chinese), 2026, 57(5), 1093-1107. DOI： 10.11777/j.issn1000-3304.2026.25326. CSTR： 32057.14.GFZXB.2026.7555.

摘要

光解调控聚合以光为外场调控手段，无需外加引发剂与催化剂，凭借其可精确控制反应发生时间与空间位置的特点，以及高聚合活性，已发展为一种重要的合成工具. 然而，该技术仍面临聚合速率与可控度之间矛盾、高能量光源依赖、对氧气敏感、以及引发转移终止剂种类有限等挑战. 我们近年来结合理论计算与实验验证，发展了一系列新型引发转移终止剂，对光解调控聚合机理有了较为深入的理解，建立了快速、可控、耐氧的三重态增强的光解调控聚合(TEPP)新方法. 本文系统总结了基于二硫代氨基甲酸酯类引发转移终止剂的多类新型光控聚合体系，在实现超高分子量可控聚合、长波长驱动、高效耐氧等方面表现出显著优势，并对设计理念与聚合性能进行了深入阐述，以期为光控自由基聚合技术的进一步发展提供参考.

Abstract

Photoiniferter polymerization has evolved into an important reversible deactivation radical polymerization technique. It employs an iniferter as the sole agent for initiation

transfer

and termination under light irradiation

demonstrating a high polymerization rate and high end-group fidelity owing to the absence of exogenous radical sources. However

this technique still faces significant challenges

such as the trade-off between the polymerization rate and controllability

reliance on high-energy light

high oxygen sensitivity

and a limited variety of iniferters. In this Feature Article

we summarize our work on the development of various efficient visible-light-controlled photoiniferter polymerization systems. Specifically

by combining theoretical calculations with experimental validation

we gained important insights into the structure-property-polymerization relationships of these photoiniferters and established a novel triplet-enhanced photoiniferter polymerization (TEPP) method

which exhibits a high polymerization rate

intrinsic oxygen tolerance

high end-group fidelity

and excellent biocompatibility owing to the high quantum yield and energy of the triplet state

enhanced chain transfer kinetics

and improved reversible combination of pyrazole-based iniferters. These novel photoiniferter polymerization systems are expected to find widespread applications in bioconjugation

3D printing

and hydrogel preparation.

关键词

Keywords

references

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